Search results

To prepare semi‐synthetic oils satisfying the classification API SF/CC and SAE 10W30 from mineral base oils derived from high paraffinic petroleum, synthetic alkylbenzenes base oils, and suitable additives.

The mixtures of base mineral oils of deep hydro‐isomerization derived from high‐paraffinic petroleum (viscosity at 100°C is 12.5 cSt) and the mixtures of the synthetic alkyl aromatics oils with the naphthenic components (viscosity at 100°C of 8.0 cSt) were used as base oil. viscosity‐temperature properties, pour points, and flash points were modified by mixing of suitable additives. Octan M‐1, Octan M‐2, Octan M‐3, and Octan M‐4 oils were obtained by application of suitable additives into the prepared base oils B‐C. In order to get the SAE 10W30 requirements the viscous additive was added (0.4‐0.6 mass percent) to prepared base oils. For obtaining the API/SF/CC grade oils, package additive (Hitec 9229) additive was added (4.7 mass percent) to the mixture. The oil (Octan M‐1) was tested in the engine of Mercedes‐Benz model 230 car and positive results over 20,000 km running.

It was observed that, viscosities and pour points change linearly as the mass percent of alkylbenzenes the in the base oil mixture is changed. This realizes the possibility of the creation of semi‐synthetic motor oil of desired properties in the case of lack of other low‐viscosity synthetic component such as poly‐á‐olefins, diester and polyester oil. The obtained oils are useful for service in relatively mild climatic conditions (average temperature of the winter period −15 to −30°C).

The obtained oils cannot fully satisfy the requirements of the engines by pour point and low‐temperature characteristics in the absence of additives.

Because of complexity of obtained mixture, it was impossible to study the structure and composition of the obtained products by modern techniques such as high field NMR spectroscopy.

Details practical information on preparation of four semi‐synthetic oils satisfying the classification API SF/CC are reported.

This paper aims to experimentally investigate the film-forming capability of base oils containing poly-methacrylate (PMA) and poly-isobutene (PIB), in a point contact under pure rolling.

By using the relative light intensity method, the film thickness is calculated from the interferometer images which are captured by multiple-contact optical elastohydrodynamic lubricated test rig.

The test results reveal that polymers, both PMA and PIB, have a significant contribution to the film-forming capability of base oils and the film thickness increases with concentration. The forming-film capabilities for PMA and PIB in base oils are similar at low concentration, while PIB gives a higher film thickness than PMA at high concentration. Shear-thinning phenomenon are observed in all polymer-based oils.

The polymer usually as an additive is added into the low viscosity base oils to improve the properties of lubricant oil. This paper reports the lubricated properties of PMA and PIB with different concentrations in base oils and to evaluate their functional mechanism in a point contact.

The peer review history for this article is available at: https://publons.com/publon/10.1108/ILT-07-2020-0263/

The objective of this paper is to measure the differences in heat transfer properties of refined hydrocarbon distillate fractions that are commonly used as base oils in aluminium sheet cold rolling applications and assess if the heat transfer coefficient (HTC) values for these oils can be predicted from their compositions. The composition and physical properties of these fluids affect their tribological behaviour by influencing hydrodynamic lubrication, wear debris removal and cooling.

A purpose-built test rig was used to measure HTCs for a wide range of hydrocarbon solvents used as aluminium cold rolling oils. The results are expressed in the form of the HTCs relative to those of 14- to 16-carbon-chain-length normal paraffins. Measured HTC values were compared to values calculated from oil compositions and from the thermal conductivities of compounds representing different classes of typical oil components.

There were significant differences between the heat transfer properties of various hydrocarbon solvents, and these differences could be estimated from their content of normal and simple iso-paraffins and heavily branched and cyclic hydrocarbons. The HTC of hydrocarbon mixtures increases with the increasing content of n-paraffinic compounds.

This paper shows how one can estimate the relative HTCs of oils of known compositions, based on the relative thermal conductivities of model compounds. This is relevant to prediction of cooling properties of aluminium cold rolling base oils.

Additives are incorporated in engine oils to improve existing desirable properties of base stocks and to impart new specific properties required by modern engines. The additives include antioxidants, detergents, dispersants, corrosion and rust inhibitors, viscosity index improvers, pour point depressants, foam inhibitors and tribological agents. In this study, the effect of boron oil fortifier added into the base oil on friction coefficient and pressure distribution was investigated between sliding surfaces of engine journal bearings. Experiments were performed firstly using only base oil at different speeds and loads. Then, this test was repeated with different concentration ratio of 1, 3, 5 and 10 percent commercial boron additive.

This paper aims to provide a detailed review of various cutting fluids (CFs).

Friction and wear are inevitable in machine parts in motion. The industrial sector uses various kinds of lubricants, which include engine oils, CFs, hydraulic fluids, greases, etc. to control friction and wear. The main purpose of using CF is to remove heat produced during machining and to reduce cutting forces, tool wear and energy associated with it. Thus, it increases the productivity and quality of the manufacturing process. But more than 80% of the CFs used in the industries now are mineral oil-based. These mineral oils and additives are highly undesirable because of their toxicity, nonbiodegradability, pollution and ecological problems. Hence, these petroleum-based oils in the lubrication system can be substituted with alternatives such as vegetable-based CF. Several studies are being conducted in the field of eco-friendly CFs. Because of the variance in fatty acid profile and availability, the selection of vegetable oils (VOs) is another problem faced nowadays. The present study is focused on bio-based oils and many eco-friendly additives. Various machining processes and comparisons relating to the same have also been made. The aim is to minimize the use of mineral oil and thereby introduce sustainability in production.

In this present study, bio-based oils, additives and various characteristic behavior of them in machining are being discussed. The VOs are found to be a potential base oil for industrial CFs.

