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This paper sets out to study the corrosion of No. 20 carbon steel without film and with films of different qualities in high‐temperature boiler water with different Cl⁻ concentrations.

The static simulated experiment in high‐pressure autoclave and the surface analysis methods of EPMA and XRD were carried out to study the corrosion effect.

Under the following conditions: T=360±3°C, pH = 9.40±0.10, c_O2<0.020 mg/l, the density of pitting corrosion on specimens without a protective film increased with the increase of C_Cl⁻ content, while C_Cl⁻ was > 0.2 mg/l. The film on specimens with integral films would not dissolve observably even until the C_Cl⁻ concentration was as high as 0.8 mg/l. Films with corrosion pits would begin dissolving when the Cl⁻ concentration reached 0.4 mg/l. The main constituents of the oxidative films in the gas and liquid phases both were Fe₃O₄.

In order to prevent carbon steel from corroding in boiler water containing Cl⁻ under conditions of low‐phosphate and low‐sodium hydroxide treatment, the concentration of Cl⁻ should be strictly controlled.

It was found that the presence of excessive Cl⁻ in boiler water accelerated the corrosion of No. 20 carbon steel and the maximum permissible concentration of Cl⁻ under the conditions (temperature and pressure) of sub‐critical drum boilers was 0.2 mg/l. The research results can provide theoretical guidelines for preventing the facilities of power plants from corroding.

The purpose of this paper is to study the effects of Cl⁻ and direct stray current on the soil corrosion of three grounding grid materials.

The electrochemical corrosion properties of three grounding grid materials, which include the Q235 steel, Q235 galvanized flat steel and copper, were measured by means of the weak polarization curve method and electrochemical impedance spectroscopy; the corrosion rate of specimens was calculated using the weight loss method; and the specimen surfaces were characterized using the scanning electron microscopy, energy-dispersive spectroscopy and X-ray diffraction analysis.

Results showed that both factors, Cl⁻ and direct stray current, can accelerate the corrosion rate of grounding grid materials. The magnitude of DC stray current density affected the mass transfer type and response frequency of the anode and cathode reaction of grounding materials, while the Cl⁻ contents of the soil only affect the mass transfer rate of the electrode material from the electrochemical impedance spectroscopy diagrams. The electric field generated by the DC stray current caused Cl⁻ directed migration. The larger the DC stray current density, the greater the diffusion process and the greater the weight loss rate of the grounding grid materials that would have a logarithmic relationship with the Cl⁻ content at the same DC stray current density. The corrosion resistance of the three materials is copper > Q235 galvanized flat steel > Q235 flat steel.

The paper provides information regarding the relationship among Cl⁻, direct stray current and corrosion of three grounding grid materials by means of electrochemical impedance spectroscopy. Meanwhile the weight loss rate is the logarithmic relationship with the Cl⁻ content, which is useful for understanding the corrosion mechanism of Q235 steel, Q235 galvanized flat steel and copper under the condition of Cl⁻ and direct stray current in soil.

The purpose of this study was to investigate the corrosion of low molecular organic acids from water-steam cycles such as acetic acid and formic acid in mental parts of steam turbine initial condensation zone.

The corrosion behavior of gray cast iron in initial condensate containing different concentrations of acetic acid and formic acid was studied by weight loss test, scanning electron microscopy, energy dispersive spectroscopy and X-ray diffraction.

The results indicated that gray cast iron had a certain degree of corrosion in the simulated initial condensate containing acetic acid and formic acid, but the acid corrosion of gray cast iron was not only caused by low molecular organic acid but also affected by inorganic anions such as Cl⁻. When Cl⁻ existed, after removing corrosion products, surface analysis results proved that the surface of gray cast iron was rough and uneven with many cracks, which was corrected more serious.

The corrosion behavior of thermal equipment by low molecular organic acids and inorganic anions in water-steam cycles was studied. The research results can provide theoretical guidelines for corrosion control of steam turbine in power plants.

