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1 – 4 of 4Rozanna Dewi, Nasrun Ibrahim, Novi Sylvia, Dahlan Abdullah and Medyan Riza
Purpose – The purpose of this research is to synthesize modified thermoplastic sago starch (TPS) through in-situ mechanism by reacting sago starch with diphenylmethanediisocyanate…
Abstract
Purpose – The purpose of this research is to synthesize modified thermoplastic sago starch (TPS) through in-situ mechanism by reacting sago starch with diphenylmethanediisocyanate (MDI) and castor oil simultaneously, resulting in a more homogenous and finer-sized polyurethane prepolymer (PUP).
Design/Methodology/Approach – The methods used were Thermal Gravimetric Analysis (TGA) and Differential Scanning Calorimetry (DSC) for thermal characterization and stability of PUP, modified TPS non-extracted and extracted with toluene and water.
Findings – TGA test results presented shows that PUP begins to decompose thermally at a temperature of 300–500 °C. Weight loss occurs rapidly between these temperatures and is completely discharged at a temperature of 500°C, which is called weight loss transition.
Research Limitations/Implications – When extracted with toluene and a water solvent, the melting point and latent heat of fusion slightly decreased; however, it is still higher than the original value of sago. In terms of thermal stability, modified TPS decomposes and loses weight at 150–200 °C in small quantities, continues with weight loss rapidly, and is completely discharged at 500°C. The thermal stability is considered high; thus, modified TPS application can be varied.
Practical Implications – DSC analysis and TGA shows that modified TPS has good thermal characteristics and thermal stability. Modified TPS has a melting point of 104.69°C, and the latent heat of fusion (ΔH) is 234.27 J/g. This value is close to the PUP melting point and latent heat of fusion, which reveals the formation of cross-link between the starch and PUP.
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Danusa Silva da Costa, Lucely Nogueira dos Santos, Nelson Rosa Ferreira, Katiuchia Pereira Takeuchi and Alessandra Santos Lopes
The aim was not to perform a systematic review but firstly to search in PubMed, Science Direct, Scopus and Web of Science databases on the papers published in the last five years…
Abstract
Purpose
The aim was not to perform a systematic review but firstly to search in PubMed, Science Direct, Scopus and Web of Science databases on the papers published in the last five years using tools for reviewing the statement of preferred information item for systematic reviews without focusing on a randomized analysis and secondly to perform a bibliometric analysis on the properties of films and coatings added of tocopherol for food packaging.
Design/methodology/approach
On January 24, 2022, information was sought on the properties of films and coatings added of tocopherol for use as food packaging published in PubMed, Science Direct, Scopus and Web of Science databases. Further analysis was performed using bibliometric indicators with the VOSviewer tool.
Findings
The searches returned 33 studies concerning the properties of films and coatings added of tocopherol for food packaging, which were analyzed together for a better understanding of the results. Data analysis using the VOSviewer tool allowed a better visualization and exploration of these words and the development of maps that showed the main links between the publications.
Originality/value
In the area of food science and technology, the development of polymers capable of promoting the extension of the shelf life of food products is sought, so the knowledge of the properties is vital for this research area since combining a biodegradable polymeric material with a natural antioxidant active is of great interest for modern society since they associate environmental preservation with food preservation.
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N. Dhanunjayarao Borra and Venkata Swamy Naidu Neigapula
The tear strength (Ts) is a significant property for any kind of soft polymeric material such as rubber, elastomer, viscoelastic material and its composites, to quantify the…
Abstract
Purpose
The tear strength (Ts) is a significant property for any kind of soft polymeric material such as rubber, elastomer, viscoelastic material and its composites, to quantify the suitability of a material for any shape memory applications. Many times, the soft elastomeric polymer material has to be capable enough to deform to a maximum extent of displacement but at the same time, it has to withstand the maximum load without fail. Along with shape recovery properties (i.e. the ability to recover its shape from programmed to the original), the success of the shape memory cycle is mainly depending on its stiffness and strength. It has to resist tear during stretching (i.e. programming stage) as repeatedly subjected to deformation, and, hence, it is important to study the tear behaviour for shape memory polymers (SMPs) and their composites. The purpose of the work is to investigate the effect of parameters on Ts of 4D printed specimen using Taguchi method.
Design/methodology/approach
The objective of the work is to tailor the Ts of SMPs by reinforcing the graphene nano particles (GNPs) in a blended photopolymer (PP) resin with flexible PP and hard PP resin. In this study, a total of nine experiments were designed based on the L9 orthogonal array (OA) using the design of experiments (DOEs). All the shape memory photopolymer composite’s (SMPPCs) specimens are fabricated using masked stereolithography (MSLA), also known as resin three-dimensional printing (R3DP) technique.
Findings
Specimens are tested using universal testing machine (UTM) for maximum tear force (Fmax) and displacement (δ) caused by tearing the specimen to evaluate the strength against the tear. The results showed that the Wt.% of resin blend highly influenced both Fmax and δ, while GNPs also had an impact on δ. The specimens are offering more tear resistance for those specimens blended with less Wt.% of flexible PP at the same time the specimens enable more δ for those specimens reinforced with 0.3 Wt.% GNPs at 10-s exposure time. The optimum combinations are A1, B1 and C3 for the Fmax and Ts and at the same time A1, B3 and C3 for δ.
Research limitations/implications
To customise the tear resistance of SMPPCs using MSLA 3 D printing, this study suggested a blend of PP resins reinforced with GNPs. This opens up a new path for creating novel, inexpensive multi-functional 4-dimensional (4D) printed parts.
Originality/value
The use of flexible PP and hard PP resin blends, fabricating the SMPPCs specimens using 3 D printed MSLA technology, investigating the effect of GNPs, resin blend and exposure time, optimizing the process parameters using Taguchi and the work were all validated using confirmation tests and regression analysis using test train method, which increases the originality and novelty.
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