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This study aims to investigate the behavior of the green biomass-derived copper (lignin/silica/fatty acids) complex, copper lignin/silica/fatty acids (Cu-LSF) complex, when incorporated into the nonpolar ethylene propylene diene (EPDFM) rubber matrix, focusing on its reinforcing and antioxidant effect on the resulting EPDM composites.

The structure of the prepared EPDM composites was confirmed by Fourier-transform infrared spectroscopy, and the dispersion of the additive fillers and antioxidants in the EPDM matrix was investigated using scanning electron microscopy. Also, the rheometric characteristics, mechanical properties, swelling behavior and thermal gravimetric analysis of all the prepared EPDM composites were explored as well.

Results revealed that the Cu-LSF complex dispersed well in the nonpolar EPDM rubber matrix, in thepresence of coupling system, with enhanced Cu-LSF-rubber interactions and increased cross-linking density, which reflected on the improved rheological and mechanical properties of the resulting EPDM composites. From the various investigations performed in the current study, the authors can suggest 7–11 phr is the optimal effective concentration of Cu-LSF complex loading. Interestingly, EPDM composites containing Cu-LSF complex showed better antiaging performance, thermal stability and fluid resistance, when compared with those containing the commercial antioxidants (2,2,4-trimethyl-1,2-dihydroquinoline and N-isopropyl-N’-phenyl-p-phenylenediamine). These findings are in good agreement with our previous study on polar nitrile butadiene rubber.

The current study suggests the green biomass-derived Cu-LSF complex to be a promising low-cost and environmentally safe alternative filler and antioxidant to the hazardous commercial ones.

The study aims to verify and establish the result of the most suitable optimization approach for higher performance and lower emission of a variable compression ratio (VCR) diesel engine. In this study, three types of test fuels are taken and tested in a variable compression ratio diesel engine (compression ignition). The fuels used are conventional diesel fuel, e-diesel (85% diesel-15% bioethanol) and nano-fuel (85% diesel-15% bioethanol-25 ppm Al₂O₃). The effect of bioethanol and nano-particles on performance, emission and cost-effectiveness is investigated at different load and compression ratios (CRs). The optimum performance and lower emission of the engine are evaluated and compared with other optimization methods.

The test engine is run by diesel, e-diesel (85% diesel-15% bioethanol) and nano-fuel (85% diesel-15% bioethanol-25 ppm Al₂O₃) in three different loadings (4 kg, 8 kg and 12 kg) and CR of 14, 16 and 18, respectively. The optimum value of energy efficiency, exergy efficiency, NO_X emission and relative cost variation are determined against the input parameters using Taguchi-Grey method and confirmed by response surface methodology (RSM) technique.

Using Taguchi-Grey method, the maximum energy and exergy efficiency, minimum % relative cost variation and NO_X emission are 24.64%, 59.52%, 0 and 184 ppm, respectively, at 4 kg load, 18 CR and fuel type of nano-fuel. Using RSM technique, maximum energy and exergy efficiency are 24.8% and 62.9%, and minimum NO_X emission and % cost variation are 208.4 ppm and –6.5, respectively, at 5.2 kg load, 18 CR and nano-fuel. The RSM is suggested as the most appropriate technique for obtaining maximum energy and exergy efficiency, and minimum % relative cost; however, for lowest possible NO_X emission, the Taguchi-Grey method is the most appropriate.

Waste rice straw is used to produce bioethanol. 4-E analysis, i.e. energy, exergy, emission and economic analysis, has been carried out, optimized and compared.

This study aims to examine the role of edible mushrooms in the Brazilian diet, considering their strategic significance in meeting nutritional goals within sustainable development. Despite their potential in the nutrition of the Brazilian population, significant knowledge gaps still exist. To address this, the authors formulated this study into five main sections: the consumption of edible mushrooms in Brazil, the factors influencing the consumption, the occurrence of edible mushrooms in Brazil, the nutritional contribution of mushrooms consumed in Brazil and sustainable mushroom production in Brazil.

The authors compiled current literature to develop this viewpoint paper using systematic review, systematic search and narrative review search methods.

Mushrooms are sporadically consumed in Brazil, primarily by the urban population, with challenges in estimating the most used species. Social, economic and cultural factors, health considerations and reduced meat consumption influence mushroom consumption behavior. While Pleurotus ostreatus, Lentinula edodes and Agaricus bisporus are primary species, ethnomycological studies highlight a more diverse consumption among traditional indigenous communities. Brazil hosts approximately 133 wild mushroom species safe for human consumption. Some can be sustainably cultivated using substrates derived from agricultural and urban waste, offering high-protein, high-fiber, low-fat foods with bioactive compounds holding antioxidant and prebiotic potential.

To the best of the authors’ knowledge, no previous study has investigated how edible mushrooms contribute to the food and nutrition of the Brazilian population. This study emphasizes the crucial role of edible mushrooms in preserving Brazil’s cultural heritage, contributing to food and nutritional security and enhancing the overall diet quality.

