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Article
Publication date: 23 August 2021

Kawaljit Singh Randhawa and Ashwin Patel

The absorption of moisture/water can affect the mechanical and thermal properties of polymers and polymer composites as many polymers, mainly polyamide thermoplastics, are…

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Abstract

Purpose

The absorption of moisture/water can affect the mechanical and thermal properties of polymers and polymer composites as many polymers, mainly polyamide thermoplastics, are sensitive to environmental humidity and can absorb a large amount of moisture. This paper investigates the effect of water molecules' absorption on mechanical and thermal properties of polyamide6/hexagonal boron nitride (PA6/h-BN) composites.

Design/methodology/approach

The PA6/h-BN composites were exposed to an open environment and water for 15 days to analyse the effect of humidity/water molecules' absorption on mechanical and thermal properties. The tensile strength, hardness and impact strength of materials were measured and compared. The scanning electron microscopy (SEM), x-ray diffraction (XRD) and differential scanning calorimetry (DSC) analyses were utilized to see the influence of water absorption on microstructure, crystallinity and glass transition temperatures.

Findings

After exposing materials to an open environment and water, the tensile strength and hardness were found to decline, while improvement in impact strength was noticed. SEM characterization revealed the formation of voids/pockets in water-immersed materials. DSC analysis revealed the loss in glass transition temperatures, and XRD analysis revealed the loss in crystallinity of water-immersed materials.

Originality/value

Environmental conditions vary according to the geographical areas, and it varies in many countries throughout the year. Polyamides are sensitive to the environmental humidity and can absorb a large amount of moisture from the environment. It becomes necessary to test these materials in their original working conditions, and sometimes it is mandatory to see the effects of extreme environmental conditions on a component. In this article, efforts have been made to investigate the influence of extreme humidity/water conditions on thermo-mechanical properties of PA6/h-BN composites.

Details

International Journal of Structural Integrity, vol. 12 no. 5
Type: Research Article
ISSN: 1757-9864

Keywords

Article
Publication date: 5 August 2021

Kawaljit Singh Randhawa and Ashwin Patel

This paper aims to investigate the tribological performance, i.e. abrasion resistance, friction coefficient and wear rates, of self-lubricated water conditioned polyamide6/boric…

98

Abstract

Purpose

This paper aims to investigate the tribological performance, i.e. abrasion resistance, friction coefficient and wear rates, of self-lubricated water conditioned polyamide6/boric oxide composites.

Design/methodology/approach

Polyamide6 and polyamide6/boric oxide self-lubricated composites were immersed in water for 15 days to analyze the effect of water conditioning on friction, wear and abrasion resistance. Tribological testing on pin-on-disc tribometer and abrasion resistance testing on TABER abrader were performed to see the friction coefficient and wear rates of materials. The scanning electron microscopy (SEM) characterizations were performed to analyze the wear tracks.

Findings

Tribological testing results revealed the loss in abrasive resistance, but there was an improvement in frictional coefficient and wear rates with steel after water absorption. The SEM images clearly show less depth of wear tracks in water-conditioned materials than dry ones. Water conditioning was found supportive in the formation of smooth lubricating transfer film on steel disc during the tribological testing.

Originality/value

The tribological behaviour of polymer composites is different in dry and in high humidity or water conditions. Experiments were performed to investigate B2O3 solid lubricant filler effectiveness on tribological behaviour of water-conditioned polyamide composites. Bonding between polyamide6 and water molecules plus the formation of orthoboric acid was found advantageous in decreasing the friction coefficient and wear rates of composites.

Details

Pigment & Resin Technology, vol. 51 no. 4
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 12 July 2021

Kawaljit Singh Randhawa and Ashwin Patel

This paper aims to investigate the mechanical and thermal behavior, i.e. tensile strength, hardness, impact strength and glass transition temperatures of water-treated…

Abstract

Purpose

This paper aims to investigate the mechanical and thermal behavior, i.e. tensile strength, hardness, impact strength and glass transition temperatures of water-treated polyamide6/boric oxide (PA) composites.

Design/methodology/approach

The PA6 and PA6/boric oxide composites were exposed to an open environment and immersed in water for 15 days to analyze the effect of environmental humidity and frequent water immersion conditions on the composite’s mechanical and thermal properties. The tensile strength, elastic modulus, hardness and impact strength of materials were measured to identify the mechanical properties. The scanning electron microscopy (SEM), X-ray diffraction (XRD) and differential scanning calorimetry (DSC) characterizations were used to see the effect of humidity/water absorption on microstructure, crystallinity and glass transition temperatures.

