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This study aims to describe the design and synthesis of two novel azo and imine chromophores-based dyes derived from two different aldehydes with intramolecular colour matching that are pH sensitive.

The visible absorption wavelength (λ_max) was extended when azo chromophore was included in imine-based systems. The dyed patterns created sophisticated colour-changing paper packaging sensors with pH-sensitive chromophores using alum as a mediator or mordant. Due to the tight adhesive bonding, the dyes on paper’s cellulose fibres could not be removed by ordinary water even at extremely high or low pH, which was confirmed by scanning electron microscopy analysis. The dyed patterns demonstrated an evident, sensitive and fast colour-changing mechanism with varying pH, from pale yellow to red for Dye-I and from pale yellow to brown-violet for Dye-II.

The λ_max for colour changing was recorded from 400 to 490 nm for Dye-I, whereas from 400 to 520 for Dye-II. The freshness judgement of food was checked using actual experiments with cooked crab spoilage, where the cooked crab was incubated at 37 ^oC for 6 h to see the noticeable colour change from yellow to brown-violet with Dye-II. The colour-changing mechanism was studied with Fourier transform infrared (FTIR) spectra at different pH, and thin layer chromatography, nuclear magnetic resonance and FTIR spectroscopy studied the desired structure formation of the dyes. Potential uses for smart packaging sensors include quickly detecting food freshness during transportation or right before consumption.

1. Two novel azo-imine dyes have been synthesized with a pH-responsive effect. 2. The pH-responsive mechanism was studied. 3. The study was supported by computational chemistry using density functional theory. 4. The obtained dyes were used to make pH-responsive sensors for seafood packaging to judge the freshness.

Asteroids have the characteristics of noncooperative, irregular gravity and complex terrain on the surface, which cause difficulties in successful landing for conventional landers. The purpose of this paper is to study the trajectory tracking problem of a multi-node flexible lander with unknown flexible coefficient and space disturbance.

To facilitate the stability analysis, this paper constructs a simplified dynamic model of the multi-node flexible lander. By introducing the nonlinear transformation, a concurrent learning-based adaptive trajectory tracking guidance law is designed to ensure tracking performance, which uses both real-time information and historical data to estimate the parameters without persistent excitation (PE) conditions. A data selection algorithm is developed to enhance the richness of historical data, which can improve the convergence rate of the parameter estimation and the guidance performance.

Finally, Lyapunov stability theory is used to prove that the unknown parameters can converge to their actual value and, meanwhile, the closed-loop system is stable. The effectiveness of the proposed algorithm is further verified through simulations.

This paper provides a new design idea for future asteroid landers, and a trajectory tracking controller based on concurrent learning and preset performance is first proposed.

Personal thermal management by controlling the radiation energies of both the body and the sun can be used in all environments and contributes to sustainability components with the advantages of energy saving, low chemical usage and comfort enhancements under dynamic conditions. In this study, passive radiative heating nanocomposite films were produced using sodium alginate as the matrix and zinc oxide (ZnO) and aluminum oxide (Al₂O₃) nanoparticles as nanofillers having far infrared radiation reflecting, hence passive heating functions.

Nanocomposite film solutions were prepared by stirring sodium alginate powder, deionized water, ZnO and Al₂O₃ nanoparticles (20% wt of matrix polymer) with surfactant using magnetic and ultrasonic stirrers in turn. Films produced within Petri dishes after drying at room temperature were analyzed by FT-IR, UV-VIS-NIR spectroscopy and SEM for chemical, radiation management and morphological characteristics, respectively. Emissivity values giving idea about the heating performances of the films were determined with an IR camera and a hotplate system. Moreover, direct heating performances were measured by the hotplate system including a far-infrared lamp.

Results showed that the emissivity of the films increased by approximately 18% and 16% with ZnO and Al₂O₃ nanoparticles, respectively. Moreover, NaAlg–Al₂O₃ nanocomposite film exhibited passive radiative heating performance of 3.58 °C, higher than the heating performance of NaAlg–ZnO nanocomposite film which is 2.97 °C when compared to the reference NaAlg film. These results indicate that both NaAlg–ZnO and especially NaAlg–Al₂O₃ nanocomposite films have excellent far-infrared emission and absorption properties ensuring a significant heating effect.

In addition to other clothing types, the heating performance obtained with the produced nanocomposite structures may be applied to different types of cosmetic/medical applications (beauty mask, wound dresses, etc.) enabling skincare/healing with the advantage of the sodium alginate matrix.

The purpose of this study is to use liposome technology in the treatment of fabrics textiles because of its efficient energy saving, reducing time and temperature.

The newly prepared lecithin liposome was used to encapsulate dyes for the purpose of increasing dyeing affinity. Different ratios of commercially available lecithin liposomes (1%, 3%, 5% and 7%) were used simultaneously in the dyeing of cotton and wool fabrics. The treated fabrics (cotton and wool fabrics) were confirmed using different analytical procedures such as scanning electron microscope (SEM), Fourier-transition infrared spectroscopy, ultraviolet protection factor, colour strength (K|S) measurements and fastness measurements.

