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The study aims to verify and establish the result of the most suitable optimization approach for higher performance and lower emission of a variable compression ratio (VCR) diesel engine. In this study, three types of test fuels are taken and tested in a variable compression ratio diesel engine (compression ignition). The fuels used are conventional diesel fuel, e-diesel (85% diesel-15% bioethanol) and nano-fuel (85% diesel-15% bioethanol-25 ppm Al₂O₃). The effect of bioethanol and nano-particles on performance, emission and cost-effectiveness is investigated at different load and compression ratios (CRs). The optimum performance and lower emission of the engine are evaluated and compared with other optimization methods.

The test engine is run by diesel, e-diesel (85% diesel-15% bioethanol) and nano-fuel (85% diesel-15% bioethanol-25 ppm Al₂O₃) in three different loadings (4 kg, 8 kg and 12 kg) and CR of 14, 16 and 18, respectively. The optimum value of energy efficiency, exergy efficiency, NO_X emission and relative cost variation are determined against the input parameters using Taguchi-Grey method and confirmed by response surface methodology (RSM) technique.

Using Taguchi-Grey method, the maximum energy and exergy efficiency, minimum % relative cost variation and NO_X emission are 24.64%, 59.52%, 0 and 184 ppm, respectively, at 4 kg load, 18 CR and fuel type of nano-fuel. Using RSM technique, maximum energy and exergy efficiency are 24.8% and 62.9%, and minimum NO_X emission and % cost variation are 208.4 ppm and –6.5, respectively, at 5.2 kg load, 18 CR and nano-fuel. The RSM is suggested as the most appropriate technique for obtaining maximum energy and exergy efficiency, and minimum % relative cost; however, for lowest possible NO_X emission, the Taguchi-Grey method is the most appropriate.

Waste rice straw is used to produce bioethanol. 4-E analysis, i.e. energy, exergy, emission and economic analysis, has been carried out, optimized and compared.

The aim of this study was to determine if there are asymmetries in the pass-through of West Texas Intermediate (WTI) crude oil prices to its derivatives (diesel and gasoline) in the Brazilian market.

Initially, the future WTI oil price series was analyzed using the self-exciting threshold autoregressive (SETAR) and logistic smooth transition autoregressive (LSTAR) non-linear models. Subsequently, the threshold autoregressive error-correction model (TAR-ECM) and Markov-switching model were used.

The findings indicated high prices throughout 2008 due to the subprime crisis. The findings indicated high prices throughout 2008 due to the subprime crisis. The results indicated that there is long-term pass-through of oil prices in both methods, suggesting an equilibrium adjustment in the prices of diesel and gasoline in the analyzed period. Regarding the short term, the variations in contemporary crude oil prices have positive effects on the variations in fuel prices. Lastly, this behavior can partly be explained by the internal price management structure adopted during almost all of the analyzed period.

This paper contributes to the literature at some points. The first contribution is the modeling of the oil price series through non-linear models, further enriching the literature on the recent behavior of this time series. The second is the simultaneous use of the TAR-ECM and Markov-switching model to capture possible short- and long-term asymmetries in the pass-through of prices, as few studies have applied these methods to the future price of oil. The third and main contribution is the investigation of whether there are asymmetries in the transfer of oil prices to the price of derivatives in Brazil. So far, no work has investigated this issue, which is very relevant to the country.

The study aims to determine the the optimal value of output parameters of a variable compression ratio (CR) diesel engine are investigated at different loads, CR and fuel modes of operation experimentally. The output parameters of a variable compression ratio (CR) diesel engine are investigated at different loads, CR and fuel modes of operation experimentally. The performance parameters like brake thermal efficiency (BTE) and brake specific energy consumption (BSEC), whereas CO emission, HC emission, CO₂ emission, NO_x emission, exhaust gas temperature (EGT) and opacity are the emission parameters measured during the test. Tests are conducted for 2, 6 and 10 kg of load, 16.5 and 17.5 of CR.

