Search results

The purpose of this study is to investigate the thermomechanical condition on the shape memory property of Polybutylene adipate-co-terephthalate (PBAT). PBAT is a widely researched and rapidly developed biodegradable copolyester. In a tensile test, we found that the fractured PBAT samples had a heat-driven shape memory effect which piqued our interest, and it will lay a foundation for the application of PBAT in new fields (such as heat shrinkable film).

The shape memory effect of PBAT and the effect of the thermomechanical condition on its shape memory property were confirmed and systematically investigated by a thermal mechanical analyzer and tensile machine.

The results showed that the PBAT film had broad shape memory transform temperature and exhibited excellent thermomechanical stability and shape memory properties. The shape memory fixity ratio (Rf) of the PBAT films was increased with the prestrain temperature and prestrain, where the highest Rf exceeded 90%. The shape memory recovery ratio (Rr) of the PBAT films was increased with the shape memory recovery temperature and decreased with the prestrain value, and the highest Rr was almost 100%. Moreover, the PBAT films had high shape memory recovery stress which increased with the prestrain value and decreased with the prestrain temperature, and the highest shape memory recovery stress can reach 7.73 MPa.

The results showed that PBAT had a broad shape memory transform temperature, exhibited excellent thermomechanical stability and shape memory performance, especially for the sample programmed at high temperature and had a larger prestrian, which will provide a reference for the design, processing and application of PBAT-based heat shrinkable film and smart materials.

This study confirmed and systematically investigated the shape memory effect of PBAT and the effect of the thermomechanical condition on the shape memory property of PBAT.

The purpose of this study is to assess the influence of Al and Ag addition on thermal, mechanical and shape memory properties of Cu-Al-Ag alloy.

The material is synthesized in a controlled atmosphere to minimize the reaction of alloying elements with the atmosphere. Cast samples were homogenized, then subjected to hot rolling and further betatized, followed by step quenching. Eight samples were chosen for study among which first four samples varied in Al content, and the next set of four samples varied in Ag composition.

The testing yielded a result that the increase in binary alloying element decreased transformation temperature range but increased entropy and elastic energy values. It also improved the shape memory effect and mechanical properties (UTS and hardness). An increase in ternary alloying element increased transformation temperature range, entropy and elastic energy values. The shape memory effect and mechanical properties are enhanced by the increase in ternary alloying element. The study revealed that compositional variation of Al should be limited to a range of 8 to 14 Wt.% and Ag from 2 to 8 Wt.%. Microstructural and diffraction studies identified the ß’1 martensite as a desirable phase for enhancing shape memory properties.

Numerous studies have been made in exploring the transformation temperature and phase formation for similar Cu-Al-Ag shape memory alloys, but their influence on shape memory effect was not extensively studied. In the present work, the influence of Al and Ag content on shape memory characteristics is carried out to increase the design choice for engineering applications of shape memory alloy. These materials exhibit mechanical and shape memory properties within operating ranges similar to other copper-based shape memory alloys.

The purpose of this paper is to understand the recovery mechanism of poly(trimethylene terephthalate) (PTT) shape memory fabrics.

Tests were designed to study the effects of force, temperature and their combinations on the fabrics' crease recoveries. In the test a cantilever device and an ironing force which simulated people ironing their clothes were used, respectively.

Temperature was found to have little effect on the recovery of both the warp and filling of the fabrics. Crease recoveries did not improve significantly when the temperature was increased to above the polymer's glass transition. However, forces, applied in primarily compressive and tensile modes to simulate ironing and hand stroking actions, were found to be very effective in the fabrics' crease recoveries. Recoveries were 81‐87 per cent even when the applied force was very small, at 5 N/cm². When forces were applied at elevated temperatures, just below and above the polymer's glass transition, there were no significant improvements in crease recoveries. Therefore, force was the main factor in PTT shape memory fabrics' recovery mechanism for the fabrics to return to their initial shapes.

The results suggest that PTT shape memory fabric has excellent shape recoverability and easy care property and it has large application potentiality.

Shape memory alloys are a fascinating class of materials because they combine both structural and functional properties. These properties strongly depend on temperature. One consequence of this dependency yields the characteristic shape‐memory effect: shape memory alloys can recover processed reference configurations after significant plastic deformations simply upon a change of temperature. For real materials, such processes incorporate characteristic hysteresis. This paper aims at an understanding of these materials from an atomistic point of view.

2D molecular‐dynamics (MD) simulations describing a chain consisting of 32 linked Lennard‐Jones crystals are presented. The crystals consist of nested lattices of two atom species. Distinct lattice structures can be identified, interpreted as austenite and (variants of) martensite. Temperature and/or load‐induced phase transitions between these configurations are observed in MD simulations. Previously, the thermal equation of state of one isolated crystal was investigated and its phase stability was discussed in detail. In the multi‐crystal chain considered in the present paper, individual crystals contribute collectively to the thermo‐mechanical behavior of the assembly.

The paper presents the results of numerical experiments with this polycrystalline chain under strain‐, load‐ and/or temperature‐control. The results show that with the assumption of simple Lennard‐Jones potentials of interaction between atoms in individual crystals and linking these crystals allows to reproduce the features associated with the fascinating behavior of shape memory alloys, including pseudo‐plasticity, pseudo‐elasticity and the shape memory effect.

Owing to the special setup chosen, interfaces are missing between adjacent crystals in the chain assembly. The paper shows that in this situation load‐induced austenite/martensite transitions do not exhibit hysteresis in tension/compression cycles. This observation indirectly supports mesoscopic‐level work in the literature which explicitly introduces interface energy to model such hysteresis.

