Effect of GNPs and resin blend on tear resistance of 4D printed shape memory photopolymer composite

Abstract

Purpose

The tear strength (Ts) is a significant property for any kind of soft polymeric material such as rubber, elastomer, viscoelastic material and its composites, to quantify the suitability of a material for any shape memory applications. Many times, the soft elastomeric polymer material has to be capable enough to deform to a maximum extent of displacement but at the same time, it has to withstand the maximum load without fail. Along with shape recovery properties (i.e. the ability to recover its shape from programmed to the original), the success of the shape memory cycle is mainly depending on its stiffness and strength. It has to resist tear during stretching (i.e. programming stage) as repeatedly subjected to deformation, and, hence, it is important to study the tear behaviour for shape memory polymers (SMPs) and their composites. The purpose of the work is to investigate the effect of parameters on Ts of 4D printed specimen using Taguchi method.

Design/methodology/approach

The objective of the work is to tailor the Ts of SMPs by reinforcing the graphene nano particles (GNPs) in a blended photopolymer (PP) resin with flexible PP and hard PP resin. In this study, a total of nine experiments were designed based on the L9 orthogonal array (OA) using the design of experiments (DOEs). All the shape memory photopolymer composite’s (SMPPCs) specimens are fabricated using masked stereolithography (MSLA), also known as resin three-dimensional printing (R3DP) technique.

Findings

Specimens are tested using universal testing machine (UTM) for maximum tear force (F_max) and displacement (δ) caused by tearing the specimen to evaluate the strength against the tear. The results showed that the Wt.% of resin blend highly influenced both F_max and δ, while GNPs also had an impact on δ. The specimens are offering more tear resistance for those specimens blended with less Wt.% of flexible PP at the same time the specimens enable more δ for those specimens reinforced with 0.3 Wt.% GNPs at 10-s exposure time. The optimum combinations are A1, B1 and C3 for the F_max and T_s and at the same time A1, B3 and C3 for δ.

Research limitations/implications

To customise the tear resistance of SMPPCs using MSLA 3 D printing, this study suggested a blend of PP resins reinforced with GNPs. This opens up a new path for creating novel, inexpensive multi-functional 4-dimensional (4D) printed parts.

Originality/value

The use of flexible PP and hard PP resin blends, fabricating the SMPPCs specimens using 3 D printed MSLA technology, investigating the effect of GNPs, resin blend and exposure time, optimizing the process parameters using Taguchi and the work were all validated using confirmation tests and regression analysis using test train method, which increases the originality and novelty.

Citation

Borra, N.D. and Neigapula, V.S.N. (2023), "Effect of GNPs and resin blend on tear resistance of 4D printed shape memory photopolymer composite", Rapid Prototyping Journal, Vol. 29 No. 6, pp. 1138-1154. https://doi.org/10.1108/RPJ-10-2022-0352