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The aim is to provide detailed mechanical and metallurgical examinations of ion‐nitrided austenitic‐stainless steels.

Austenitic‐stainless steel was the material chosen for the present study. Ion nitriding process was applied to fatigue and tensile samples prepared by machining. Process temperature was 550°C and treatment time period 24 and 60 h. Then, tensile, fatigue, notch‐impact, hardness tests were applied and metallographic examinations were performed.

High temperature and longer treatment by ion nitriding decreased fatigue and tensile strengths together with notch‐impact toughness. Scanning electron microscopy and energy dispersive X‐ray spectroscopy analysis revealed formation of nitrides on the sample surfaces. Surface hardness increased with an increase in process time due to diffusion of nitrogen during ion nitriding.

It would be interesting to search the different temperature and time intervals of the ion nitriding. It could be a good idea if future work could be concentrated on ion nitriding on welded stainless steels.

Surfaces of mechanical parts are exposed to higher stress and abrasive forces compared to inside mechanical parts during the time period that mechanical components carry out their expected functions. When stresses and forces exceed the surface strength limit of the material, cracks begin to form at the material surface leading to abrasion and corrosion. Therefore, surface strength of materials needs to be increased to provide a longer service life. Ion (plasma) nitriding is a possible remedy for surface wear.

The main value of this paper is to contribute and fulfil the detailed mechanical and metallurgical examinations of ion‐nitrided austenitic‐stainless steels that are being studied so far in the literature.

The purpose of this paper was to determine the mode and cause of failure of polyester-coated galvanized corrugated steel sheets that exhibited degradation of the coating after seven months into service.

Visual inspection and light microscopy revealed the extent of damage exhibited by the panels. Standard metallographic techniques were used to prepare samples obtained from both unused and failed sections. Light microscopy, scanning electron microscopy combined with energy dispersive x-ray spectroscopy and x-ray diffraction techniques were used to study the surface morphology, microstructural features, elemental composition and structure of the samples.

The failure occurred in the form of delamination and blistering of coated layer. Presence of solar radiation, humidity and water retention resulted in loss of adhesion, leading to coating delamination and flaking especially at the top surface. The coating at the bottom surface of the panels showed evidence of blistering caused by water vapor differential that existed between the environment and the coating because of prolonged (four months) wet conditions that existed at the manufacturer’s site during storage.

It is recommended that the coated panels are stored in covered area where direct exposure to atmospheric conditions can be prevented. If open storage is unavoidable, then the use of tarpaulin or plastic sheet as covering and vapor-phase inhibitors was recommended.

This paper provides an account of failure analysis of metal sheet panels. It identifies the mode and cause of failure and also provides recommendations to avoid such occurrences in the future. The information contained in this paper is useful for plant engineers and project managers working in the metal sheet industry.

The purpose of this study is to address two kinds of printed circuit board (PCB) failures with electrolytic Ni/Au as the surface finish. One was the weak bondability of gold wires to Ni/Au pads and the other was “dull gold” and weak solder wettability, which both caused great loss for the PCB manufacturer.

The failure samples were studied and analyzed in terms of macro- and micro-morphology of the surface finish, its element composition and thickness by various characterization techniques, such as three-dimensional stereo microscope, scanning electron microscope, energy dispersive spectroscopy and X-ray fluorescence spectrum.

Then the causes of the two failures were both found to be the inadequate thickness of gold deposit and other surface finish defects, but these causes played different roles in either failure or the mechanisms differ. Finally, their failure mechanisms were discussed and corresponding countermeasures were put forward for prevention.

This study not only addresses a practical failure problem but also provides some clues to a better and further understanding of the effect of PCB process and management on its quality and reliability in manufacturing practice.

It sheds light on how the thickness and quality of surface finish affects its wire bonding and soldering performances.

The purpose of this study was to investigate the performances of two inhibitors in controlling corrosion of steel products in industrial and marine atmosphere.

Corrosion rates were determined by weight loss measurements. At certain periods of atmospheric exposure, the (disc shape) specimens were retrieved and studied by scanning electron microscopy and energy-dispersive spectrometry surface analysis techniques.

