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This paper aims to investigate the impact of three different flow channel cross sections on the performance of the fuel cell.

A comprehensive three-dimensional polymer electrolyte membrane fuel cell model has been developed, and a set of conservation equations has been solved. The flow is assumed to be steady, fully developed, laminar and isothermal. The investigated cross sections are the commonly used square cross section, the increasingly used trapezoidal cross section and a novel hybrid configuration where the cross section is square at the inlet and trapezoidal at the outlet.

The results show that a slight gain is obtained when using the hybrid configuration and this is because of increased velocity, which improves the supply of the reactant gases to the catalyst layers (CLs) and removes heat and excess water more effectively compared to other configurations. Further, the reduction of the outlet height of the hybrid configuration leads to even better fuel cell performance and this is again because of increased velocity in the flow channel.

The data generated in this study will be highly valuable to engineers interested in studying the effect of fluid cross -sectional shape on fuel cell performance.

This study proposes a novel flow field with a variable cross section. This design can supply a higher amount of reactant gases to the CLs, dissipates heat and remove excess water more effectively.

This study aims to prepare an imprinted composite membrane with grafted temperature-sensitive blocks for the efficient adsorption and separation of rhenium(Re) from aqueous solutions.

PVDF resin membrane was used as the substrate, dopamine and chitosan (CS) were used to modify the membrane surface and temperature-sensitive block PDEA was grafted on the membrane surface. Then acrylic acid (AA) and N-methylol acrylamide (N-MAM) were used as the functional monomers, ethyleneglycol dimethacrylate (EGDMA) as the cross-linker and ascorbic acid-hydrogen peroxide (Vc-H₂O₂) as the initiator to obtain the temperature-sensitive ReO4⁻ imprinted composite membranes.

The effect of the preparation process on the performance of CS–Re–TIICM was investigated in detail, and the optimal preparation conditions were as follows: the molar ratios of AA–NH₄ReO₄, N-MAM and EGDMA were 0.13, 0.60 and 1.00, respectively. The optimal temperature and time of the reaction were 40 °C and 24 h. The maximum adsorption capacity of CS–Re–TIICM prepared under optimal conditions was 0.1071 mmol/g, and the separation was 3.90 when MnO4⁻ was used as the interfering ion. The quasi first-order kinetics model and Langmuir model were more suitable to describe the adsorption process.

With the increasing demand for Re, the recovery of Re from Re-containing secondary resources becomes important. This study demonstrated a new material that could be separated and recovered Re in a complex environment, which could effectively alleviate the conflict between the supply and demand of Re.

This contribution provided a new material for the selective separation and purification of ReO4⁻, and the adsorption capacity and separation of CS–Re–TIICM were increased with 1.673 times and 1.219 time compared with other Re adsorbents, respectively. In addition, when it was used for the purification of NH₄ReO₄ crude, the purity was increased from 91.950% to 99.999%.

Reliable estimations of the extent of corrosion and time required to reach specific safety limits are crucial for assessing the reliability of aging reinforced concrete (RC) bridges. Engineers and decision-makers can use these figures to plan suitable inspection and maintenance operations.

Analytical, empirical and numerical approaches for estimating the service life of corroded RC structures were presented and compared. The concrete cover cracking times, which were predicted by the previously proposed analytical models, were compared with the experimentally obtained cracking times to identify the model/s for RC bridges. The shortcomings and limitations of the existing models are discussed.

The empirical models typically depend on the rate of corrosion, diameter of steel reinforcement and concrete cover depth and based on basic mathematical formula. In contrast, the analytical and numerical models contain the strength and stiffness properties of concrete as well as type of corrosion products and incorporate more complex mechanical factors. Four existing analytical models were analyzed and their performance was evaluated against existing experimental data in literature. All the considered analytical models were assumed thick-walled cylinder models. The maximum difference between observed cracking time from different test data and calculated cracking time using the developed models is 36.5%. The cracking times extend with increase in concrete cover and decrease with corrosion current density. The development of service life prediction models that considers factors such as heterogeneity of concrete, non-uniform corrosion along rebar, rust production rate and a more accurate representation of the corrosion accommodating region are some of the areas for further research.

Outcome of this paper partially bridge the gap between theory and practice, as it is the basis to estimate the serviceability of corrosion-affected RC structures and to propose maintenance and repair strategies for the structures. For structural design and evaluation, the crack-width criterion is the greatest practical importance, and structural engineers, operators and asset managers should pay close attention to it. Additionally, repair costs for corrosion-induced serviceability failures, particularly concrete cracking and spalling, are significantly higher than those for strength failures. Therefore, to optimize the maintenance cost of RC structures, it is essential to precisely forecast the serviceability of corrosion-affected concrete structures. The lifespan of RC structures may be extended by timely repairs. This helps stake holders to manage the resources.

