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This paper seeks to summarise the results of available research on the use of high velocity oxy‐fuel (HVOF) thermal‐spray technique to provide protection against high temperature corrosion and erosion‐corrosion of materials.

This paper describes one of the recent thermal‐spray processes, namely HVOF thermal‐spray technology and presents a survey of the studies on the use of this technique to provide protection against corrosion and erosion‐corrosion of high temperature alloys, with a special emphasis on boiler steels.

High temperature corrosion and erosion‐corrosion are serious problems observed in steam‐powered electricity generation plants, gas turbines, internal combustion engines, fluidized bed combustors, industrial waste incinerators and recovery boilers in paper and pulp industries. These problems can be prevented by changing the material or altering the environment, or by separating the component surface from the environment. Corrosion prevention by the use of coatings for separating materials from the environment is gaining importance in surface engineering. Amongst various surface modifying techniques, thermal spraying has developed relatively rapidly due to the use of advanced coating formulations and improvements in coating application technology. One of the variants of thermal spraying, namely HVOF has gained popularity in recent times due to its flexibility for in‐situ applications and superior coating properties.

This review covers mainly information that has been reported previously in the open literature, international journals and some well‐known textbooks.

The paper presents a concise summary of information for scientists and academics, planning to start their research work in the area of surface engineering.

This paper fulfils an identified information/resources need and offers practical help to an individual starting out on a career in the area of surface engineering for erosion‐corrosion and wear.

To examine the tensile properties of high velocity oxy‐fuel (HVOF) sprayed Inconel 625 coating of steel substrate before and after the aqueous corrosion.

Workpieces were cut from steel sheets. After chemical and ultrasonic cleaning, workpiece surfaces were sand blasted and HVOF sprayed Inconel 625 coated. The coated and un‐coated surfaces were subjected to the aqueous corrosion tests for one and three weeks. After the completion of the corrosion tests, tensile properties of the workpieces were examined.

The workpieces subjected to a three weeks static corrosion environment fail at a lower load than the untreated workpiece due to high stiffness. The defect sites in the coating and at the interface act as stress risers and contribute substantially crack initiation and propagation in the coating. Under increasing tensile load in the plastic region, the substrate material can no longer support the coating. This results in extended cracking and gradually spalling of the coat. When the local critical stress for crack propagation is reached, elongated cracks occur, which in turn initiates splitting separation between the adjacent zones in the coating. The shear deformation of the adjusted zones results in the total failures of the coating.

The tests can be extended to include the duplex treated workpieces such as the laser treatment of surface after HVOF sprayed coating. This enhances the bonding of the coating through thermal integration of the coating and the base substrate material.

The results can be used to assess the HVOF sprayed coatings.

This paper provides information on mechanical behavior of HVOF sprayed coating when subjected to the tensile force and offers practical help for the researchers and scientists working in the coating area.

The thermal spraying technique of High-Velocity Oxygen Fuel (HVOF) coating was used to deposit coatings of an alloy composed of Ni-based substrates on stainless steel AISI 304. The aim of this study was to determine the mechanical properties such as hardness and bond strength that these coatings have when the spray distance is varied, as well as the microstructure and phases formed during the thermal spray process.

The coatings were applied by HVOF and characterized by scanning electron microscopy, image analysis, X-ray diffraction, microhardness and bond strength to analyze the mechanical properties.

The microstructure of the coatings showed low porosity, oxide content and interface contamination in the substrate–coating interface, without the presence of unmolten particles. The microhardness values reached 600 HV for the three spray distances used and the bond strength values reached over 55 MPa.

The use of coatings on aircraft components is growing dramatically owing to the high costs of advanced materials and the growing lifecycle requirements for high-performance systems, which are taken into account because of the variety of coatings and complexity of environmental factors.

The originality of this study lies in the development of new coating materials for the manufacture and protection of various turbine components. The value is based on the development of materials and processes to be used to manufacture them.

