Search results

1 – 8 of 8
Article
Publication date: 22 November 2023

Khishn Kumar Kandiah, Vengadaesvaran Balakrishnan, Amirul Syafiq, Nasrudin Abd Rahim, Adarsh Kumar Pandey, Yee Seng Tan, Sanjay J Dhoble, Ramesh Kasi and Ramesh Subramaniam

There is a strong inducement to develop new inorganic materials to substitute the current industrial pigments, which are known for their poor ultraviolet absorbent and low…

Abstract

Purpose

There is a strong inducement to develop new inorganic materials to substitute the current industrial pigments, which are known for their poor ultraviolet absorbent and low photoluminescence (PL) properties. The purpose of this paper is to invent a better rare-earth-based pigment material as a spectral modifier with good luminescence properties to enhance the spectral response for photovoltaic panel application.

Design/methodology/approach

Different phosphor samples made of nano-calcium carbonate (CaCO3) with varied wt.% of the dopant Dysprosium doped calcium borophosphate (CBP/Dy) as (W0 – 0%, W1 – 3,85%, W2 – 7.41%, W3 –10.71% and W4 –13.79%) were prepared via the solid-state diffusion method at 600 °C for 6 h using a muffle furnace. The structural, morphological and luminescence properties of the CaCO3:CBP/Dy powder samples were examined using scanning electron microscopy (SEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) and PL test.

Findings

The XRD, SEM and FTIR results verified the crystalline formation, morphological behaviour and vibration bonds of synthesized CBP/Dy-doped CaCO3 powder samples. XRD pattern revealed that the synthesized powder samples exhibit crystalline structured materials, and SEM results showed irregular shape and porous-like structured morphologies. FTIR spectrum shows prominent bands at 712, 874 and 1,404 cm−1, corresponding to asymmetric stretching vibrations of CO32− groups and out-of-plane bending. PL characterization of CBP/Dy-doped CaCO3 (sample W) shows emission at 427 nm (λmax) under the excitation of 358 nm. The intensity of PL emission spectra drops due to the concentration quenching effect, while the maximum PL intensity is observed in the W3 phosphor powder system.

Research limitations/implications

This phosphor powder is expected to find out the potential application such as a spectral modifier which is applied to match the energy of photons with solar cell bandgap to improve spectral absorption and lead to better efficiency.

Originality/value

The introduction of a nano-CaCO3:CBP/Dy hybrid powder system with good luminescence properties to be used as spectral modifiers for solar cell application has been synthesized in the lab, which is a novel attempt.

Details

Pigment & Resin Technology, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 29 September 2023

Junjian Lu, Hongbin Zhong and Fei Luo

The purpose of this research is as follows: DPP-BOH-PVA has been synthesized from 1,1′:3′,1″-terphenyl-5'-boronic acid (DPP-OH) and polyvinyl alcohol (PVA). The afterglow lifetime…

Abstract

Purpose

The purpose of this research is as follows: DPP-BOH-PVA has been synthesized from 1,1′:3′,1″-terphenyl-5'-boronic acid (DPP-OH) and polyvinyl alcohol (PVA). The afterglow lifetime of DPP-BOH-PVA was studied by changing contents of DPP-OH (1, 2 and 4 Wt.%). These films were characterized with Fourier transform infrared, X-ray diffraction as structural analysis and DSC as thermal analysis. Afterglow lifetimes were evaluated as time-resolved emission decay profile analysis. Fiber films of DPP-BOH-PVA-2-E have been prepared by electrospinning method with the diameter of 5 μm and afterglow life time of 2.1 s (@ 535 nm) under ambient conditions. Stimulus responsive properties with afterglow emission for fiber film were investigated.

Design/methodology/approach

During the synthesis of the polymer, modification was carried out using DPP-OH/PVA with a molar ratio of 1/4, under an alkalinity medium with ammonium hydroxide and with a temperature of 80°C.

Findings

XRD results indicate that DPP-BOH-PVA film had high crystallinity, which is crucial for preparing organic room temperature phosphorescence (RTP) materials.

Research limitations/implications

The reaction mixture must be stirred continuously. Temperature should be controlled to prevent the rapid evaporation of ammonium hydroxide.

Practical implications

This study provides technical information for the synthesis of multidimensional stimulation response RTP micron fiber thin film. The electrospinning technology may also promote the applications of the large areas of RTP films.

Social implications

This resin will be used for the multidimensional stimulation response RTP fiber thin film.

Originality/value

The diameter of fiber film of PP-BOH-PVA-2-E by electrospinning method was in the range of 5 μm, and its afterglow lifetime decayed to be 2.1 s.

Details

Pigment & Resin Technology, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 30 April 2024

Sophie van Roosmale, Amaryllis Audenaert and Jasmine Meysman

This paper aims to highlight the expanding link between facility management (FM) and building automation and control systems (BACS) through a review of literature. It examines the…

Abstract

Purpose

This paper aims to highlight the expanding link between facility management (FM) and building automation and control systems (BACS) through a review of literature. It examines the opportunities and challenges of BACS for facility managers and proposes solutions for mitigating the risks associated with BACS implementation.