The results show that increasing liposome ratios in dyeing baths leads to increased dyeing affinity for cotton and wool fabrics compared with conventional dyeing without using liposomes. In addition to that, the colour strength values, infrared spectra, SEM and fastness properties of non-liposome-dyed fabrics and liposome-dyed fabrics were investigated.

The research paper provides broad spectrum of green encapsulation fabrics using liposome technology to perform the dye stability, dye strength and fastness.

The aim of this paper is to review the literature on the prediction of cutting tool life. Tool life is typically estimated by predicting the time to reach the threshold flank wear width. The cutting tool is a crucial component in any machining process, and its failure affects the manufacturing process adversely. The prediction of cutting tool life by considering several factors that affect tool life is crucial to managing quality, cost, availability and waste in machining processes.

This study has undertaken the critical analysis and summarisation of various techniques used in the literature for predicting the life or remaining useful life (RUL) of the cutting tool through monitoring the tool wear, primarily flank wear. The experimental setups that comprise diversified machining processes, including turning, milling, drilling, boring and slotting, are covered in this review.

Cutting tool life is a stochastic variable. Tool failure depends on various factors, including the type and material of the cutting tool, work material, cutting conditions and machine tool. Thus, the life of the cutting tool for a particular experimental setup must be modelled by considering the cutting parameters.

This submission discusses tool life prediction comprehensively, from monitoring tool wear, primarily flank wear, to modelling tool life, and this type of comprehensive review on cutting tool life prediction has not been reported in the literature till now. The future suggestions provided in this review are expected to provide avenues to solve the unexplored challenges in this field.

In the era of digital intelligence, individuals are increasingly interacting with digital information in their daily lives and work, and a growing phenomenon known as digital hoarding is becoming more prevalent. Prior research suggests that humanities researchers have unique and longstanding information interaction and management practices in the digital scholarship context. This study therefore aims to understand how digital hoarding manifests in humanities researchers’ behavior, identify the influencing factors associated with it, and explore how they perceive and respond to digital hoarding behavior.

Qualitative research methods enable us to acquire a rich insight and nuanced understanding of digital hoarding practices. In this study, semi-structured interviews were conducted with 20 humanities researchers who were pre-screened for a high propensity for digital hoarding. Thematic analyses were then used to analyze the interview data.

Three main characteristics of digital hoarding were identified. Further, the research paradigm, digital affordance, and personality traits and habits, collectively influencing the emergence and development of digital hoarding behaviors, were examined. The subtle influence of traditional Chinese culture was encountered. Interestingly, this study found that humanists perceive digital hoarding as a positive expectation (associated with inspiration, aesthetic pursuit, and uncertainty avoidance). Meanwhile, humanists' problematic perception of this behavior is more widely observed — they experience what we conceptualize as an “expectation-perception” gap. Three specific information behaviors related to avoidance were identified as aggravating factors for digital hoarding.

The findings deepen the understanding of digital hoarding behaviors and personal information management among humanities researchers within the LIS field, and implications for humanities researchers, digital scholarship service providers, and digital tool developers are discussed.

This study aims to produce textile-like surfaces using fused deposition modelling (FDM) 3D printers and create a garment collection.

Experiments were conducted using different types of materials in FDM 3D printers until the sufficient flexibility was achieved to create textile-like structures. During the research, properties of polylactic acid (PLA), acrylonitrile butadiene styrene (ABS) and thermoplastic polyurethane (TPU) were observed. Geometrical patterns were printed and each of them gave a different result depending on the pattern. Based on the information obtained from the experiments, a garment collection with four total looks was designed inspired by Vivaldi’s “Four Seasons”.

Among the materials used, TPU, a flexible filament, yielded the best results. Because of the rigid properties of PLA and ABS, chain-like structures were printed to create relatively flexible surfaces, but the results were still not successful enough to create a clothing material. Therefore, TPU was preferred for the garment material selection.

In this study, combinations of 3D printed flexible structures and different types of fabrics were used to create a garment collection. It was concluded that, with the right material selection, 3D printing can be used as an alternative method to create a new aesthetic language in fashion design.

This paper aims to focus on the research progress of intelligent self-healing anti-corrosion coatings in the aviation field in the past few years. The paper provides certain literature review supports and development direction suggestions for future research on intelligent self-healing coatings in aviation.

This mini-review uses a systematic literature review process to provide a comprehensive and up-to-date review of intelligent self-healing anti-corrosion coatings that have been researched and applied in the field of aviation in recent years. In total, 64 articles published in journals in this field in the last few years were analysed in this paper.

The authors conclude that the incorporation of multiple external stimulus-response mechanisms makes the coatings smarter in addition to their original self-healing corrosion protection function. In the future, further research is still needed in the research and development of new coating materials, the synergistic release of multiple self-healing mechanisms, coating preparation technology and corrosion monitoring technology.