In order to improve modeling of corrosion-induced cracking, important areas for future research were identified. Heterogeneity properties of concrete, concept of porous zone (accommodation effect of pores should be quantified), actual corrosion morphology (non-uniform corrosion along the length of rebar), interaction between sustain load and corrosions were not considered in existing models. Therefore, this work suggested for further researches should consider them as input and develop models which have best prediction capacity.

This work has positive impact on society and will not affect the quality of life. Predicting service life of structures is necessary for maintenance and repair strategy plans. Optimizing maintenance strategy is used to extend asset life, reduce asset failures, minimize repair cost, and improve health and safety for society.

The degree of accuracy and applicability of the existing service life prediction models used for RC were assessed by comparing the predicted cracking times with the experimentally obtained times reported in the literature. The shortcomings of the models were identified and areas where further research is required are recommended.

In recent years, using aberration-corrected transmission electron microscopy, the authors have achieved precisely detecting the structural evolution of passive film as well as its interface zone at atomic scale. The purpose of this paper aims to make a brief review to show the authors’ new understanding and perspective on the issue of critical factors determining stability of passive film of Fe-Cr alloy.

The introduction of single crystal enabled the authors to obtain a distinct metal/passive film interface and better characterize the structure of the interface region. The authors use aberration-corrected TEM to conduct cross-sectional observation and directly capture the details across the entire film at a high spatial and energy resolution.

Apart from the passive film itself, the interface zone, including metal/film (Me/F) interface and the adjacent metal side, is also the site which is attacked. Accordingly, the nature of the interface zone, such as microstructure, composition and atomic configuration, is one of the critical factors determining the stability of passive film.

Deciphering the critical factors determining the stability of passive film is of great significance and has been a fundamental issue in corrosion science. Great attention has been paid to the nature of the passive film itself. In contrast, the possible role of the interface between the passive film and the metal is rarely taken into account. Based on the advanced analytical tool with high spatial resolution, the authors have specified the significant role of interface structures on the macro-scale stability of passive film.

The theoretical findings serve as a foundation for further research into understanding sulfide-based solid-state electrolytes, ultimately advancing the progress of all-solid-state batteries.

The electronic properties of Li₇P₃S₁₁ are thoroughly explored through first-principles calculations.

This investigation encompasses the intricate atom-dominated valence and conduction bands, spatial charge density distribution and the breakdown of atom and orbital contributions to van Hove singularities. Additionally, the compound’s wide and discrete energy spectra reflect the substantial variations in bond lengths and its highly anisotropic geometric structure. The complex and nonuniform chemical environment indicates the presence of intricate hopping integrals.

This study provides valuable insights into the critical multiorbital hybridizations occurring in the Li-S and P-S chemical bonds. To validate the theoretical predictions, experimental techniques can be employed. By combining theoretical predictions with experimental data, a comprehensive understanding of the geometric and electronic characteristics of Li₇P₃S₁₁ can be achieved.

The purpose of this paper is to study the corrosion behavior of Q235 steel in saturated acidic red and yellow soils.

The corrosion behavior of Q235 steel in saturated red and yellow soils was compared by weight-loss, SEM/EDS, 3D ultra-depth microscopy and electrochemical measurements.

R_p of the steel gradually increases and i_corr gradually decreases in both the red and yellow soils with time. The R_p of the steel in the red soil is lower, but its i_corr is higher than that in the yellow soil. The uniform corrosion rate, diameter and density of the corrosion pit on the steel surface in the red soil are greater than those in the yellow soil. Lower pH, higher contents of corrosive anions and high-valence Fe oxides in the red soil are responsible for its higher corrosion rates and local corrosion susceptibility.

This paper investigates the difference in corrosion behavior of carbon steel in saturated acidic red and yellow soils, which can help to understand the mechanism of soil corrosion.

The authors investigated how emotional intelligence (EI) affects the relationship between project managers' (PMgs) expertise and experience and project success for both the team and client.

This study collected 290 valid responses from IT project managers. The results were analyzed using an ordinary least squares (OLS) regression, with Process v4.0 procedure and the Johnson-Neyman (JN) technique to assess the moderating effect of the level of EI.

Results showed that moderate levels of EI can enhance the impact of PMgs' experience on the project client, while higher levels of EI are necessary to positively impact the team. Moderate levels of EI can improve PMgs' expertise impact on the project team, increasing their effectiveness in interactions with clients and other stakeholders.

It is recommended to consider emotional intelligence alongside technical skills when selecting project managers to address emotional labor, stress, stakeholder management and agility. Providing EI training and experiential learning opportunities internally can improve project managers' emotional intelligence.

