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The purpose of this study is to evaluate the effectiveness of nanocontainer solutions in removing deteriorated and aged polymers commonly used in coating and consolidating archaeological glass.

This study focused on characterizing glass surfaces coated with two commonly used polymeric materials in archaeological glass preservation. Furthermore, the study evaluates the elimination of these coatings from the surfaces by using innovative aqueous systems composed of micellar solutions (MS) and oil-in-water (O/W) Texapon-P microemulsions (TEX). Glass samples coated with selected polymers were subjected to thermal and photochemical aging to simulate natural degradation conditions. This study aimed to evaluate the effectiveness of nanocontainer aqueous systems compared to acetone (Ac), a conventional solvent commonly used for removal procedures. The characterization procedures involved transmission electron microscopy, USB digital microscopy, scanning electron microscopy, color alteration and gravimetric measurement.

The findings indicate that the effectiveness of novel techniques using aqueous nanocontainer systems is quite promising when considering a “green approach” to preserving cultural heritage. Microscopic examination demonstrated the efficacy of MS in effectively removing acrylic and vinyl polymers from the glass surface. Furthermore, TEX proved effective in removing polyvinyl acetate (PVA) over Paraloid B72 (B-72). In addition, the measurement of color alteration values revealed a decrease after using MS compared to the standard sample before applying the polymers, with values of ΔE = 1.48 and 1.82 for B-72 polymer and PVA, respectively.

This research provides nanocontainer solutions for removing aged polymers from the glass surface. This makes the current study a promising step for treating archaeological glass.

The paper aims to design the optimum formulation of the nano-titanium dioxide (TiO2) hydrophilic coating system using the synthetic polypropylene glycol (PPG), which can create the reflection and absorption property.

TiO2 nanoparticles are used as fillers, and PPG has been blended at the proper ratio of 1PPG: 0.2TiO2. The prepared resin has been applied onto the glass substrate at different numbers of glass immersions during the dip-coating fabrication process. One-time glass immersion is labeled as T1 coating, two-time glass immersion is labeled as T2 coating and three-time glass immersion is labeled as T3 coating. All the prepared coating systems were left dry at ambient temperature.

T3 coating showed the lowest reading of WCA value at 40.50°, due to higher surface energy at 61.73 mN/m. The T3 coating also shows the greatest absorbance property among the prepared coating systems among the prepared coating. In terms of reflectance property, the T2 coating system has great reflectance in UV region and near-infrared region, which is 16.47% and 2.77 and 2.73%, respectively. The T2 coating also has great optical transmission about 75.00% at the visible region.

The development of thermal insulation coating by studying the relationship between convection heat and reflectance at different wavelengths of incident light.

The developed coating shows high potential for glass window application.

The application of the hydrophilic coating on light absorption, reflectance and transmission at different wavelengths.

This study aims to examine senior male employees’ perspectives on the glass ceiling in the Nigerian banking sector.

The data were collected qualitatively using interviews with 43 senior male employees in four Nigerian banks.

This study finds that senior male employees acknowledge the challenges their female counterparts face concerning promotion. Senior male employees’ views on the value of gender-diverse leadership underscore the illusion of a “level playing field” because of a gender-neutral performance policy and a family–friendly policy for women. Nonetheless, the study notes a divergence in senior male employees’ perspectives about the professional progression of female employees (based majorly on age and ethnicity). The study concludes that the organisational culture and leadership that underpin poor female career progression are embedded in and driven by the culture in the empirical context.

The examination of senior male employees’ perspectives on the glass ceiling in the Nigerian banking sector offers significant theoretical and practical contributions to the extant literature on gendered occupational segregation by providing unique insights into how patriarchal societal and occupational culture, as well as (limited) family–friendly policies for women, influence the configuration of men’s views of gendered occupational segregation in the Nigerian banking sector.

The main aim of the current study is to investigate the effect of Anti-Crack HP 67/36 glass fibre on the mechanical performance of mortars made of cement, with a focus on post-cracking evaluations using the digital image correlation (DIC) technique.

Experimental tests were carried out on 36-mm long fibres at 0.8% by volume and added to the normal strength (NSM), high strength (HSM) and high strength mortar with fly ash (HSMFA) mortars. CEM I 52.5 CP2 NF, CEM II/A-L 42.5 NF and CEM III/C 32.5 N-SR PM were used for each series of mortar to assess the performance of the glass fibres with the types of cement. F-class fly (FA) ash was used to reduce global CO₂ emissions.

The mortar’s strength decreased as the cement types changed from CEM I to CEM II and III. However, due to changes in the portlandite content of the cement, water porosity increased for both types of mortar, without and with fibre. It was also found that using glass fibre increased flexural strength more than compressive strength, regardless of the type of cement used. For all the strength classes, it was found that the mortar mixes with CEM I had the highest critical crack opening (w_c) and fracture energy (G_F), followed by CEM II and III. No significant effects were observed in the mortar’s property by replacing fly ash (12%).