Findings

The testing results revealed the loss in strength, elastic modulus and hardness, while the impact resistance was improved after exposure of materials to humidity/water. SEM images clearly show the formation of voids and XRD graphs revealed the loss in crystallinity after water immersion. The DSC plots of water immersed materials revealed the loss of glass transition temperatures up to 15°C.

Originality/value

The mechanical and thermal behavior of PA composites varies according to the surrounding atmosphere. Experiments were performed to investigate the influence of water treatment on the PA6/B2O3 composite’s mechanical and thermal properties. Water treatment resulted in the bonding between PA and water molecules, which generated voids in the materials. These voids generations are found the main reason for the low strength and hardness of water-treated materials.

Details

Pigment & Resin Technology, vol. 51 no. 3
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 8 June 2023

Kawaljit Singh Randhawa

The purpose of this study is to look into the hygroscopic and tribo-mechanical properties of a polypropylene/polyamide-6 (PP/PA6) blend and a PP/PA6/Boron sesquioxide composite.

Abstract

Purpose

The purpose of this study is to look into the hygroscopic and tribo-mechanical properties of a polypropylene/polyamide-6 (PP/PA6) blend and a PP/PA6/Boron sesquioxide composite.

Design/methodology/approach

The hygroscopic behaviour of the PP/PA6 blend and PP/PA6/Boron sesquioxide composite was studied using a water contact angle goniometer in this study. To validate the hygroscopic behaviour of the blend and composite, water contact angles and surface energy of the materials were investigated. Tensile strength and hardness tests were used to determine mechanical characteristics, and tribological experiments on a pin-on-disc tribometer were used to demonstrate the friction and wear rates of dry and water-conditioned blends and composites. The melting temperature of dry and water-conditioned composites was determined using DSC analysis.

Findings

The hygroscopic effect of the PP/PA6 blend was found to be minimal in the experiment, while it was relatively dominating in the PP/PA6/Boron sesquioxide composite. Tensile strength was found to be somewhat lower in blend and composite compared to virgin PP, whereas hardness was found to be higher in both blend and composite. The composite’s tribological testing findings were fairly outstanding, with the coefficient of friction (COF) and wear rates significantly reduced due to boron sesquioxide reinforcement. The reaction between boron sesquioxide and water molecules produced boric acid, which increased the tribological characteristics of the composite even further. Following 30 days of water conditioning, the weight of the blend increased by 3.64% and the weight of the composite increased by 6.45% as compared to the dry materials. After water conditioning, tensile strength reduced by 0.8% for the blend and 14.16% for the composite. Hardness was determined to be the same in the dry state and after water-conditioning for blend but dropped 1% for composite. As compared to blend, the COF and wear resistance of composite were 15.52% and 25.16% higher, respectively. After absorbing some water, the results increased to 28.57% and 34.9%, respectively.

Originality/value

The mechanical and thermal behaviour of polymer composites (particularly polyamide composites) vary depending on the surrounding environment. Tests were carried out to explore the effect of water treatment on the tribo-mechanical and thermal characteristics of PP/PA6/Boron sesquioxide composite. Water treatment caused polyamides to bind with water molecules, resulting in voids in the material. The interaction between boron sesquioxide and water molecules produced boric acid, which increased the tribological characteristics of the composite.

Details

Pigment & Resin Technology, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 17 April 2023

Kawaljit Singh Randhawa

The purpose of this study is to prepare a state-of-the-art review on advanced ceramic materials including their fabrication techniques, characteristics, applications and…

Abstract

Purpose

The purpose of this study is to prepare a state-of-the-art review on advanced ceramic materials including their fabrication techniques, characteristics, applications and wettability.

Design/methodology/approach

This review paper presents the various types of advanced ceramic materials according to their compounding elements, fabrication techniques of advanced ceramic powders as well as their consolidation, their characteristics, applications and wetting properties. Hydrophobic/hydrophilic properties of advanced ceramic materials are described in the paper with their state-of-the-art application areas. Optical properties of fine ceramics with their intrinsic characteristics are also presented within. Special focus is given to the brief description of application-based manipulation of wetting properties of advanced ceramics in the paper.