The purpose of this study is to experimentally determine whether mechanical properties of concrete can be improved by using olive pomace aggregates (OPA) as a substitute for natural sand. Two types of OPA were tested by replacing an equivalent amount of natural sand. The first type was OPA mixed with olive mill wastewater (OMW), and the second type was OPA not mixed with OMW. For each type, two series of concrete were produced using OPA in both dry and saturated states. The percentage of partial substitution of natural sand by OPA varied from 0% to 15%.

The addition of OPA leads to a reduction in the dry density of hardened concrete, causing a 5.69% decrease in density when compared to the reference concrete. After 28 days, ultrasonic pulse velocity tests indicated that the resulting material is of good quality, with a velocity of 4.45 km/s. To understand the mechanism of resistance development, microstructural analysis was conducted to observe the arrangement of OPA and calcium silicate hydrates within the cementitious matrix. The analysis revealed that there is a low level of adhesion between the cement matrix and OPA at interfacial transition zone level, which was subsequently validated by further microstructural analysis.

The laboratory mechanical tests indicated that the OPCD_OPW (5) sample, containing 5% of OPA, in a dry state and mixed with OMW, demonstrated the best mechanical performance compared to the reference concrete. After 28 days of curing, this sample exhibited a compressive strength (R_c) of 25 MPa. Furthermore, it demonstrated a tensile strength of 4.61 MPa and a dynamic modulus of elasticity of 44.39 GPa, with rebound values of 27 MPa. The slump of the specimens ranged from 5 cm to 9 cm, falling within the acceptable range of consistency (Class S2). Based on these findings, the OPCD_OPW (5) formulation is considered optimal for use in concrete production.

This research paper provides a valuable contribution to the management of OPA and OMW (OPA_OMW) generated from the olive processing industry, which is known to have significant negative environmental impacts. The paper presents an intriguing approach to recycling these materials for use in civil engineering applications.

The purpose of this study is to prepare a new adsorbent activated carbon immobilized on polystyrene (ACPS) for uranium (VI) and thorium (IV) removal from an aqueous solution. Activated carbon (AC) was derived from biochar material by chemical activation to increase the active sites on its surface and enhance the adsorption capacity. Activated carbon (AC) was immobilized on polystyrene (PS) to improve the physical properties and facilitate separation from the working solution. A feasibility study for the adsorption of uranium (VI) and thorium (IV) on the new adsorbent (ACPS) has been achieved. Adsorption kinetics, isotherms, and thermodynamics models of the adsorption process were used to describe the reaction mechanism.

Activated carbon was synthesized from biochar charcoal by 2 M H₂SO₄. Activated carbon was immobilized on the pretreatment polystyrene by hydrothermal process forming new adsorbent (ACPS). Characterization studies were carried out by scanning electron microscope, energy-dispersive X-ray spectrometer, infrared spectroscopy and X-ray diffraction techniques. Different factors affect the adsorption process as pH, contact time, solid/liquid ratio, initial concentration and temperature. The adsorption mechanism was explained according to kinetic, isothermal and thermodynamic studies. Also, the regeneration of spent ACPS was studied.

The experimental results showed that pH and equilibrium time of the best adsorption were 6.0 and 60 min for U(VI), 4.0 and 90 min for Th(IV), (pH_PZC = 3.4). The experimental results fit well with pseudo-second order, Freundlich and Dubinin–Radushkevich models proving the chemisorption and heterogenous adsorption reaction. Adsorption thermodynamics demonstrated that the adsorption process is exothermic and has random nature of the solid/liquid interface. In addition, the regeneration of spent ACPS research showed that the adsorbent has good chemical stability. According to the comparative study, ACPS shows higher adsorption capacities of U(VI) and Th(IV) than other previous bio-adsorbents.

This study was conducted to improve the chemical and physical properties of bio-charcoal purchased from the local market to activated carbon by hydrothermal method. Activated carbon was immobilized on polystyrene forming new adsorbent ACPS for eliminating U(VI) and Th(IV) from aqueous solutions.

Understanding farmer and consumer behavior is essential to the successful implementation of behavior change interventions. The purpose of this study is to summarize existing research, provide a comprehensive overview of nudge interventions, and identify important trends in behavioral agricultural economics. Research on nudge interventions can help policymakers encourage farmers and consumers to change their behavior in desired direction like switching to organic agriculture or eco-labeled products and promote innovation in sustainable agriculture.

The paper contains a bibliometric analysis of nudge research in general and agricultural economics as well as a literature review of the 53 empirical studies on nudge interventions between 2003 and 2023.

The frequency of nudge research in all research fields and in agricultural economics has increased over the years. This study summarizes nudge interventions that can be used by farmers and consumers on a variety of agricultural economic issues. Information, social norms, and social comparison as nudge interventions are most prominent in the publications, while green nudges have not been researched to a greater extent.

This study provides a comprehensive overview of nudge research in agricultural economics with potential for theoretical and policy implications. It highlights potential nudge interventions among farmers and consumers that can be applied in practices.