Only mortars were formulated in this study, but the results must be verified at the concrete scale.

Validation of the DIC technique to characterize the post-cracking behaviour of cement-based material. Use of glass fibres to improve the material’s resistance to cracking.

Use of CEM II and CEM III cements with low CO₂ footprint instead of CEMI without altering the mechanical performance of the material.

The work is a further contribution to studying the cracking behaviour of several series of variable mortars depending on the resistance class and the type of cement used.

This study aims to assess the efficacy of nano-alumina (nano-Al₂O₃) in improving the performance of epoxy adhesives used to assemble archaeological glass. The conservators face a significant problem in assembling this type of artifact. Therefore, the assembling process is considered one of the important stages that must be taken care of to preserve these artifacts from damage and loss.

To evaluate the stability of adhesives, the samples were subjected to artificial aging under varying environmental conditions. Some investigative techniques and mechanical testing were used in this study to evaluate the selected materials. It includes a transmission electron microscope, X-ray diffraction, visual assessment, digital microscope, scanning electron microscopy (SEM), color change and tensile strength test.

The visual evaluation and the digital microscope results showed that the epoxy/nano-Al₂O₃ greatly resisted artificial aging. Although slight yellowing was present, it did not significantly affect the general appearance of the samples. On the other hand, the pure epoxy sample showed cracks of different sizes on its surface due to aging, as evidenced by SEM examination. Furthermore, epoxy/nano-Al₂O₃ has a better tensile strength (11.27 MPa) and slight color change (ΔE = 2.06).

The main objective of the experimental study was to identify appropriate adhesive materials that possess key properties such as non-yellowing and improved tensile strength by conducting various tests and evaluations. Ultimately, the goal was to identify materials that could serve as effective adhesives for assembling the archaeological glass.

The purpose of the study was to describe faculty women’s perspectives of the workplace environment in hospitality higher education.

Female faculty members in hospitality (n = ∼50) completed an online survey about their beliefs about women’s experiences, advancement characteristics the glass ceiling and gender equity.

Respondents concurred that being self-directed, assertive and a risk-taker were essential; leadership is the most important characteristic for advancement and the glass ceiling is prevalent and prominent. It may be assumed that the milieu of academia would be free or freer of the glass ceiling, but research, including this study, suggests otherwise. Glass ceilings persist even in organizations with explicit policies promoting equality in advancement. Research participants identified raising awareness about the glass ceiling and its presence within academic institutions as crucial. However, for initiatives to be effective, they must be supported authentically and unwaveringly by top administrators, including both male and female leaders.

The findings underscore both progress and persisting disparities, shedding light on the need for targeted efforts to improve inclusivity and gender equity within academia in hospitality management. These findings contribute to the ongoing discourse on fostering a more diverse and equitable landscape in higher education, particularly within the field of hospitality.

The purpose of this study to identify and optimize the machining of polyvinyl butyral (PVB) material for industrial uses. The research is based on input machining parameters of rotary ultrasonic machining for better understand the output response surface roughness (SR) property of polyvinyl butyral (PVB) by using the Taguchi approach. The grey relational grade analysis (GRG) is also implemented to resolve the complex interrelationship of SR data for optimization and predicting and validate the results.

In experimental work, the input parameters, namely, concentration, abrasives, power rate, grit size, tool material and hydrofluoric (HF) acid has been selected. The experiment’s design was created using MINITAB Software; the L27 orthogonal array was selected for the experimentation. SR was examined with the GRG technique for process optimization. On the other hand, for single parameter optimization analysis of variance (ANOVA) has been used.

ANOVA optimization technique gives the best result on concentration (40%) of abrasive (Al2O3+SiC+B4C), power rate (40%), grit size (600), HF acid (1.5%) and tool material (D2 alloy) are the optimal parameters to provide the slightest degree of SR. GRG optimization of multi-response parameter setting: 40% concentration, SiC+B4C mixed abrasive slurry, 40% of power rating, 280 grit size, 0.5% HF acid and high-speed tool steel tool material gives better results. The SR of PVB glass material improved by 20% after grey relational analysis.

There are several practical applications in a variety of material processing sectors, including metallurgy, machinery, electronics and transportation. These real-world applications have produced substantial and discernible economic benefits.

The analytical and optimization results will be used in the various material processing sectors, including metallurgy, machinery, electronics and transportation.

The ANOVA and grey theory approaches offer the reader a primary picture of the machining research and process parameter optimization. Combined abrasive slurry of Al₂O3+SiC+B₄C with a high power-rating exhibits lower SR. Similarly, grit size is vital; larger grits produce better SR. Ra – 0. 611 m is the lowest SR value at the hole found in trial 25 after the experimentation.