To the best of the authors’ knowledge, this is one of the few systematic literature reviews on intelligent self-healing anti-corrosion coatings in aviation. The authors provide a comprehensive overview of the topical issues of such coatings and present their views and opinions by discussing the opportunities and challenges that self-healing coatings will face in future development.

A new Chatbot system is implemented to provide both voice-based and textual-based communication to address student queries without any delay. Initially, the input texts are gathered from the chat and then the gathered text is fed to pre-processing techniques like tokenization, stemming of words and removal of stop words. Then, the pre-processed data are given to the Natural Learning Process (NLP) for extracting the features, where the XLnet and Bidirectional Encoder Representations from Transformers (BERT) are utilized to extract the features. From these extracted features, the target-based fused feature pools are obtained. Then, the intent detection is carried out to extract the answers related to the user queries via Enhanced 1D-Convolutional Neural Networks with Long Short Term Memory (E1DCNN-LSTM) where the parameters are optimized using Position Averaging of Binary Emperor Penguin Optimizer with Colony Predation Algorithm (PA-BEPOCPA). Finally, the answers are extracted based on the intent of a particular student’s teaching materials like video, image or text. The implementation results are analyzed through different recently developed Chatbot detection models to validate the effectiveness of the newly developed model.

A smart model for the NLP is developed to help education-related institutions for an easy way of interaction between students and teachers with high prediction of accurate data for the given query. This research work aims to design a new educational Chatbot to assist the teaching-learning process with the NLP. The input data are gathered from the user through chats and given to the pre-processing stage, where tokenization, steaming of words and removal of stop words are used. The output data from the pre-processing stage is given to the feature extraction phase where XLnet and BERT are used. In this feature extraction, the optimal features are extracted using hybrid PA-BEPOCPA to maximize the correlation coefficient. The features from XLnet and features from BERT were given to target-based features fused pool to produce optimal features. Here, the best features are optimally selected using developed PA-BEPOCPA for maximizing the correlation among coefficients. The output of selected features is given to E1DCNN-LSTM for implementation of educational Chatbot with high accuracy and precision.

The investigation result shows that the implemented model achieves maximum accuracy of 57% more than Bidirectional long short-term memory (BiLSTM), 58% more than One Dimansional Convolutional Neural Network (1DCNN), 59% more than LSTM and 62% more than Ensemble for the given dataset.

The prediction accuracy was high in this proposed deep learning-based educational Chatbot system when compared with various baseline works.

This research purpose was to explore the meaning of historicism, architectural historicism, the architectural attributes, design principles, elements and ornamentations of churches in medieval Western architecture, and how they were reflected in contemporary churches' design in Jordan.

This research used the historical descriptive–interpretive qualitative research method. Around 24 Western medieval churches were selected, studied and analyzed to explore the common design attributes of each historical era. The design attributes of each era were segmented under three categories: Design principles (plans' typology, facades, shapes, details, composition and building form), design elements (openings, towers and entrances) and ornamentation (sculptures, paintings and interior decoration). Additionally, three modern Jordanian churches were analyzed using the same method to compare with the historical churches through personal observations, field trips, researchers' memories, site visits, archival records, plans, images, books, slides, details and note-making. Different types of evidence were used, such as determinate, contextual and inferential. In addition, different tactics for analysis were used in analyzing the historical churches: site familiarity, use of existing documents, virtual and visual inspection and comparison with conditions elsewhere. Credibility was achieved when the results were reviewed and compared with the original and similar information.

Early Christian design principles, elements and ornamentations were reflected in Jordanian churches more than in Byzantine, Renaissance, Romanesque and Gothic. The design principles of Western medieval architecture were reflected in the selected Jordanian churches more than in ornamentation and design elements. Moreover, this research found that the highest reflection of Western medieval architecture on Jordanian churches was in designing the plans, which is a basilica with a central nave and aisles followed by opening styles, façade, shapes, entrances design, composition, painting and the minimum reflection was in sculptures. Additionally, there was no reflection on tower design and interior decoration.

This research encourages architects to enhance architectural historicism by focusing on historical styles in contemporary designs and using design elements, principles and decorations of historical styles in medieval architecture to enrich the variety and originality of architectural design and create new modern stylistic architecture. Architectural historicism increases historical self-awareness and helps a generation of architects to answer the question: In what style should be built.

Learning the design principles, not copying the past, is becoming a trend for most architects. Architectural historicism introduces new temporal elements, gives a new meaning and primary function to architecture to become socio-temporal and contextual contrast and reflects the essential points of references of the past through design methodology to express the present. The advantage of this research is to put an end to architects' role in syncretism and subjectivism. Instead, historicism architects equipped with the necessary knowledge and supported by the published research and inventors of historical architecture, can choose, imitate, adapt, borrow and use the correct historical forms that originated in a given period.