This paper describes the importance of sustainable CFs.

The purpose of this paper is to study a novel Mannich adduct of benztriazole-containing diphenylamine (coded as BD) and its anti-oxidation properties as an additive in two typical synthetic ester-based oils.

The anti-oxidation properties in two typical synthetic ester-based oils were evaluated in detail, using rotating pressure vessel oxidation test. The tribological properties of BD in synthetic ester-based oil (A51) were also tested with Optimal SRV-I oscillating friction and wear tester at atmosphere.

The results of tests demonstrated that the novel BD compound is, indeed, a high-performance anti-oxidation additive that was able to remarkably improve the oxidation stability of synthetic ester-based oils, when it was added at only 0.5 per cent concentration and compared with the base oils containing 0.5 per cent of the commercial available antioxidant additives such as 2, 6-di-tert-butyl-4-methylphenol and octyl-butyl diphenylamine. A plausible mechanism of exceptional synergistic anti-oxidation was proposed.

This paper first investigated the anti-oxidation properties and mechanisms of the compound with the structure of BD, which can be very useful and would promote the application of BD antioxidant in the lubricant industry.

This study aims to investigate the behavior of vegetable oil with two additives. Base oil’s tribological qualities can be improved with the help of several additions. In the present investigation, soybean oil is served as the foundational oil due to its eco-friendliness and status as a vegetable oil with two additives, named polytetrafluoroethylene (PTFE) and molybdenum disulfide (MoS₂).

As additives, PTFE and MoS₂ are used; PTFE is renowned for its anti-friction (AF) properties, while MoS₂ is a solid lubricant with anti-wear (AW) properties. This investigation examines the synergistic impact of AF and AW additions in vegetable oil. The lubricity of the base oil is measured by using a four-ball tester, and the wear properties of the oil at different additive amounts are determined by using a universal tribometer.

PTFE (at 5 Wt.%) and MoS₂ (at 1 Wt.%) were found to improve the tribological performance of the base oil. The weld load is significantly increased when 5 Wt.% of PTFE + MoS₂ is added to the base oil.

A better tribological characteristic can be achieved by combining additives that amount to less than 1% of the base oil. In experiments with highly concentrated MoS₂, the adequate pressure improved dramatically, but the lubricant’s tribological characteristics did not.

The peer review history for this article is available at: https://publons.com/publon/10.1108/ILT-11-2022-0321/

Formulation of mineral-based specialty lubricants without anti-wear (AW) and extreme-pressure (EP) additives is a challenging task. This study aims to propose an environment friendly alternative to mineral-based lubricants with superior wear preventive characteristics.

In this study, analysis of wear under trimethylolpropane trioleate (TMPTO)-based lube using operating parameters of four-ball tester was done. The effects of type of lube oil, temperature, load and speed on specific wear rate were investigated using Taguchi L27 orthogonal array. Based on the Taguchi experimental results and single-to-noise ratios, ranking of the four ball parameters was done. The surface analysis of worn steel balls was carried out using optical microscopic images of wear scar and energy dispersive spectrometry (EDS).

Results depict that the blend of sulfurized additives with TMPTO base oil showed a synergistic effect in terms of reduction in specific wear rate by the formation of protective film layer on the surface. The possible physical or chemical interactions between base oil and additives were studied based on the surface morphology of test balls.

The formulated lubricant has the potential to be used as a tapping/broaching oil.

To the best of the authors’ knowledge, the paper is a novel study investigating the effect of different additive in TMPTO. The results could prove beneficial in making TMPTO-based lube oil a viable replacement of mineral-based oils.

The purpose of this study is to investigate the tribological properties of tetrahedral diamond-like carbon (DLC) films in self-mated contacts in the presence of additivated and non-additivated vegetable oils. DLC films have high practical value due to low friction and low wear properties. On the other hand, vegetable oils are considered to be lubricants for future due to its resource renewability and biodegradability. Sometimes different chemical agents are added to vegetable oils to further improve its tribological properties. Thus, the tribological study of DLC films against additivated oils becomes important.

The tribology tests were conducted in a four ball tribo-meter under the boundary lubricated conditions.

Ta-C DLC exhibited 80 per cent lower wear rate under Zinc dialkyldithiophosphates (ZDDP)-added oil compared to that of base oil. In contrast, the friction coefficient under additivated oil was slightly higher than the base oil lubricated case. Moreover, the carbonyl band area as well as the viscosity change of ZDDP-added oil was much smaller than that of base oil. Therefore, ZDDP reduced the wear of DLC film and prevented the oxidation of base oil during tribotests.

This is the first work on the tribological properties of ta-C DLC lubricated with corn oil with and without anti-wear additives.

The screening of lube oil performance prior to field trials is the most significant for the formulation of novel lubricants. This paper aims to investigate the efficacy of trimethylolpropane trioleate oil (TMPTO) based lubricants with different additives.

In this endeavor, initially five lubricating blends along-with TMPTO based oil with variable additives were evaluated for their tribological performances using ASTM standards. Out of these, the top three best-performing oils were further investigated for possible physical or chemical synergies among lube oils, additives and ball surface using SEM. The molecule structures of TMPTO based lube oils were confirmed using Fourier transform infrared spectroscopy (FTIR).

The wear preventive and extreme pressure characteristics of different TMPTO based samples were evaluated and compared for compatibility and synergy of additives. Morphological analysis of SEM images was used to understand the wear behavior of the worn surfaces.

Further investigation of TMPTO oil on its oxidation stability at high temperature and pressure to make it technologically competitive and commercially viable metal-working lubricant is suggested.

This paper highlights the tribo-effects of TMPTO to be rendered as a suitable lubricant for metal-cutting operations. The surface morphology of the worn-out surface significantly demonstrates the effect of loading conditions.