Both inhibitors were effective against corrosion of steel in the early stages of the atmospheric exposure (for about two months). With further exposure to the atmosphere, their inhibition effectiveness deteriorated and was totally lost within four months. Analysis of the specimens before exposure showed that the inhibitor film was thin for both treatments, and the unexposed treated surface for both inhibitors appeared similar to the untreated unexposed specimen surface. Characterization of the specimens at different exposure periods showed fewer corrosion blisters on dicyclohexylamine nitrite- and sodium benzoate-treated surfaces than on untreated specimens.

The objective of this study was to characterize the surfaces of the steel products produced locally during their exposure to the industrial and marine atmosphere of the Arabian Gulf region after being treated by sodium benzoate and dicyclohexylamine nitrite in controlling the corrosion of local mild steel products. According to the literature review, this study is original and will add value to the studies of inhibition of steel corrosion under similar environments.

The purpose of this paper is to investigate the mechanical properties changing of geopolymer cement under different brine salinity.

Geopolymer Cement of Class F Fly Ash and Class G Cement slurries were prepared according to API RP 10B. The optimum alkaline activator/cement and water/cement ratio of 0.44 was used for geopolymer and Class G cement samples, respectively. The alkaline activator was prepared by mixing the proportion of Sodium Hydroxide (NaOH) solutions of 8 M and Sodium Silicate (Na2SiO3) using ratio of 1:2.5 by weight. The slurries were cured for 24 hours at 130^oC and 3,000 psi in HPHT Curing Chamber followed by coring process. Both cement sample were immersed in brine water salinity up to 28 days with different brine salinity up to 30 per cent of NaCl. The mechanical properties were investigated using OYO Sonic Viewer-SX and Uniaxial Compressive Strength. The surfaces of the cement samples were extracted for Scanning Electron Microscope (SEM) and EDS tests to evaluate the morphology and chemical compositions of the cured samples.

The paper shows that geopolymer samples experiences strength reduction in brine water but the reduction rate of geopolymer is about half of the Ordinary Portland cement based oil well cement. The finding was also verified by SEM and EDS result.

This paper investigates the mechanical property changes of emerging geopolymer cement due to different water salinity. The results provide potential application of geopolymer cement for oil well cementing.

This paper aims to fabricate and characterize ZnO-based multilayer varistors.

Tape casting technique was utilized for preparation of multilayer varistors based on ZnO doped with Pr, Bi, Sb, Co, Cr, Mn and Si oxides. Scanning electron microscope (SEM), energy-dispersive X-ray spectroscopy (EDS) and X-ray diffraction (XRD) methods were used to study the microstructure, elemental and phase compositions, respectively, of the varistors. Dielectric properties were investigated by impedance spectroscopy. Current–voltage (I–U) dependences were measured to characterize nonlinear behavior of the fabricated varistors.

XRD, SEM and EDS studies revealed dense microstructure of ceramic layers with ZnO grains sized 1-4 μm surrounded by nanometric Bi-rich films, submicrometer Zn₇Sb₂O₁₂ spinel grains and needle-shaped Pr₃SbO₇ crystallites. Praseodymium oxide was found to be very effective as an additive restricting the ZnO grain growth. I–U characteristics of the fabricated multilayer varistors were nonlinear, with the nonlinearity coefficients of 23-27 and 19-51 for the lower and higher Pr₂O₃ content, respectively. The breakdown voltages were 60-150 V, decreasing with increasing sintering temperature.

Low-temperature cofired ceramics technology enables attaining a significant progress in miniaturization of electronic passive components. Literature concerning application of this technology for multilayer varistors fabrication is limited. In the present work, the results of XRD, SEM and EDS studies along with the I–U and complex impedance dependences are analyzed to elucidate the origin of the observed varistor effect. The influence of sintering temperature and Pr₂O₃-doping level was investigated.

This study aims to using Fourier transform infrared (FTIR) spectroscopy, Raman spectroscopy and scanning electron microscope/energy dispersive Xray spectrometer to identify different automotive coatings for forensic purpose.

Two four-layered samples in a hit-and-run case were compared layer by layer with three different methods. FTIR spectroscopy was used to primarily identify the organic and inorganic compositions. Raman spectrum and scanning electron microscope/energy dispersive Xray spectrometer (SEM-EDS) were further used to complement the FTIR results.

Two weak and tiny peaks in one layer found between two samples by FTIR, Raman microscope and SEM-EDS verified the result of differences. The study used the three instruments in combination and found it’s effective in sensing coatings, especially in the inorganic additives.

Using these three instruments in combination is more accurate than individually in multilayered coating analysis for forensic purpose.

