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The amorphous Al-Ni-Fe-Gd coatings were fabricated to improve anti-corrosion performance of offshore platforms.

The amorphous Al-Ni-Fe-Gd coatings were first fabricated on S355 steel using the laser thermal spraying.

The amorphous forming capability and corrosion resistance increases with the laser powers increasing.

The amorphous Al-Ni-Fe-Gd coatings were applied on S355 steel of offshore platforms to increase its long-term heavy and anti-corrosion protection.

The amorphous Al-Ni-Fe-Gd coatings were first fabricated using a laser thermal spraying, improving its anti-corrosion.

The purpose of this study is to evaluate the effect of graphene, basalt flakes and their synergy on the corrosion resistance of zinc-rich coatings. As the important heavy-duty anticorrosion coatings, zinc-rich coatings provided cathodic protection for the substrate. However, to ensure cathodic protection, a large number of zinc powder made the penetration resistance known as the weakness of zinc-rich coatings. Therefore, graphene and basalt flakes were introduced into zinc-rich coatings to coordinate its cathodic protection and shielding performance.

Three kinds of coatings were prepared; they were graphene modified zinc-rich coatings, basalt flakes modified zinc-rich coatings and graphene-basalt flakes modified zinc-rich coatings. The anticorrosion behavior of painted steel was studied by using the electrochemical impedance spectroscopy (EIS) technique in chloride solutions. The equivalent circuit methods were used for EIS analysis to obtain the electrode process structure of the coated steel system. Simultaneously, the corrosion resistance of the three coatings was evaluated by water resistance test, salt water resistance test and salt spray test.

The study found that the addition of a small amount of graphene and basalt flakes significantly improved the anticorrosion performance of coatings by enhancing their shielding ability against corrosive media and increasing the resistance of the electrochemical reaction. The modified coatings exhibited higher water resistance, salt water resistance and salt spray resistance. The graphene-basalt flakes modified zinc-rich coatings demonstrated the best anticorrosion effect. The presence of basalt scales and graphene oxide in the coatings significantly reduced the water content and slowed down the water penetration rate in the coatings, thus prolonging the coating life and improving anticorrosion effects. The modification of zinc-rich coatings with graphene and basalt flakes improved the utilization rate of zinc powder and the shielding property of coatings against corrosive media, thus strengthening the protective effect on steel structures and prolonging the service life of anticorrosion coatings.

The significance of developing graphene-basalt flakes modified zinc-rich coatings lies in their potential to offer superior performance in corrosive environments, leading to prolonged service life of metallic structures, reduced maintenance costs and a safer working environment. Furthermore, such coatings can be used in various industrial applications, including bridges, pipelines and offshore structures, among others.

The purpose of this paper is to investigate the effects of laser power on the electrochemical corrosion performance in 3.5% NaCl, 0.1 M H₂SO₄ and 0.1 M NaOH solutions, which provided an experimental basis for the application of Al–Ti–Ni amorphous coating in marine environment.

Amorphous Al–Ti–Ni coatings were fabricated on S355 structural steel by laser thermal spraying (LTS) at different laser powers. The surface and cross-section morphologies, chemical element distribution, phases and crystallization behaviors of obtained coatings were analyzed using a scanning electron microscope, energy-dispersive X-ray spectroscope, X-ray diffraction and differential scanning calorimetry, respectively. The effects of laser power on the electrochemical corrosion performances of Al–Ti–Ni coatings in 3.5% NaCl, 0.1 M H₂SO₄ and 0.1 M NaOH solutions were investigated using an electrochemical workstation.

The crystallization temperature of Al–Ti–Ni coatings fabricated at the laser power of 1,300 and 1,700 W is ∼520°C, whereas that fabricated at the laser power of 1,500 W is ∼310°C. The coatings display excellent corrosion resistance in 3.5% NaCl and 0.1 M NaOH solutions, while a faster dissolution rate in 0.1 M H₂SO₄ solution. The coatings fabricated at the laser power of 1,300 and 1,700 W present the better electrochemical corrosion resistance in 3.5% NaCl and 0.1 M NaOH solutions, whereas that fabricated at the laser power of 1,500 W exhibits the better electrochemical corrosion resistance in 0.1 M H₂SO₄ solution.

In this work, Al-wire-cored Ti–Ni powder was first on S355 steel with the laser power of 1,300, 1,500 and 1,700 W, and the effects of laser power on the electrochemical corrosion performance in 3.5% NaCl, 0.1 M H₂SO₄ and 0.1 M NaOH solutions were investigated using an electrochemical workstation.

In this study, an amorphous Al-Ti-Ni coating was fabricated on S355 steel using an arc spraying, and its corrosion behavior immersed in 3.5 per cent NaCl solution for 720 h was discussed, which provided an experimental basis for the application of arc sprayed Al-Ti-Ni coating on S355 steel on marine platform.

An amorphous Al-Ti-Ni coating was sprayed on S355 structural steel using an arc spraying. The surface-interface morphologies, chemical element compositions and phases of the obtained Al-Ti-Ni coating were analyzed using a scanning electron microscope, energy dispersive spectrometer and X-ray diffractometer, respectively. The distributions of chemical elements on the coating surface and interface were analyzed using an energy spectrum scanning; the bonding mechanism between the coating and the substrate was also discussed.

Financial support for this research by the Key Research and Development Project of Jiangsu Province (BE2016052).