Findings

The study of wetting/hydrophobicity/hydrophilicity of ceramic materials is important by which it can be further modified to achieve the required applications. It also makes some sense that the material should be tested for its wetting properties when it is going to be used in some important applications like biomedical and dental. Also, these advanced ceramics are now often used in the fabrication of filters and membranes to purify liquid/water so the study of wetting characteristics of these materials becomes essential. The optical properties of advanced ceramics are equally making them suitable for many state-of-the-art applications. Dental, medical, imaging and electronics are the few sectors that use advanced ceramics for their optical properties.

Originality/value

This review paper includes various advanced ceramic materials according to their compounding elements, different fabrication techniques of powders and their consolidation, their characteristics, various application area and hydrophobic/hydrophilic properties.

Details

Pigment & Resin Technology, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 17 May 2021

Abhishek Vyas and Kawaljit Singh Randhawa

The purpose of this study is to improve the mechanical and tribological performance of polypropylene (PP) material. The influence of hexagonal boron nitride (h-BN) microparticles…

Abstract

Purpose

The purpose of this study is to improve the mechanical and tribological performance of polypropylene (PP) material. The influence of hexagonal boron nitride (h-BN) microparticles on mechanical and tribological properties of PP/polyamide 6 (nylon 6) (PA6) blend has been investigated in this paper.

Design/methodology/approach

Tensile strength, elongation, elastic modulus and Rockwell hardness were measured to identify the mechanical properties of materials. Coefficient of friction (COF) and wear rates of materials were measured with the help of a pin-on-disc tribometer to check the tribological behavior of blend and composite materials.

Findings

As a result, a small decrease in tensile strength and elongation and improvement in elastic modulus were found for PP/PA6 and PP/PA6/h-BN composite compared to pure PP. The wear rate of PP/PA6 blend and PP/PA6/h-BN composite was found low compared to pure PP matrix, while the COF of PP/PA6 blend was found slightly higher owing to the presence of harder PA6 matrix which was then improved by the h-BN filler reinforcement in PP/PA6/h-BN composite. The addition of PA6 in PP improved the wear rate of PP by 8–24%, whereas the addition of h-BN microparticles improved the wear rate by 22–50% and 24–44% compared to pure PP and PP/PA6 blend, respectively, in different parameters.

Originality/value

Modulus of elasticity and hardness of pure PP was enhanced by blending with PA6 and was further improved by h-BN fillers. The addition of PA6 in PP improved the wear rate, while h-BN fillers were found effective in reducing the COF by generating smooth thin lubricating film.

Details

World Journal of Engineering, vol. 18 no. 6
Type: Research Article
ISSN: 1708-5284

Keywords

Article
Publication date: 19 July 2021

Kawaljit Singh Randhawa and Ashwin Patel

The mechanical and tribological properties of polymers and polymer composites vary with different environmental conditions. This paper aims to review the influence of…

Abstract

Purpose

The mechanical and tribological properties of polymers and polymer composites vary with different environmental conditions. This paper aims to review the influence of humidity/water conditions on various polymers and polymer composites' mechanical properties and tribological behaviors.

Design/methodology/approach

The influence of humidity and water absorption on mechanical and tribological properties of various polymers, fillers and composites has been discussed in this paper. Tensile strength, modulus, yield strength, impact strength, COF and wear rates of polymer composites are compared for different environmental conditions. The interaction between the water molecules and hydrophobic polymers is also represented.

Findings

Pure polymer matrices show somewhat mixed behavior in humid environments. Absorbed moisture generally plasticizes the epoxies and polyamides and lowers the tensile strength, yield strength and modulus. Wear rates of PVC generally decrease in humid environments, while for polyamides, it increases. Fillers like graphite and boron-based compounds exhibit low COF, while MoS2 particulate fillers exhibit higher COF at high humidity and water conditions. The mechanical properties of fiber-reinforced polymer composites tend to decrease as the rate of humidity increases while the wear rates of fiber-reinforced polymer composites show somewhat mixed behavior. Particulate fillers like metals and advanced ceramics reinforced polymer composites exhibit low COF and wear rates as the rate of humidity increases.

Originality/value

The mechanical and tribological properties of polymers and polymer composites vary with the humidity value present in the environment. In dry conditions, wear loss is determined by the hardness of the contacting surfaces, which may not effectively work for high humid environments. The tribological performance of composite constituents, i.e. matrix and fillers in humid environments, defines the overall performance of polymer composite in said environments.

Details

Industrial Lubrication and Tribology, vol. 73 no. 9
Type: Research Article
ISSN: 0036-8792

Keywords

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