The three different instruments all present unique information on the composition, and provided similar and mutually verifiable results on the two samples.

With this method, scientists could identify and discriminate important coating evidences with tiny but characteristic differences.

The biomaterials are natural or synthetic materials used to improve quality of life either by replacing tissue/organ or assisting their function in medical field. The purpose of the study is to analyze the hydroxyapatite (HAP), HAP-TiO₂ (25 percent) composite coatings deposited on 316 LSS by High Velocity Flame Spray (HVFS) technique.

The coatings exhibit almost uniform and dense microstructure with porosity (HAP = 0.153 and HAP-TiO₂ composite = 0.138). Electrochemical corrosion testing was done on the uncoated and coated specimens in Ringer solution (SBF). As-sprayed coatings were characterized by XRD, SEM/EDS and cross-sectional X-ray mapping techniques before and after dipping in Ringer solution. Microhardness of composite coating (568.8 MPa) was found to be higher than HAP coating (353 MPa).

During investigations, it was observed that the corrosion resistance of steel was found to have increased after the deposition of HAP and HAP-TiO₂ composite coatings. Thus, coatings serve as an effective diffusion barrier to prohibit the diffusion of ions from the SBF into the substrate. Composite coatings have been found to be more corrosion resistant as compared to HAP coating in the simulated body fluid.

It has been concluded that corrosion resistance of HAP as well as composite coating is because of the desirable microstructural changes such as low porosity high microhardness and flat splat structures in coatings as compared to bare specimen.

This study is useful in the selection of biomedical implants.

This study is useful in the field of biomaterials.

No reported literature on corrosion behavior of HAP+ 25%- TiO₂ has been noted till now using flame spray technique. The main focus of the study is to investigate the HAP as well as composite coatings for biomedical applications.

The purpose of this paper is to evaluate the corrosion of silver due to hydrogen sulphide pollutant in indoor conditions at a microelectronics plant located in Mexicali, Baja California, a semi‐arid zone in the northwest of Mexico.

Silver coupons and silver plated on to copper‐lead frames are exposed in the assembly process building of a microelectronics company during a period of 60 days and also in a sheltered test chamber that simulates indoor conditions with ambient concentrations of atmospheric pollutants, temperature and relative humidity (rH). Other exposures are made in the test chamber to study the corrosion behaviour of silver coupons over a duration of 24 months. The corrosion products were analysed using the Scanning Electron Microscope (SEM) and Energy Dispersive X‐ray Spectroscopy (EDS). Corrosion rates were measured by Quartz Crystal Microbalance (QCM) under laboratory‐controlled conditions.

The presence of silver sulphide corrosion products, dendrites and whiskers is observed on the exposed samples using SEM and EDS analysis.

The paper is designed to establish whether the company, where the exposure is taking place, constituted an indoor environment with outdoor hydrogen sulphide pollutant in sufficient concentration to induce silver corrosion.

The methodology used in this work can be applied to study the indoor corrosion behaviour of other metals, which will be of interest to the microelectronics industry.

Microbes that are able to grow on different surfaces can cause the deterioration of the underlying layers because of their metabolic activity. The purpose of this study is report the ability of fungi-bacteria consortium (FBC) in anaerobic media, and marine strain bacteria, to attach onto UNS 1008 carbon steel and zinc epoxy coats.

Impedance analysis, scanning electronic microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDS) were used to evaluate the adherence, biofilm formation and corrosion effect of FBC and marine bacteria onto UNS1008 carbon steel in anaerobic and aired conditions, respectively. In a similar way, the anticorrosive performance of hybrid coats on UNS 1008 carbon steel against marine bacteria.

In aerobic conditions, the outer layer shows a micro-crack appearance and several semi-sphere products that could be because of spore formation. In anaerobic conditions, evidence of iron sulfide surrounded by a mixture of sulfur-containing extracellular polymer substance was observed by SEM images and EDS analysis. The presence of hybrid coats (zinc epoxy with carbon nanotubes CNT content) affected the level of microbial adherence and the concentration of corrosion products (Fe₂O₃, Fe(OH)₂ and FeS); the cell attachment was lower when the steel surface was coated with Zn/CNTs.

This study opens a window for further evaluations of CNTs associated with metals as active materials to assess the corrosion on extreme corrosive environments, like in oil and gas industries the microorganisms play an important role either to increase or reduce the corrosion processes.