Study of corrosion behaviour could benefit from quantum chemical calculation to investigate the role of adsorption of main anions such as OH⁻ and Cl⁻ on metallic surfaces. The purpose of this study is to report the quantum chemical study of aluminium immersed in NaOH, NaCl and HCl solutions and verifying the calculations by potentiodynamic and open-circuit potential (OCP) measurements.

The electrochemical evaluations based on potentiodynamic polarization and OCP experiments were carried out. For theoretical investigations, the quantum chemical calculation was performed. In this regard, the adsorption of Cl⁻, OH⁻ and H⁺ on aluminium surface was investigated. Furthermore, the natural bond orbital for the direction and magnitude of charge transfer interactions was calculated.

The calculations indicate that higher interaction energy between ions with the metallic cluster being modelled together with natural bond orbital calculations of direction and magnitude of charge transfer accurately predicts corrosion.

This paper shows that ions such as Cl⁻, OH⁻ and H⁺ cause the corrosion of aluminium in NaOH, NaCl and HCl environments. The overall theoretical data corroborate with experimental results.

When concrete is manufactured, it can be instantaneously contaminated by chloride (Cl⁻) ions or later by their intrusion from the environment. This work aims to study the electrochemical behavior of the passive layer formed on the reinforcing steel surface in the presence of the same Cl⁻ ion concentration, with and without passivation time. This will, undoubtedly, affect the corrosion threshold values thereafter.

Electrochemical polarizations were carried out in two concrete pore solutions. The surfaces of samples immersed for 255 days in saturated Ca(OH)₂ solution were examined with optical and scanning electron microscopy and Raman microspectroscopy.

Cl⁻ ion origins in reinforced concrete lead to different values of corrosion thresholds. The passive layer behaves like a physicochemical barrier, and corrosion occurs at higher NaCl concentration thresholds. The formed passive film on the steel surface shows differences in the chemical composition and the morphology. The results show a rich presence of hematite. Maghemite, lepidocrocite, akaganeite and goethite are also present in much lower concentrations. The Cl⁻ ion presence in fresh concrete at the beginning of the manufacture harms the good formation and the good stability of these oxides, leading to corrosion initiation.

This study contributes to a better understanding of the passive layer role, not only in reducing the corrosion rate value but also in reconsidering new Cl⁻ ion corrosion threshold values.

The chemical behaviour within the occluded cell of simulated cast iron artefact in 3.5 percent NaCl solution has been investigated by means of a simulated occluded cell. It was observed that the pH value and the amount of Cl⁻ migration in the occluded cell were related to the quantity of passing electric current. Electrochemical techniques were capable of providing information on the behaviour of the cast iron in a simulated occluded cell at various time intervals. The results of potentiodynamic polarisation and impedance measurements indicated that corrosion potentials became more negative and the cast iron was corroded more seriously. SEM micrographs clearly revealed the morphologies of specimens after simulated occluded cell galvanostatic tests for different time intervals at 1 mA/cm² anodic current density. An auto‐catalysing process was responsible for the enrichment of chloride ions in occluded cell which was confirmed by Energy Dispersive Spectroscopy (EDS).

The purpose of this paper is to investigate the influence of Cl‐ions on the pitting corrosion of water‐wall tube of a boiler and the principle behind it.

The specimens were immersed for seven hours at 300°C in deaerated water subjected to simulation‐modified equilibrium phosphate treatment, containing Cl‐ions at various concentrations. The effects of Cl‐ions on pitting corrosion were assessed by the rate mass loss, transmission reflection metallurgical microscopy, SEM, EDS, and XRD.

The results indicated that Cl‐ions cause the breakdown of passive films. The corrosion mechanism of Cl‐is proposed to involve an intermediate dissolution stage. The Cl‐ions act as a catalyst of corrosion, by inducing the hydrolysis of Fe2+. The critical susceptive Cl‐concentrations are 0.2 and 0.6 mg·L^‐1 for the passivated specimens and for the unpassivated specimens, respectively.