In this study, an amorphous Al-Ti-Ni coating was fabricated on S355 steel using an arc spraying, its corrosion behavior immersed in 3.5 per cent 25 NaCl solution for 720 h was discussed.

The purpose of this paper is to investigate the effects of load and speed on the corrosive wear performance of Al coating in 3.5% NaCl solution, which provided an experimental reference for the anti-corrosion engineering on offshore platforms.

A layer of Al coating was prepared on S355 steel using an arc spraying. The corrosive wear test was carried out with CFT–1 type surface property tester. The effects of load and speed on the corrosive wear performance of Al coating were investigated and the wear mechanism was also discussed. The electrochemical tests were conducted using a CHI660E type electrochemical workstation, the anti-corrosion mechanism was analyzed.

The average coefficient of frictions (COFs) of Al coating under loads of 1.5, 2.5 and 3.5 N are 0.745, 0.847 and 0.423, the wear mechanism is abrasive wear. The average COFs of Al coating at the speeds of 200, 400 and 600 rpm are 0.745, 0.878 and 0.617, respectively, the wear mechanism at the speeds of 200 and 400 rpm are abrasive wear, while that at the speed of 600 rpm is abrasive wear and fatigue wear. The anti-corrosion mechanism is the isolation of Cl^– corrosion and cathodic protection of sacrificial anode.

This paper mainly studied corrosive wear and electrochemical corrosion performances of Al coating. This study hereby confirms that this manuscript is the original work and has not been published nor has it been submitted simultaneously elsewhere. This paper further confirms that all authors have checked the manuscript and have agreed to the submission.

The parameters for Quality Control of both the anti‐corrosion coating and, where required, concrete weight coaling, are reviewed for six major pipelines in which the authors have been directly involved. The importance of field joint anti‐corrosion coatings are discussed, particularly for concrete weight coated pipelines. The differing environment of each project is identified and includes “in‐service” temperature, water depth, mode of pipe lay, together with cathodic protection considerations. The importance of quality control is traced from initial design study to coating and includes practical aspects of on‐site quality assurance. Material selection, application, inspection, safety aspects and economics are discussed.

The purpose of this paper is to provide an experimental basis for studying the effects of laser remelting on the surface modification of arc-sprayed Al coating.

A layer of arc-sprayed Al coating on S355 steel was remelted with a CO₂ laser, and the surface-interface morphologies, compositions of chemical elements and phases of Al coating were analyzed with scanning electron microscopy, energy disperse spectroscopy and X-ray diffraction, respectively. The effects of laser remelting on compositions of chemical elements and bonding performance of Al coatings were discussed.

The result shows that there are some pores existing on the Al coating surface after arc spraying, and the combination mode of coating interface is primarily composed of mechanical bonding. The pores on the Al coating reduce after laser remelting, which improves the compact performance, and the mechanical binding mode by arc spraying is changed into metallurgical bonding. The Fe and Al atoms at the coating interface are distributed with gradient, and the stratified enrichment is evident, which improves binding performance of the Al coating. The Al coating exhibits general corrosion before laser remelting and local corrosion after laser remelting, which improves the corrosion resistance of Al coating.

The arc-sprayed Al coating is remelted by CO₂ laser, improving its microstructures and bonding mode with the substrate.

The aim of this study is to investigate the effects of Al₂O₃ mass fraction on the corrosive-wear and electrochemical performance of NiTi coating in 3.5% NaCl solution.

The NiTi–xAl₂O₃ coatings were fabricated on S355 steel by laser cladding, and their corrosive-wear and electrochemical performance were investigated using a wear tester and electrochemical workstation, respectively.

The wear rates of NiTi–5%Al₂O₃, –10%Al₂O₃ and –15%Al₂O₃ coatings are 82.33, 54.23 and 30.10 µm³ mm⁻¹ N⁻¹, respectively, showing that the wear resistance of NiTi–15%Al₂O₃ coating is the best. The wear mechanism is abrasive wear, which is attributed to the increase of coating hardness by the Al₂O₃ addition. The polarization resistance of NiTi–5%Al₂O₃, –10%Al₂O₃ and –15%Al₂O₃ coatings is 3,639, 5,125 and 10,024 O cm², respectively, exhibiting that the NiTi–15% Al₂O₃ coating has the best corrosion resistance.

The roles of Al₂O₃ in the corrosive-wear and electrochemical performance of NiTi–xAl₂O₃ coating were revealed through the experimental investigation.

The peer review history for this article is available at: https://publons.com/publon/10.1108/ILT-02-2024-0044/

The development of the Hutton Field in the UK sector of the North Sea incorporates, for the first time, a buoyant Tension Leg Platform maintained in position by an array of sixteen tubular steel tension leg strings. To satisfy the stringent design criteria associated with this new generation of offshore oil production facilities, all corrosion control systems have to be effective, reliable and contribute little to structure weight. An intensive review of the various available design options was undertaken, from which emerged the use of aluminium metal sprayed coatings as possibly the optimum method of corrosion control for the tension legs. Since there was limited service data available relating to the performance of sprayed metal coatings in sea water immersion service, a development programme was completed to determine the perfomance characteristics of these coatings under tension leg operating conditions. In parallel, the problems of applying the coatings were addressed since it was considered that, as for all coating systems, correct application is critical to the satisfactory in‐service performance of the coating. The potential advantages of sprayed metal coatings for immersion service in the offshore industry was significant.