The purpose of this study was to fabricate carbon nanotubes (CNT)-reinforced chromium oxide coatings and investigate mechanical and microstructural properties of these newly developed coatings on the boiler tube steel.

1 and 4 Wt.% CNT-reinforced Cr₂O₃ composite coatings were prepared and successfully deposited on ASTM-SA213-T22 (T22) boiler tube steel substrates using high-velocity oxy fuel (HVOF) thermal spraying method. Microhardness, porosity, metallography, X-ray diffraction (XRD), scanning electron microscopy (SEM)/energy-dispersive X-ray spectroscopy, cross-sectional elemental analysis and X-ray mapping analysis have been used to examine the coated specimens.

The porosity of the CNT-Cr₂O₃ composite coatings was found to be decreasing with the increases in CNT content, and hardness has been found to be increasing with increase in percentage of CNT in the composite coatings. The CNT were able to increase hardness by approximately 17 per cent. It was found that the CNT were uniformly distributed throughout Cr₂O₃ matrix. The CNT were found to be chemically inert during the spraying process.

It must be mentioned here that studies related to fabrication of HVOF sprayed CNT reinforced Cr₂O₃ composite coatings on T22 boiler tube steel are not available in the literature. Hence, present investigation can provide valuable information related to fabrication and properties of CNT reinforced coatings on boiler steel.

The purpose of this paper is to investigate the corrosion resistance of high velocity oxy-fuel (HVOF)-sprayed Diamalloy 2002 coating on carbon steel. The coating microstructure is examined in line with the corrosion resistance.

HVOF spraying of coating is achieved, and the coating response to electrolytic solution is measured experimentally in terms of corrosion resistance.

HVOF coating improves the corrosion resistance of the substrate such that the corrosion rate of the substrate is 7.1 mpy and the coating results in 4.5 mpy. However, presence of deep pit sites at the surface suggests the occurrence of preferential corrosion around the splat boundaries. In addition, closely spaced surface texture peaks act as crevice corrosion centers at the surface while initiating the formation of deep pit sites.

This study is limited by experimental investigations. In future, it may be extended to include model studies.

The findings of this study are very useful for those working in the coating industry. However, HVOF coating is limited to high temperature protection in harsh environments.

It is useful for the power industry, particularly for gas turbines.

It is an original work and describes the corrosion resistance of the coating surface. It is found that the coating improved the corrosion resistance of the steel surface.

This paper aims to use the high-velocity oxy fuel (HVOF) spraying process for depositing 93(WC–Cr₃C₂)–7Ni, 75Cr₃C₂–25NiCr, 83WC–17C_O and 86WC–10C_O–4Cr coatings on ASME SA213 T91 to study the corrosion resistance of these coatings in an actual boiler environment.

The HVOF spraying process was used for depositing 93(WC–Cr₃C₂)–7Ni, 75Cr₃C₂–25NiCr, 83WC–17C_O and 86WC–10C_O–4Cr coatings on ASME SA213 T91. All the coatings obtained are found to be uniform, dense and having thickness between 200 and 250 μm. All the coatings were exposed in an actual boiler environment at 900°C temperature for 10 cycles. Each cycle consisted of 100 h heating followed by 1 h cooling at ambient conditions. X-ray diffraction, scanning electron microscopy and energy-dispersive spectroscopy techniques were used to analyse corrosion products.

All the coated samples were found to be having higher corrosion resistance than the uncoated samples. Among coated specimens, 93(WC–Cr₃C₂)–7Ni coating has shown maximum and 75Cr₃C₂–25NiCr coating has shown minimum resistance to corrosion.

This paper is original research.

This paper seeks to examine the fatigue properties of HVOF sprayed Inconel‐625 coating of steel substrate before and after the aqueous corrosion.

Workpieces were cut from steel sheets. After chemical and ultrasonic cleaning, workpiece surfaces were sand‐blasted and HVOF sprayed Inconel‐625 coated. The coated and un‐coated surfaces were subjected to the aqueous corrosion tests for one and three weeks. After the completion of the corrosion tests, fatigue properties of the workpieces were examined.

