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A chromate conversion coating was prepared on the surface of bare AA2024 aluminum alloy by direct immersion in the chromating treatment bath, and the corrosion behavior of chromated AA2024 aluminum alloy in 3.5 per cent NaCl solution was studied by electrochemical measurement and microstructural observation.

According to the polarization curve test and the scanning electron microscope observation, the corrosion evolution of chromated AA2024 in 3.5 per cent NaCl solution was divided into the following three stages: coating failure, pitting corrosion and intergranular corrosion (IGC).

In the first stage, the chromate coating degraded gradually due to the combined action of chloride anions and water molecules, resulting in the complete exposure of AA2024 substrate to 3.5 per cent NaCl solution. Subsequently, in the second stage, chloride anions adsorbed at the sites of θ phase (Al2Cu) and S phase (Al2CuMg) on the AA2024 surface preferentially, and some corrosion pits initiated at the above two sites and propagated towards the deep of crystal grains. However, the propagation of a pit terminated when the pit front arrived at the adjacent grain boundary, where the initiation of IGC occurred.

Finally, in the third stage, the corrosion proceeded along the continuous grain boundary net and penetrated the internal of AA2024 substrate, resulting in the propagation of IGC. The related corrosion mechanisms for the bare and the chromated AA2024 were also discussed.

The purpose of this paper is to present the results of an atomic force microscopy (AFM) based approach to local impedance spectroscopy (LIS) measurement performed on AA2024 and AA2024‐T3 aluminium alloys.

AFM‐LIS measurements were performed ex‐situ without the electrolyte environment, so in fact the electrical not electrochemical impedance was obtained.

Relative local impedance values recorded for AA2024 alloy during the researches carried out were maximally approximately three orders of magnitude higher than the ones obtained for age‐hardened AA2024‐T3 alloy. Moreover, in the case of AA2024‐T3 alloy, a region located in the interior of α crystals exhibited localized impedance one order of magnitude higher than that measured at its grain boundary when affected by intergranular corrosion.

The paper presents differences in localized impedance between grain and grain boundaries activity.

Modeling of material behavior by physically or microstructure-based models helps in understanding the relationships between its properties and microstructure. However, the majority of the numerical investigations on the prediction of the deformation behavior of AA2024 alloy are limited to the use of phenomenological or empirical constitutive models, which fail to take into account the actual microscopic-level mechanisms (i.e. crystallographic slip) causing plastic deformation. In order to achieve accurate predictions, the microstructure-based constitutive models involving the underlying physical deformation mechanisms are more reliable. Therefore, the aim of this work is to predict the mechanical response of AA2024-T3 alloy subjected to uniaxial tension at different strain rates, using a dislocation density-based crystal plasticity model in conjunction with computational homogenization.

A dislocation density-based crystal plasticity (CP) model along with computational homogenization is presented here for predicting the mechanical behavior of aluminium alloy AA2024-T3 under uniaxial tension at different strain rates. A representative volume element (RVE) containing 400 grains subjected to periodic boundary conditions has been used for simulations. The effect of mesh discretization on the mechanical response is investigated by considering different meshing resolutions for the RVE. Material parameters of the CP model have been calibrated by fitting the experimental data. Along with the CP model, Johnson–Cook (JC) model is also used for examining the stress-strain behavior of the alloy at various strain rates. Validation of the predictions of CP and JC models is done with the experimental results where the CP model has more accurately captured the deformation behavior of the aluminium alloy.

The CP model is able to predict the mechanical response of AA2024-T3 alloy over a wide range of strain rates with a single set of material parameters. Furthermore, it is observed that the inhomogeneity in stress-strain fields at the grain level is linked to both the orientation of the grains as well as their interactions with one another. The flow and hardening rule parameters influencing the stress-strain curve and capturing the strain rate dependency are also identified.

Computational homogenization-based CP modeling and simulation of deformation behavior of polycrystalline alloy AA2024-T3 alloy at various strain rates is not available in the literature. Therefore, the present computational homogenization-based CP model can be used for predicting the deformation behavior of AA2024-T3 alloy more accurately at both micro and macro scales, under different strain rates.