The paper provides information regarding the relationship between Cl‐concentrations and pitting corrosion, useful for understanding the mechanism of Cl‐induced pitting corrosion, and the research results can provide theoretical guidelines for preventing water‐wall of power plants from corroding.

Pitting inhibition efficiency of SO₄⁻ and NO₃⁻ on AISI 316L stainless steel in contact with Cl⁻-containing fiber dyeing solutions together with the influence of the anions on absorption behavior of the solutions were investigated. The purpose of the study is to experimentally determine an optimized dyeing solution efficient on both – inhibition of the steel’s pitting and exhaustion of the dyes dissolved.

Methods such as electrochemical cyclic polarization, UV-visible range spectrophotometry and scanning electron microscopy have been used to assess the performance of two inhibitors on both pitting inhibition of the steel and dissolving ability over the reactive dyes. To find out a promising dyeing solution mixture in both aspects, Cl content of the original dyeing solution was replaced gradually with the inhibiting anions, where the total anionic content was kept constant to unchange the dye exhaustion potential of the solution. Then, those solutions came out with diverse pitting inhibition, and dye absorption levels were compared together for reducing/avoiding the pitting issues of the reactive dyeing vessels of the industry.

Rather high absorption levels detected by visible range spectrophotometry on the solutions showing sound inhibition levels indicated possibility of unaltered reactive dyeing qualities with an enhanced vessel lifetime as the inhibitive anions replace Cl⁻. Nitrate performed better than sulfate both on inhibition and absorption in the dyeing solutions. Also, 316L vessels became open to an extra anodic protection in inhibitor added solutions.

The findings are valid for a certain group of reactive dyes and dyeing solutions held at 70°C. However, the testing methods are available to almost any dyeing solution and dyeing temperature.

The work presents a combined testing of pitting inhibition and absorption behavior of dyeing solutions involving Cl⁻ that has not been reported so far. It shows that solution recipes least harmful to the steel vessels can be outlined for various reactive or other types of dye groups.

The purpose of this investigation is to study the corrosion behavior of iron and aluminum in HCl and NaOH media by means of theoretical and experimental approaches.

For theoretical investigations, the quantum chemical calculation was performed. In this regard, the adsorption of OH⁻ and Cl⁻ on iron and aluminum surfaces was investigated. Furthermore, the natural bond orbital for the direction and magnitude of charge transfer interactions were calculated. In addition, the electrochemical evaluations based on potentiodynamic experiments were carried out.

The quantum chemical calculation results showed that the charge transfer from OH⁻ to the iron surface is more than that from Cl⁻, and also the charge transfer from Cl⁻ is more than that from OH⁻ to aluminum cluster. Furthermore, these anions donate more electrons to the iron cluster than to the aluminum cluster. The experimental data showed that the rate of corrosion of iron in 1.0M NaOH solution was less than in 1.0M HCl solution. The corrosion of aluminum in HCl solution was less than that in NaOH solution. The rate of corrosion of iron in both solutions was less than that of aluminum.

The findings of this paper indicate that calculations based on the natural bond orbital analysis of the charge transfer rates from OH⁻ and Cl⁻ to the iron or aluminum surfaces, and their comparison with experimental results, exhibited excellent agreement.

The purpose of this paper was to study the relationship between safe storage life and storage mode of hot-rolled sheet (Q235, X70) in humid environment, and a prediction model of safe storage life under different storage modes was established.

The corrosion behavior of hot-rolled sheets under different storage conditions was studied with immersion experiment and morphology observation.

The results show that pitting occurs on the hot-rolled sheets in humid environment, and the corrosion behavior is strongly related with the storage mode. When they are stored separately, the number and depth of pits first increase and then decrease as the Cl⁻ concentration rises, while for the stack storage, pit depth increases with increasing Cl⁻ concentration. The safe storage time of separate storage is longer than that of stack storage. Based on this, a model of chloride ion concentration and storage life was established.

A storage safe life model of hot-rolled sheet in humid environment is proposed.