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Many of the industrially important processes follow a complex reaction scheme and more than one reaction takes place simultaneously for these systems. Design and scale up of these processes are important but due to the nature of the system and high numbers of the affected parameters, modeling of the complex reactions becomes correspondingly difficult. The purpose of this paper is to develop a general model, which can simplify modeling of such (or similar) complex reactions.

Virtual model is a generalized novel approach for modeling of these complex reactions. In this model, the complex reactions have been imagined as a simple reaction. Now, kinetic and structural parameters of this simple reaction have been obtained by fitting the model relationships with the experimental data.

In this work, the ability of the virtual model has been validated using the experimental data pertinent to the reduction of molybdenum disulfide and cuprous sulfide by hydrogen in the presence of lime.

Virtual model is a generalized novel approach for modeling of these complex reactions. In this model, the complex reactions have been imagined as a simple reaction.

Natural convection in finite enclosures is a common phenomenon in various thermal applications. To provide the thermal design guidelines, this study aims to numerically explore the potential of using internal baffles and nanofluids to either enhance or suppress heat transport in a vertical annulus. Furthermore, the annular-shaped enclosure is filled with aqueous-silver nanofluid and the effects of five distinct nanoparticle shapes are examined. In addition, the influence of baffle design parameters, including baffle position, thickness and length, is thoroughly analyzed.

The finite difference method is used in conjunction with the alternating direction implicit and successive line over relaxation techniques to solve nonlinear and coupled partial differential equations. The single phase model is used for nanofluid which is considered as a homogeneous fluid with improved thermal properties. The independence tests are carried out for assessing the sufficiency of grid size and time step for obtaining results accurately.

The baffle dimension parameters and nanoparticle shape exhibit significant impact on the convective flow and heat transfer characteristics, leading to the following results: sphere- and blade-shaped nanoparticles demonstrate around 30% enhancement in the heat transport capability compared with platelet-shaped nanoparticles, which exhibit the least. When considering the baffle design parameter, either a decrease in the baffle length and thickness or an increase in baffle height leads to an improvement in heat transport rate. Consequently, a threefold increase in baffle height yields a 40% improvement in thermal performance.

Understanding the impact of nanoparticle shapes and baffle design parameters on flow and thermal behavior will enable engineers to provide valuable insight on thermal management and overall system efficiency. Therefore, the current work focuses on exploring buoyant nanofluid flow and thermal mechanism in a baffled annular-shaped enclosure. Specifically, an internal baffle that exhibits conductive heat transfer through it is considered, and the impact of baffle dimensions (thickness, length and position) on the fluid flow behavior and thermal characteristics is investigated. In addition, the current study also addresses the influence of five distinct nanoparticle shapes (e.g. spherical, cylindrical, platelet, blade and brick) on the flow and thermal behavior in the baffled annular geometry. In addition to deepening the understanding of nanofluid behavior in a baffled vertical annulus, the current study contributes to the ongoing advancements in thermal applications by providing certain guidelines to design application-specific enclosures.

The purpose of this study is to examine the physical processes experienced by a particle-laden gas due to various types of collisions, different heat transfer modalities and jet axis switching. Here, attention is focused on a particle-laden gas subjected to jet axis switching while experiencing fluid flow and heat transfer.

The methodology used to model and solve these complex problems is numerical simulation treated here as a two-phase turbulent flow in which the gas and the particles keep their separate identities. For the turbulent flow model, validation was achieved by comparisons with appropriate experimental data. The considered interactions between the fluid and the particles include one-way fluid–particle interactions, two-way fluid–particle interactions and particle–particle interactions.

For the fluid flow portion of the work, emphasis was placed on the particle collection efficiency and on independent variables that affect this quantity and the trajectories of the fluid and of the particles as they traverse the space between the jet orifice and the impingement plate. The extent of the effect depended on four factors: particle size, particle density, number of particles and the velocity of the fluid flow. The major effect on the heat transferred to the impingement plate occurred when direct heat transfer between the impinging particles and the plate was taken into account.

This paper deals with issues never before dealt with in the published literature: the effect of jet axis switching on the fluid mechanics of gas-particle flows without heat transfer and the effect of jet axis switching and the presence of particles on jet impingement heat transfer. The overall focus of the work is on the impact of jet axis switching on particle-laden fluid flow and heat transfer.