Design/methodology/approach

This paper reviews various research papers to explore the positive influences of BACS on FM, such as support with strategic decision-making, predictive maintenance, energy efficiency and comfort improvement. It also discusses the challenges of BACS, including obsolescence, interoperability, vendor lock-in, reliability and security risks and suggests potential solutions based on existing literature.

Findings

BACS offers numerous opportunities for facility managers, such as improved decision-making, energy efficiency and comfort levels in office buildings. However, there are also risks associated with BACS implementation, including obsolescence, interoperability, vendor lock-in, reliability and security risks. These risks can be mitigated through measures such as hardware and software obsolescence management plans, functional requirement lists, wireless communication protocols, advanced feedback systems and increased awareness about BACS security.

Originality/value

To the best of the authors’ knowledge, no prior academic research has been conducted on the expanding link between FM and BACS. Although some papers have touched upon the opportunities and challenges of BACS for FM, this paper aims to provide a comprehensive overview of these findings by consolidating existing literature.

Details

Facilities , vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0263-2772

Keywords

Article
Publication date: 29 April 2024

Mohd Hasfarisham Abd Halim, Nor Khairunnisa Talib, Shyeh Sahibul Karamah Masnan and Mokhtar Saidin

This study was conducted with the main purpose of recording primary data related to environmental factors, which has become the main criteria in the selection of the Sungai Batu…

Abstract

Purpose

This study was conducted with the main purpose of recording primary data related to environmental factors, which has become the main criteria in the selection of the Sungai Batu Archaeological Complex (SBAC) as the center of the iron smelting industry and trade in ancient Kedah.

Design/methodology/approach

To fulfill this purpose, field studies involving drone photogrammetry mapping, augering, core drilling and geophysical mapping methods were carried out.

Findings

The results obtained through the application of the method have shown that SBAC has a good environment, which has a wide and deep river flow, the existence of Mount Jerai and the abundance of iron ores, mangrove Merbok and clay.

Research limitations/implications

Resources did not allow for environment studies of the by-products tourism sites as part of the current study.

Practical implications

The study also included a survey and mapping to obtain potential primary data around SBAC in the process of developing it as the center of the world iron industry.

Social implications

One finding is that attention to heritage policy and protection must be ongoing at all levels of government and the local community to ensure that the survey and mapping data carried out can be developed as a sustainable heritage tourism product.

Originality/value

This study reveals primary data related to the suitability of paleoenvironment in the SBAC development process as a world iron smelting industry area.

Details

Journal of Cultural Heritage Management and Sustainable Development, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 2044-1266

Keywords

Article
Publication date: 6 November 2023

Huda Abdullah, Norshafadzila Mohammad Naim, Kok Seng Shum, Aidil Abdul Hamid, Mohd Hafiz Dzarfan Othman, Vidhya Selvanathan, Wing Fen Yap and Seri Mastura Mustaza

Regular monitoring of bacteria, especially Escherichia coli, in wastewater is crucial to ensure the maintenance of public health. Amperometric detection proves to be a fast…

Abstract

Purpose

Regular monitoring of bacteria, especially Escherichia coli, in wastewater is crucial to ensure the maintenance of public health. Amperometric detection proves to be a fast, sensitive and economically viable solution for E. coli enumeration. This paper reported a prototype amperometric sensor based on PANI-ZnO-NiO nanocomposite thin films prepared by sol–gel method and irradiated with gamma ray. The purpose of this study is to investigate the sensor performance of PANI-ZnO-NiO nanocomposite thin films to detect E. coli in water.

Design/methodology/approach

The films were varied with different compositions of ZnO and NiO by using the formula PANI-(ZnO)1-x-(NiO)x, with x = 0.2, 0.4, 0.6 and 0.8. PANI-ZnO-NiO nanocomposite thin films were characterized by using X-ray diffraction (XRD) and atomic force microscopy (AFM) to study the crystallinity and surface morphology of the films. The sensor performance was conducted using the current–voltage (I-V) measurement by testing the films in clean water and E. coli solution.

Findings

XRD diffractograms show the peaks of ZnO (1 0 0) and NiO (1 0 2). AFM analysis shows the surface roughness, and the grain size of PANI-ZnO-NiO thin films decreases when the concentration ratios of NiO increased. I-V curves show the difference in current flow, where the current in E. coli solution is higher than the clean water.

Originality/value

PANI-(ZnO)1-x-(NiO)x nanocomposite thin film with the highest concentration of ZnO performed the highest sensitivity among the other concentrations, which can be used to indicate the presence of E. coli bacteria in water.

Details

Pigment & Resin Technology, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 21 December 2022

Liliya Frolova and Olga Sergeyeva

This paper aims to develop a simple and efficient plasma technology for the production of copper (I) oxide with the ability to control the morphology and size of Cu2O particles…

Abstract

Purpose

This paper aims to develop a simple and efficient plasma technology for the production of copper (I) oxide with the ability to control the morphology and size of Cu2O particles. To achieve this goal, the phase composition of the precipitate formed was estimated, the composition and size of the obtained particles were determined and Pourbaix diagrams were constructed.