The purpose of this paper was to study the corrosion resistance of AA2024 alloy using surfactant-modified halloysite nanocapsules capable of holding benzotriazole (BTA) as the corrosion inhibitor and discharging it into the solution.

The effect of surfactant shells was studied by surfactant-modified halloysite nanotubes fabricated through assembly of two types of cationic surfactants. The zeta potential and size distribution measurements were performed using a Zetasizer Nano. The concentration of BTA during release into the solution was detected by using a UV–vis spectrophotometer. The anti-corrosion activity of nanocapsules as free agents with respect to the AA2024 alloy was investigated using the potentiodynamic scan (PDS) method. An epoxy resin doped with nanocapsules was used as an anti-corrosion coating deposited on the AA2024 alloy. The corrosion protection performance of coatings was studied by using the electrochemical impedance spectroscopy (EIS) method.

The results indicate that the release of the inhibitor from nanocapsules depends on the surfactant shell components. The PDS results confirmed the feasibility of developing “smart” corrosion protection by inhibitor-loaded nanocapsules. The results of EIS measurements showed that the coating with the nanocapsules exhibited enhanced corrosion protection in comparison with the undoped coating.

The findings of this paper indicate that surfactant-modified halloysite nanocapsules can be added to epoxy resin coatings to improve their corrosion protective properties for the AA2024 alloy.

The purpose of this paper was to study the corrosion resistance of water-based sol-gel coatings containing titania nanoparticles doped with organic inhibitors for corrosion protection of AA2024 alloy.

The coatings were obtained using tetraethylorthosilicate, 3-glycidoxypropyltrimethoxysilane, titanium (IV) tetrapropoxide and poly(ethylene imine) polymer as cross-linking agents. As corrosions inhibitors, 2-mercaptobenzoxazole and salicylaldoxime were incorporated into the sol-gel for the improvement of the corrosion resistance. The corrosion protection performance of coatings was studied using the potentiodynamic scan and the electrochemical impedance spectroscopy (EIS) methods. Atomic force microscopy was used to investigate surface morphology of the coatings.

The results indicated that doping the sol-gel coatings with inhibitors leads to improvement of the corrosion protection. The comparison of doped coatings confirmed that corrosion protection performance of the sol-gel coatings doped with 2-mercaptobenzoxazole was better than for the sol-gel coatings doped with salicylaldoxime. Also the EIS results verified self-healing effects for the sol-gel coatings doped with 2-mercaptobenzoxazole.

This paper indicates 2-mercaptobenzoxazole and salicylaldoxime can be added as corrosion inhibitors to sol-gel coatings to improve their corrosion protective properties for AA2024 alloy.

This paper aims to evaluate the validity of bilinear hardening model to represent the stress flow of high-pressure torsion (HPT)-strengthened lightweight material, AA2024.

Finite-element HPT simulation was performed by applying a simultaneous prescribed displacement on the axial and rotational axis that is equivalent to 4 GPa pressure and 30° torsion. The material behaviour incorporates plasticity attributes with a bilinear constitutive equation that consists of elastic and tangent modulus.

As a result, the von Mises stress generated from the simulation is in good agreement with the experiment, indicating that the assumptions of plasticity properties applied for the FEM simulation model are acceptable. The model verification confirms the anticipated plasticity parameters’ effect on the generated von Mises stress. The disc centre also evidenced an insignificant stress increment due to the limited shear straining.

A reliable hardening model would assist in understanding the stress flow associated with mechanical properties enhancement.

The bilinear hardening model exhibits a satisfactory stress estimation. It simplifies the ideal strain variable hardening procedures and lessens the total computation time that is valuable in solving severe plastic deformation problems.

An integration of well-defined input parameters, concerning the hardening behaviour and the plasticity properties, contributes to the establishment of a validated HPT simulation model, particularly for AA2024. This study also proved that perfectly plastic behaviour is inappropriate to represent hardening in the HPT-strengthened materials due to the remarkable stress deviation from the experimental data.

One of the challenges in the prediction of fatigue crack growth is to identify representative initial flaws and defects that can cause fatigue crack initiation and subsequent crack growth. Representative initial flaws identified from this experimental study provided an essential input for the fatigue life assessment programme of the PC-9/A training aircraft currently in service. The paper aims to discuss these issues.

