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The purpose of this paper is to prepare stabile emulsions with 0–15% of colloidal silica and high monomer/water ratio and to investigate the influence of silica addition and surface modification on the polyacrylate properties.

Improving the properties of the composite can be achieved by optimizing the compatibility between the phases of the composite system with improving the interactions at the matrix/filler interface. Therefore, the silica surface was modified with nonionic emulsifier octylphenol ethoxylate, cationic initiator 2,2'-azobis-(amidinopropane dihydrochloride) and 3-methacryloxypropyltrimethoxysilane and polyacrylate/silica nanocomposites were prepared via in situ emulsion polymerization. Particle size distribution, rheological properties of the emulsions and morphology, thermal properties and mechanical properties of the film prepared from the emulsions were investigated.

Polyacrylate/silica systems with unmodified silica, silica modified with nonionic emulsifier and cationic initiator have micrometer, while pure PA matrix and systems with silica modified with silane have nanometer particle sizes. Addition and surface modification of the filler increased emulsion viscosity. Agglomeration of silica particles in composites was reduced with silica surface modification. Silica filler improves thermal stability and tensile strength of polyacrylate.

This paper provides broad spectrum of information depending on filler surface modification and latex preparation via in situ emulsion polymerization and properties with high amount of filler and monomer/water ratio with the aim that prepared latex is suitable for film formation and final application.

The purpose of this study is to analyze the nonhomogeneous model on the mixed convection of Al2O3–Fe3O4 Bingham plastic hybrid nanofluid in a ventilated enclosure subject to an externally imposed uniform magnetic field. Entropy generation and the pressure drop are determined to analyze the performance of the heat transfer. The significance of Joule heating arising due to the applied magnetic field on the heat transfer of the yield stress fluid is described.

The ventilation in the enclosure of heated walls is created by an opening on one vertical wall through which cold fluid is injected and another opening on the opposite vertical wall through which fluid can flow out.

This study finds that the inclusion of Fe₃O₄ nanoparticles with the Al₂O₃-viscoplastic nanofluid augments the heat transfer. This rate of enhancement in heat transfer is higher than the rate by which the entropy generation is increased as well as the enhancement in the pressure drop. The yield stress has an adverse effect on the heat transfer; however, it favors thermal mixing. The magnetic field, which is acting opposite to the direction of the inlet jet, manifests heat transfer of the viscoplastic hybrid nanofluid. The horizontal jet of cold fluid produces the optimal heat transfer.

The objective of this study is to analyze the impact of the inclined cold jet of viscoplastic electrically conducting hybrid nanofluid on heat transfer from the enclosure in the presence of a uniform magnetic field. The combined effect of hybrid nanoparticles and a magnetic field to enhance heat transfer of a viscoplastic fluid in a ventilated enclosure has not been addressed before.

One of the major challenges in the design of thermal equipment is to minimize the entropy production and enhance the thermal dissipation rate for improving energy efficiency of the devices. In several industrial applications, the structure of thermal device is cylindrical shape. In this regard, this paper aims to explore the impact of isothermal cylindrical solid block on nanofluid (Ag – H₂O) convective flow and entropy generation in a cylindrical annular chamber subjected to different thermal conditions. Furthermore, the present study also addresses the structural impact of cylindrical solid block placed at the center of annular domain.

The alternating direction implicit and successive over relaxation techniques are used in the current investigation to solve the coupled partial differential equations. Furthermore, estimation of average Nusselt number and total entropy generation involves integration and is achieved by Simpson and Trapezoidal’s rules, respectively. Mesh independence checks have been carried out to ensure the accuracy of numerical results.

Computations have been performed to analyze the simultaneous multiple influences, such as different thermal conditions, size and aspect ratio of the hot obstacle, Rayleigh number and nanoparticle shape on buoyancy-driven nanoliquid movement, heat dissipation, irreversibility distribution, cup-mixing temperature and performance evaluation criteria in an annular chamber. The computational results reveal that the nanoparticle shape and obstacle size produce conducive situation for increasing system’s thermal efficiency. Furthermore, utilization of nonspherical shaped nanoparticles enhances the heat transfer rate with minimum entropy generation in the enclosure. Also, greater performance evaluation criteria has been noticed for larger obstacle for both uniform and nonuniform heating.

The current numerical investigation can be extended to further explore the thermal performance with different positions of solid obstacle, inclination angles, by applying Lorentz force, internal heat generation and so on numerically or experimentally.

A pioneering numerical investigation on the structural influence of hot solid block on the convective nanofluid flow, energy transport and entropy production in an annular space has been analyzed. The results in the present study are novel, related to various modern industrial applications. These results could be used as a firsthand information for the design engineers to obtain highly efficient thermal systems.