Stainless steel coated workpieces demonstrated excellent fatigue life resistance versus coated carbon steel workpieces. Stainless steel workpieces apparently have a high‐cycle fatigue represented by in excess of 1.50 million cycles without cracking, thereby assuring a high‐fatigue life. The carbon steel specimens have low‐cycle fatigue and consequently a short fatigue life. In addition, high velocity impacting of splats on to the workpiece enhances the hardness of the surface. This, in turn, improves fatigue properties at the interface, particularly for stainless steel workpieces.

The tests can be extended to include the duplex treated workpieces such as the laser treatment of surface after HVOF sprayed coating. This enhances the bonding of the coating through thermal integration of the coating and the base substrate material.

The results can be used to assess the HVOF sprayed coatings.

This paper provides information on the fatigue behavior of HVOF sprayed coatings when subjected to the cyclic load and offers practical help for the researchers and scientists working in the coatings area.

Four thermal spray coatings were subjected to high temperature corrosive environments of oil‐fired boiler conditions to compare their corrosion protection under simulated conditions. The coatings included FeCrAl, Tafaloy 45CT, which were arc‐sprayed, 50Ni‐50Cr and Cr₃C₂‐NiCr, which were coated by high velocity oxy fuel spray (HVOF) method.

The coating substrates used were SA213TP 347H, SA213 T11 and SA213 T22 alloys that are widely used as boiler tube materials. Specimens were covered with a synthetic ash mixture of 70 per cent V₂O₅‐20 per cent Na₂SO₄‐10 per cent NaCl and exposed to 550°C and 650^oC°for 192 h (6 cycles). After high temperature corrosion tests, weight change curves were obtained; specimens were examined by metallographical techniques, scanning electron microscopy and EDX analyses.

Salt deposits attacked steels and coatings during the exposure. The corrosion rates were strongly affected by the composition of the scale formed adjacent to the steels and coatings surfaces. Austenitic steel was only bare material that experienced uniform corrosion in the tests. Ferritic steels were primarily attacked by grain boundary corrosion. Thermally sprayed coatings were mainly attached through oxides and voids at splat boundaries. FeCrAl and 50Ni‐50Cr were prone to spalling. Tafaloy 45CT is also a promising method for producing homogenous coatings. Cr₃C₂‐NiCr 80/20 coating remained mostly intact.

This paper provides useful information about corrosion behaviours of four coatings used for common boiler tubes. It shows with a practical explanation how the bare material and coatings react in corrosion simulated environments.

This paper presents the application of grey modeling for thermal spray processing parameter analysis in less data environment.

Based on processing knowledge, key processing parameters of thermal spray process are analyzed and preselected. Then, linear and non-linear grey modeling models are integrated to mine the relationships between different processing parameters.

Model A reveals the linear correlation between the HVOF process parameters and the characterization of particle in-flight with average relative errors of 9.230 percent and 5.483 percent for velocity and temperature.

The prediction accuracies of coatings properties vary, which means that there exists more complex non-linear relationship between the identified input parameters and coating results, or more unexpected factors (e.g. factors from material side) should be further investigated.

According to the modeling case in this paper, method has potential to deal with other diverse modeling problems in different industrial applications where challenge to collecting large quantity of data sets exists.

It is the first time to apply grey modeling for thermal spray processing where complicated relationships among processing parameters exist. The modeling results show reasonable results to experiment and existing processing knowledge.

This study investigated the corrosion stability of high velocity oxy‐fuel (HVOF) spray SUS316L coatings on aluminium substrate as lightweight bipolar plate materials for proton exchange membrane fuel cells (PEMFC). Contact resistance, microhardness and structure of the coatings were characterised using a four‐point probe, pneumatic microhardness, XRD and scanning electron microscope techniques. Preliminary electrochemical results indicate that the SUS316L coated plates significantly lowered the corrosion current of the aluminium substrate by more than one order of magnitude. Corrosion stability in relation to the coating thickness is discussed in terms of the structure composition and transpassivity of chromium.