This paper addresses this challenge with a critical literature review and experimental assessment of initial flaw types that may cause fatigue crack initiation, by fatigue testing and fractography analysis using optical microscope and scanning electron microscopy (SEM).

With a focus on aluminium alloy (AA) 2024-T3 thin sheet, the results cover various discontinuities from microstructural constituent particles inherent from the material process to macrostructural defects and surface discontinuities (such as burrs and machining marks) introduced during the production of airframes. It was found that most fatigue cracks originated from the bore surface discontinuities of rivet holes in the PC-9 vertical stabiliser thin panels rather than microstructural material defects of AA2024-T3 inherent from the material process.

The experimental study has found that quantifying fatigue initial flaw sizes which resulted from poorly finished fastener holes with arbitrary discontinuities at the surface is a challenging topic. This topic is under the current investigation using a statistics based analysis of initial flaws in the prediction of fatigue crack growth.

The results obtained from this experimental study provided an essential input for the empennage and aft fuselage recertification and life assessment programme for the PC-9/A training aircraft currently in service.

This experimental study examined AA2024-T3 thin skin panels from two different PC-9/A aircraft. The post-test failure analysis using optical microscope and SEM found that machining defects dominate fatigue crack initiation that can result in subsequent crack propagation.

This paper aims to monitor, evaluate and adjust the joint quality of dissimilar friction stir welded AA2024-T3 and AA7075-T6 Al alloys.

Taguchi analysis for design of experiments and ANOVA analysis were applied. Tensile test, visual inspection and macro and microstructure investigations were carried out at each welding condition. In addition, the grain size of stir zone and the value of heat input were measured.

Using Taguchi analysis, the optimum values of tool rotary speed, welding speed and axial load were 1,200 rpm, 100 mm/min and 1,300 kg, respectively, yielding the maximum tensile strength of the joints of 427 MPa. ANOVA analysis indicated that the most significant parameter on the joint strength is the tool rotary speed, followed by welding speed and axial load, with contributions of 67, 27 and 2 per cent, respectively. Best mixing between Al alloys in the stir zone with no defects was observed at moderate speeds because of proper heat input and grain size, resulting in high strength.

A relation between structure characteristics of the joint, the process parameters and the joint strength was established to control the joint quality.

This paper aims to improve the anti-corrosive properties of aluminum alloy AA2024-T3 by coating of hybrid sol-gel coating incorporated with TiO₂ nanosheets and to investigate the effect of nanosheets’ size on the improvement of corrosion-resistant performance.

A series of hybrid sol-gel films incorporated with varying amounts of TiO2 nanosheets were developed to enhance the corrosion protection performance of the bare metal. Scanning electron microscopy, transmission electron microscopy and atomic force microscopy were used to investigate the structure and morphology of the coatings obtained. In addition, the corrosion-resistant properties of the coatings were evaluated using salt spray test and electrochemical impedance spectroscopy.

The corrosion current was as low as 9.55 × 10-4 µA/cm² and optimal positive corrosion potential reached −0.6 V when the size and loading amount of TiO₂ nanosheet were optimized, resulting in a remarkable improvement in anti-corrosive properties.

This work first investigates the effect of incorporation of TiO₂ nanoparticles on hybrid sol-gel coating on the improvement of anti-corrosive performance of aluminum alloy AA2024-T3.

The purpose of this paper is to deal with the study of properties of anticorrosion powder based coatings on aluminium alloy 2024.

The powder based coatings were applied to the AA2024 substrates using a spray coating technique. All the substrates were covered with a primer prior the powder based coatings. The morphology and composition of the coatings was examined by scanning electron microscopy and energy dispersive X-ray analysis, respectively. Studies on the corrosion resistance of these coatings were made using electrochemical impedance spectroscopy.

The results reveal that the powder based coatings together with the primer coatings demonstrate improved corrosion protection to AA2024 after exposure to corrosive environment. Moreover, the primer coating is mechanically enhanced compared to the top coating, while the top coating exhibited significant resistance to wear.

The paper deals with the evaluation of corrosion and nanomechanical properties of coatings applied on aluminium alloy.