Design/methodology/approach

An integrated approach combining thermodynamic calculations and experimental research methods is used. The constructed Pourbaix diagram makes it possible to suggest the phase composition of the sediment. The use of cyclic voltammetry made it possible to establish the mechanism of deposit formation on the cathode during the treatment of the solution with contact nonequilibrium low-temperature plasma. The resulting product was examined using X-ray phase analysis and scanning electron microscopy.

Findings

The article presents the results of theoretical and experimental studies on the synthesis of copper (II) oxide. The influence of the parameters of plasma-chemical synthesis on the shape and phase composition of the deposits formed has been studied.

Originality/value

A plasma-chemical technology for obtaining copper oxide in the form of single crystals of a regular faceted shape is proposed. The mechanism of formation of copper oxide has been established by cyclic voltammetry. The constructed Pourbaix diagrams show the area of existence of the product.

Details

Pigment & Resin Technology, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 8 June 2023

Kawaljit Singh Randhawa

The purpose of this study is to look into the hygroscopic and tribo-mechanical properties of a polypropylene/polyamide-6 (PP/PA6) blend and a PP/PA6/Boron sesquioxide composite.

Abstract

Purpose

The purpose of this study is to look into the hygroscopic and tribo-mechanical properties of a polypropylene/polyamide-6 (PP/PA6) blend and a PP/PA6/Boron sesquioxide composite.

Design/methodology/approach

The hygroscopic behaviour of the PP/PA6 blend and PP/PA6/Boron sesquioxide composite was studied using a water contact angle goniometer in this study. To validate the hygroscopic behaviour of the blend and composite, water contact angles and surface energy of the materials were investigated. Tensile strength and hardness tests were used to determine mechanical characteristics, and tribological experiments on a pin-on-disc tribometer were used to demonstrate the friction and wear rates of dry and water-conditioned blends and composites. The melting temperature of dry and water-conditioned composites was determined using DSC analysis.

Findings

The hygroscopic effect of the PP/PA6 blend was found to be minimal in the experiment, while it was relatively dominating in the PP/PA6/Boron sesquioxide composite. Tensile strength was found to be somewhat lower in blend and composite compared to virgin PP, whereas hardness was found to be higher in both blend and composite. The composite’s tribological testing findings were fairly outstanding, with the coefficient of friction (COF) and wear rates significantly reduced due to boron sesquioxide reinforcement. The reaction between boron sesquioxide and water molecules produced boric acid, which increased the tribological characteristics of the composite even further. Following 30 days of water conditioning, the weight of the blend increased by 3.64% and the weight of the composite increased by 6.45% as compared to the dry materials. After water conditioning, tensile strength reduced by 0.8% for the blend and 14.16% for the composite. Hardness was determined to be the same in the dry state and after water-conditioning for blend but dropped 1% for composite. As compared to blend, the COF and wear resistance of composite were 15.52% and 25.16% higher, respectively. After absorbing some water, the results increased to 28.57% and 34.9%, respectively.

Originality/value

The mechanical and thermal behaviour of polymer composites (particularly polyamide composites) vary depending on the surrounding environment. Tests were carried out to explore the effect of water treatment on the tribo-mechanical and thermal characteristics of PP/PA6/Boron sesquioxide composite. Water treatment caused polyamides to bind with water molecules, resulting in voids in the material. The interaction between boron sesquioxide and water molecules produced boric acid, which increased the tribological characteristics of the composite.

Details

Pigment & Resin Technology, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 11 October 2021

H.N.K. Al-Salman, Qutaiba A. Qasim, Rajaa Hussein Fayadh and Hussein H. Hussein

The purpose of this study is to establish Loratadine [LRD] quantification in purified and capsule formulations using a precise and specific Reversal Phase with a very…

Abstract

Purpose

The purpose of this study is to establish Loratadine [LRD] quantification in purified and capsule formulations using a precise and specific Reversal Phase with a very high-performance liquid Chromatographic [RP-HPLC] technique. The approach was evaluated in agreement with the principles of the International Conference on Harmonization [ICH]. Arcus EP-C18 Ion Pac column, 5 m, 4.6 mm, 250 mm, mobile phase Methanol: Acetonitrile (60:40) v/v. Dibasic potassium phosphate buffer, pH 7.2, flow rate 1.0 ml/min.

Design/methodology/approach

The HPLC system used a 340 nm UV detector for testing. A 10-min run time was used for the analysis. At concentrations ranging from 2 to 10 g/ml, the technique was linear (R2 = 0.9998), exact (intra-day and inter-day relative standard deviation [RSD] values 1.0%), accurate (range recovery = 96%–102%), exclusive and strong.

Findings

The detecting and quantitation limits were 0.92 g/ml and 2.15 g/ml, respectively.

Originality/value

The findings demonstrated that the proposed method could accurately determine LRD in bulk and pill dose formats quickly and accurately.

Details

International Journal of Human Rights in Healthcare, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 2056-4902

Keywords

1 – 8 of 8