This study contributes to the literature on emotional intelligence and project management, highlighting the relationship between technical skills and emotional intelligence levels of PMgs. This research emphasizes the significance of experience and EI in project management, particularly in overseeing complex projects. Additionally, moderate levels of EI enhance PMgs' effectiveness in engaging with stakeholders closely involved in projects.

The purpose of this paper is to assess previous research on conditions for managers’ learning and development in daily work practices and how such conditions may influence their sustainability and also to propose a concept and a heuristic model that reconceptualizes and expands on the theoretical foundations generated in previous studies of managers’ learning and development at work.

This paper is based on an integrative literature review. The literature search identified 1,403 unique studies. Nine qualitative and seven quantitative studies met the relevance and quality criteria and were included in the review.

The results of the review found associations between managers’ learning conditions, career opportunities, individual engagement and sustainability. However, the small amount of empirical data used in the reviewed studies and the cross-sectional design of the studies make it difficult to establish the nature of the relationship between different variables.

The results of this paper show that managers need to care for and take advantage of opportunities for their own development and not only function as creators of their employees’ development. Employers should keep in mind that the development environment includes managers and employees.

This paper contributes with an original concept of managers’ development environments and a conceptual model that integrates theory with results from the included studies. Based on the model, propositions that may serve as an agenda for future research are formulated.

Incorporating pre-existing crack in service life prediction of reinforced concrete structures subjected to corrosion is crucial for accurate assessment, realistic modelling and effective decision-making in terms of maintenance and repair strategies.

An accelerated corrosion test was conducted by using impressed current method on cylindrical specimens with varying cover thickness and crack width. Mechanical properties of the specimens were evaluated by tensile tests.

The results show that, the pre-cracked samples exhibited shorter concrete cover cracking times, particularly with wider cracks when compared to the uncracked samples. Moreover, the load-bearing capacity of the reinforcement bars decreased owing to the pre-cracks, causing structural deflection and a shortened yield plateau. However, the ductility index remained consistent across all sample types, implying that the concrete had good overall ductility. Comparing the results of the non-corroded rebar and corroded rebar samples, the maximum reduction in the yield load was 25.22%, whereas the maximum reduction in the ultimate load was 26.23%. The simple mathematical model proposed in this study provides a reliable method for predicting the chloride ion diffusion coefficient in cracked concrete of existing reinforced concrete structures.

A simple mathematical model was proposed for evaluation of the equivalent chloride ion diffusion coefficient considering crack width, average crack spacing and crack extending lengths for cracked reinforced concrete structures, which is used to incorporate existing crack in service life prediction models.

Gas insulated systems, such as gas insulated lines (GIL), use insulating gas, mostly sulfur hexalfluoride (SF₆), to enable a higher dielectric strength compared to e.g. air. However, under high voltage direct current conditions, charge accumulation and electric field stress may occur, which may lead to partial discharge or system failure. Therefore, numerical simulations are used to design the system and determine the electric field and charge distribution. Although the gas conduction shows a more complex current–voltage characteristic compared to solid insulation, the electric conductivity of the SF₆ gas is set as constant in most works. The purpose of this study is to investigate different approaches to address the conduction in the gas properly for numerical simulations.

In this work, two approaches are investigated to address the conduction in the insulating gas and are compared to each other. One method is an ion-drift-diffusion model, where the conduction in the gas is described by the ion motion in the SF₆ gas. However, this method is computationally expensive. Alternatively, a less complex approach is an electro-thermal model with the application of an electric conductivity model for the SF₆ gas. Measurements show that the electric conductivity in the SF₆ gas has a nonlinear dependency on temperature, electric field and gas pressure. From these measurements, an electric conductivity model was developed. Both methods are compared by simulation results, where different parameters and conditions are considered, to investigate the potential of the electric conductivity model as a computationally less expensive alternative.

The simulation results of both simulation approaches show similar results, proving the electric conductivity for the SF₆ gas as a valid alternative. Using the electro-thermal model approach with the application of the electric conductivity model enables a solution time up to six times faster compared to the ion-drift-diffusion model. The application of the model allows to examine the influence of different parameters such as temperature and gas pressure on the electric field distribution in the GIL, whereas the ion-drift-diffusion model enables to investigate the distribution of homo- and heteropolar charges in the insulation gas.

This work presents numerical simulation models for high voltage direct current GIL, where the conduction in the SF₆ gas is described more precisely compared to a definition of a constant electric conductivity value for the insulation gas. The electric conductivity model for the SF₆ gas allows for consideration of the current–voltage characteristics of the gas, is computationally less expensive compared to an ion-drift diffusion model and needs considerably less solution time.