The manufacture of polymer composites with a lower environmental footprint requires incorporation of sustainably sourced components. In addition, the incorporation of novel components should not compromise the material properties. The purpose of this paper is to demonstrate the use of a synthetic amine functional toluidine acetaldehyde condensate (AFTAC) as a modifier for fiber-reinforced epoxy composites. One of the fiber components was sourced from agricultural byproducts, and glass fiber was used as the fiber component for comparison.

The AFTAC condensate was synthesized via an acid-catalyzed reaction between o-toluidine and acetaldehyde. To demonstrate its efficacy as a toughening agent for diglycidyl ether bisphenol A resin composites and for the comparison of reinforcing materials of interest, composites were fabricated using a natural fiber (mat stick) and a synthetic glass fiber as the reinforcing material. A matched metal die technique was used to fabricate the composites. Composites were prepared and their mechanical and thermal properties were evaluated.

The inclusion of AFTAC led to an improvement in the mechanical strengths of these composites without any significant deterioration of the thermal stability. It was also observed that the fracture strengths for mat stick fiber-reinforced composites were lower than that of glass fiber-reinforced composites.

To the best of the authors’ knowledge, the use of the AFTAC modifier as well as incorporation of mat stick fibers in epoxy composites has not been demonstrated previously.

Epoxy resins are widely used in a variety of engineering applications, including composite wind turbine blades used in the renewable energy industry, highly complex structural components for aircraft, paints, coatings, industrial tooling, biomedical systems, adhesives, electronics and automotive. Epoxies' low fracture toughness is one of the key obstacles preventing its adoption in a wider range of applications. To address epoxy's low fracture toughness, this paper aims to examine the roles of intra-ply hybridization and nano reinforcing.

This paper investigates the role of intra-ply hybridization of glass-carbon woven fibers and adding 0.8 wt.% of multiwall carbon nanotube (MWCNT) nano reinforcement to overcome the low fracture toughness of epoxy. A bending test is used to calculate the composites elastic parameters, and a notched sample three-point bending test is used to show crack behavior in addition to using materials characterization methods to reveal the effect of the MWCNT on structure, bonding, glass transition temperature (Tg) and dispersion of MWCNT in the matrix. Furthermore, this paper suggests using the finite element method to overcome the difficulty in calculating the crack extension.

Intra-ply hybridization and MWCNT reinforcement decrease the crack extension of epoxy with time. The inclusion of high-strength carbon fiber increased the fracture toughness of glass composite. Furthermore, the existence of MWCNT in the surrounding area of the notch in epoxy composites hinders crack propagation and provides stiffness at the interface by bridging the crack and eventually enhancing its fracture toughness.

Studying the role of intra-ply hybridization of glass-carbon woven fibers and adding 0.8 wt.% of MWCNT nano reinforcement to overcome the low fracture toughness of epoxy. Additionally, this research recommends using the finite element method to overcome the challenge of computing the crack extension.

The purpose of this study is to develop black pigmented ceramic stoneware bodies that integrate various aspects of material composition and color potential. Recent research has explored black pigmented calcium aluminosilicate glass (BPCG), a specialized material known for its unique properties, which holds promise for transforming the color capabilities of traditional ceramics.

In this investigation, initially composite ceramic sample (B-1) was prepared by milling process prior to sieve analysis to attain the particle size within 44 microns. Microanalysis and morphology and thermography were studied by energy-dispersive X-ray spectroscopy, scanning electron microscope and thermogravimetric analysis and found Sample-B-1 received attractive properties like firing shrinkage, porosity, bulk density and firing strength along with good pyro-plastic properties at various temperatures like 950°C, 1050°C, 1000°C and 1180°C. Furthermore, BPCG-assisted pigmented ceramic composites were synthesized with B-1 matrix. CIE lab investigation of the attributed composites (C-series) within selective soaking range of 5–20 min was performed, and the investigation found that prominent black hue appeared (L: 24.09, a*: −0.17, b*: −0.49) for C-10 containing appeared phases of Di-Co-Silicide (26%), Ni-Chromite, Stilpnomelane (rich in iron) as obtained by X-ray diffraction studies.

Ceramic material played a significant role in the realms of art and craft, as well as in technology. The artistic facet reveals concepts or ornamentation, while the craft echoes both traditional and functional appeal. Technology, on the other hand, involves the logical implementation behind the creation.

This C-10 Sample comprised the lower percentage of mullite which attributed that the BPCG homogeneously mixed in the matrix of base (B-1) and appeared as spinal staff. Therefore, BPCG was a potential candidate for ceramic metallization, and this traditional metallization processes often faced some challenges like uniformity and mixing in the ceramic composite domain practices. This study aimed to open up new avenues for artistic decoration and bridging the gap between traditional craftsmanship and modern technology. Furthermore, BPCG’s role in color assessment through shocking techniques added an exciting concept for the ceramic practitioners, designers or ceramic educators.