The agriculture sector is crucial for all economies, especially the developing ones. However, agricultural production is influenced by government intervention, which outshines the significant role of good governance indicators in agricultural productivity. In addition to this, the major climate changes also posed various challenges and led to water shortages and yield losses. Thus affecting agricultural production. In this paper, we address the issue by determining the association between state governance and agricultural productivity in N-11 countries.

Panel data have been collected from 2000 to 2021 through the Governance Indicator, World Development Indicator and World Bank databases. For data analysis, the researcher has utilized the autoregressive distributed lag (ARDL) estimations.

Through ARDL estimations, it is suggested that corruption (CC), employment in agriculture (EAG), political stability and violence absence (PS), rule of law (RL), regulatory equality (RQ) and water quality (WQ) significantly impact agricultural productivity (AGP) in the long run. In the short run, the impact of RL on AGP has been significant.

This study follows the method of data collection from secondary sources, which hinders the effectiveness of this study as, on the basis of the respective data, the potential of the researcher to get specific answers to research questions has been affected. Also, this study examines the context of N-11 countries from 2000 to 2021, which exerts a geographical limitation. While exploring the association between state governance and agricultural productivity, this study neglects the internal aspects of implementing state policies in firms.

On practical grounds, the significant association demonstrated by this study encourages agricultural firms to keenly consider state policies to gain sustainable agricultural development. Moreover, this study encourages agricultural firms to efficiently follow governance policies for efficient productivity. The outcomes of the study have shown that agricultural employment and governance infrastructure can efficiently enhance agricultural productivity. Besides, as per the results, water quality also positively impacts agricultural productivity; thus, relevant steps can be taken by the agricultural sector to improve the quality of water.

Additive manufacturing (AM) is a layer-by-layer technique that helps to create physical objects from a three-dimensional data set. Fused deposition modeling is a widely used material extrusion (MEX)-based AM technique that melts thermoplastic filaments and selectively deposits them over a build platform. Despite its simplicity and affordability, it suffers from various printing defects, with partial warping being a prevalent issue. Warpage is a physical deformation caused by thermal strain incompatibility that results in the bending of the printed part away from the build platform. This study aims to investigate the warpage characteristics of printed parts based on geometrical parameters and build orientations to reduce the warpage extent.

Cuboidal samples of thermoplastic acrylonitrile butadiene styrene ranging from 5 to 80 mm were printed using a commercial MEX system. A Taguchi method-based design of experiment trial was performed to optimize the placement and orientation of the part for minimal warpage.

It was found that a lower value of the “in-plane” aspect ratio and a more prominent part thickness are favorable for minimal warpage. The part should always be placed near the region with the highest temperature (least thermal gradient) to minimize the warpage.

A novel dimensionless parameter (Y) is proposed that should be set to a minimum value to achieve minimal warpage. The results of this study can help improve the design and part placement for the MEX technique, thus elevating the print quality.

Human activities in recent years with the excessive emission of greenhouse gases have had a negative impact on increasing global temperatures. In this regard, one of the best ways to control it is to move toward sustainability with more use of renewable energy. Therefore, this study aims to assess the indicators of sustainable energy, explore benefits of sustainable energy and evaluate strategies to enhance energy sustainability in line with Sustainable Development Goal (SDG) 7.

Quantitative research strategy was adopted. Questionnaires were developed and administered through convenience and snowball sampling techniques to professionals in the energy sector. Data collected was validated by using Cronbach’s alpha coefficient and discriminant validity, whereas objectives were analyzed by using the relative importance index, mean score ranking and Kruskal–Wallis test.

From the findings, the significant indicators of sustainable energy were as follows: reduction in greenhouse gas emissions from energy production, use of renewable energies and policies on proper utilization of energy resources. Furthermore, a reduction in greenhouse gas emissions, less harm caused to the environment and an increase in the economic and social development process were the major benefits of sustainable energy. Finally, the findings of the study revealed that a strong and accounted policy program, adopting sustainable energy indicators and strategic communication are the significant strategies needed to be put in place to enhance energy sustainability.

The study serves as a reminder to policymakers of the crucial role they have to play in enhancing energy sustainability by putting in place suitable policy programs and methods.

The originality of this study is that it is arguably a pioneering study in Ghana and contributes to the body of knowledge on energy sustainability.

This study aims to investigate the impact of Holland’s theory of career choice (RIASEC [realistic, investigative, artistic, social, enterprising and conventional]) on the entrepreneurial event model (EEM) and the agropreneurial intention among university students.

This study is quantitative research, and 772 undergraduate students from public and private universities in Malaysia participated. The data were then analysed using SmartPLS 4.

The statistical analysis revealed that the realistic, artistic, enterprising and conventional in Holland’s theory of career choice (RIASEC) are antecedents of perceived desirability and feasibility, which has an indirect effect on agropreneurial intention. Additionally, all dimensions of EEM have a direct effect on agropreneurial intention.

Despite the importance of agriculture in providing food security and reducing poverty, especially in rural areas, there is very limited empirical research in this area. Notably, most of the research on the intention to become an entrepreneur is general entrepreneurship. This study, therefore, undertakes an interventionist role to investigate the factors influencing agropreneurial intention among youth.