The purpose of this paper is to investigate the thermoelastic interactions in a homogeneous, transversely isotropic infinite medium with a spherical cavity in the context of two temperature Lord-Shulman (2TLS) generalized theory of thermoelasticity considering Eringen’s nonlocal theory and memory dependent derivative (MDD). Memory-dependent derivative is found to be better than fractional calculus for reflecting the memory effect which leads us to the current investigation.

The governing field equations of the problem are solved analytically using the eigenvalue approach in the transformed domain of Laplace when the cavity’s boundary is being loaded thermomechanically. Using MATLAB software the numerical solution in real space-time domain is obtained by Stehfest method.

Numerical results for the different thermophysical quantities are presented in graphs and the effects of delay time parameter, non-local parameter and two temperature parameters are studied thereafter. The outcomes of this study convince that the displacement u, conductive temperature ϕ, thermodynamic temperature θ are concave upward whereas radial stress τ_rr is concave downward for every choice of delay time parameter ω, two temperature parameter η and non-local parameter “ζ”. As a specific instance of our findings, the conclusions of an equivalent problem involving integer order thermoelasticity theory can be obtained, and the corresponding results of this article can be readily inferred for isotropic materials.

The novelty of this research lies in the adoption of generalized thermoelastic theory with memory dependent derivative and Eringen’s nonlocality for analyzing the thermoelastic interactions in an infinite body with spherical cavity by employing eigenvalue approach. It has applications to many thermo-dynamical systems.

Human performance, particularly that of the warfighter, has been the subject of a large amount of research during the past few decades. For example, in the Medline database of medical and psychological research, 1,061 papers had been published on the topic of “military performance” as of October 2003. Because warfighters are often pushed to physiological and mental extremes, a study of their performance provides a unique glimpse of the interplay of a wide variety of intrinsic and extrinsic factors on the functioning of the human brain and body. Unfortunately, it has proven very difficult to build performance models that can adequately incorporate the myriad of physiological, medical, social, and cognitive factors that influence behavior in extreme conditions. The chief purpose of this chapter is to provide a neurobiological (neurochemical) framework for building and integrating warfighter performance models in the physiological, medical, social, and cognitive areas. This framework should be relevant to all other professionals who routinely operate in extreme environments. The secondary purpose of this chapter is to recommend various performance metrics that can be linked to specific neurochemical states and can accordingly strengthen and extend the scope of the neurochemical model.

The purpose of this paper is to evaluate the influence of layer thickness and post-curing temperature on shape memory properties in components manufactured by stereolithography.

Layer thicknesses of 20 and 100 µm and 22 and 45°C for post-curing temperature were selected following the design of experiments approach. Tensile and bending tests were applied for quantitative evaluation of the shape memory effect (SME). Qualitative analysis was performed using complex geometries and computed tomography as a measurement tool. Additionally, the degree of photopolymerization and glass transition temperature (T_g) were evaluated.

The tensile test resulted in fixity and recovery ratio values close to 100%. In bending, they varied between 97%–111% for fixity and 88%–95% for recovery. The layer thickness was found to have a higher influence on the SME. In complex structures, SME was dependent on geometry and less sensitive to variation in process parameters. The post-curing temperature had a higher influence on the photopolymerization and T_g. Average T_g of 77.5°C was achieved at 45°C, compared to 73.1°C at 22°C.

In the current state of the art in the processing of shape memory polymers with vat photopolymerization typically, the chemical composition or the thermal and deformation patterns are studied. The effect of the processing parameters is, however, not explored. This paper aims to close the research gap and facilitate the process optimization towards high fixing and recovery characteristics.

The purpose of this paper is to present short characteristics of shape memory alloys (SMA) and shape memory polymers (SMP) and some examples of application of these materials in industrial sealing technology.

In this paper, short characteristic of shape memory materials and design examples of applying them in industrial sealing technology such as: tube coupling in hydraulic systems, flanged pipe connections, lip radial seal, mechanical face seal, soft gland packing, magnetic fluid seal, and in bearing seal system for drill bit, are given.

The paper provides information about innovative fluid seal designs based on particular properties of the shape memory materials, applied in stationary joints, and rotary equipments. These new solutions provide often to simplify seal design, their miniaturization, increase of tightness, and reduction of operating costs.

This paper offers some new fluid seal designs based on the shape memory materials and their practical application in industrial sealing technology.

The purpose of this paper is to present numerical studies on thermally induced vibrations of piezo‐thermo‐viscoelastic composite beam subjected to a transient thermal load using coupled finite element method.

The thermal relaxation and viscoelastic relaxations are taken into consideration to obtain the system response. The concept of “memory load” along with the thermal relaxation is accounted for viscoelastic core material. The influence of type of core material on the response of the system also analyzed.

The findings show viscoelastic behavior with relaxation times in composite sandwich structures.

The paper shows accounting relaxation times as a memory load in composite sandwich structures.

This paper aims to examine customized NiTi jewels with functional properties fabricated through four-dimensional (4D)-printing.

Two opened rings are fabricated through selective laser melting starting from 55.2Ni-Ti (wt.%) micrometric powder. After the additive process the two rings present the one-way shape memory effect (OWSME). A specific training is accomplished on one of the two printed rings to promote the two-way shape memory effect (TWSME). Both the samples, namely, the rings, respectively, presenting the OWSME and TWSME property, follow a series of post-processing routes to improve the surface finish. Furthermore, a thermal treatment at high temperature is used to create a thin colored oxide layer on the sample surface.

Results show that the change of shape owing to the OWSME and TWSME properties allows the customized 4D-printed rings to be adaptable to environmental changes such as load and temperature variations. This adaptability improves comfort and fit of the jewels.

To the best of the authors’ knowledge, in this work, first cases of additively manufactured NiTi jewels are reported to propose innovative solutions in the design and processing industry of jewels.