In this investigation, the first engine was fueled with 100% diesel and 100% Calophyllum inophyllum oil in single-fuel mode. Then Calophyllum inophyllum oil with producer gas was fed to the engine. Calophyllum inophyllum oil offers lower BTE, CO and HC emissions, opacity and higher EGT, BSEC, CO₂ emission and NO_x emissions compared to diesel fuel in both fuel modes of operation observed. The performance optimization using the Taguchi approach is carried out to determine the optimal input parameters for maximum performance and minimum emissions for the test engine. The optimized value of the input parameters is then fed into the prediction techniques, such as the artificial neural network (ANN).

From multiple response optimization, the minimum emissions of 0.58% of CO, 42% of HC, 191 ppm NO_x and maximum BTE of 21.56% for 16.5 CR, 10 kg load and dual fuel mode of operation are determined. Based on generated errors, the ANN is also ranked for precision. The proposed ANN model provides better prediction with minimum experimental data sets. The values of the R² correlation coefficient are 1, 0.95552, 0.94367 and 0.97789 for training, validation, testing and all, respectively. The said biodiesel may be used as a substitute for conventional diesel fuel.

The blend of Calophyllum inophyllum oil-producer gas is used to run the diesel engine. Performance and emission analysis has been carried out, compared, optimized and validated.

Combustion of fuel with oxidizer inside a combustion chamber of an internal combustion engine forms inevitable oxides of nitrogen (NOx) due to high temperature at different locations of the combustion chamber. This study aims to quantify NOx formed inside the combustion chamber using two fuels, a conventional diesel (n-heptane) and a biodiesel (methyl oleate).

This research uses a computational fluid dynamics simulation of chemically reacting fluid flow to quantify and compare oxides of nitrogen (NOx) in a compression ignition (CI) engine. The study expends species transport model of ANSYS FLUENT. The simulation model has provided the temperature profile inside the combustion chamber, which is subsequently used to calculate NOx using the NOx model. The simulation uses a single component hydrocarbon and oxygenated hydrocarbon to represent fuels; for instance, it uses n-heptane (C₇H₁₆) for diesel and methyl-oleate (C₁₉H₃₆O₂) for biodiesel. A stoichiometric air–fuel mixture is used for both fuels. The simulation runs a single cylinder CI engine of 650 cm³ swept volume with inlet and exhaust valves closed.

The pattern for variation of velocity, an important flow parameter, which affects combustion and subsequently oxides of nitrogen (NOx) formation at different piston locations, is similar for the two fuels. The variations of in-cylinder temperature and NOx formation with crank angles have similar patterns for the fuels, diesel and biodiesel. However, the numerical values of in-cylinder temperature and mass fraction of NOx are different. The volume averaged static peak temperatures are 1,013 K in case of diesel and 1,121 K in case of biodiesel, while the mass averaged mass fractions of NOx are 15 ppm for diesel and 141 ppm for biodiesel. The temperature rise after combustion is more in case of biodiesel, which augments the oxides of nitrogen formation. A new parameter, relative mass fraction of NOx, yields 28% lower value for biodiesel than for diesel.

This work uses a new concept of simulating simple chemical reacting system model to quantify oxides of NOx using single component fuels. Simplification has captured required fluid flow data to analyse NOx emission from CI engine while reducing computational time and expensive experimental tests.

This study aims to provide a new method for precisely sizing photovoltaic (PV) arrays for standalone, direct pumping PV Water Pumping (PVWP) systems for irrigation purposes.

The method uses historical weather data and considers daily variability in regional temperatures and rainfall, crop evapotranspiration rates and seasonality effects, all within a nonparametric bootstrapping approach to synthetically generate daily rainfall and crop irrigation needs. These needs define the required daily supply of pumped water to achieve a user-specified level of reliability, which provides the input to an intuitive approach for PV array sizing. An economic comparison of the costs for the PVWP versus a comparably powered diesel generator system is provided.

Pumping 22.8646 m³/day of water would meet the pasture crop irrigation needs on a one-acre (4046.78 m²) tract of land in South Florida, with 99.9% reliability. Given the specified assumptions, an 8.4834 m² PV array, having a peak power of 1.1877 (kW), could provide the 1.2347 (kWh/day) of hydraulic energy needed to supply this volume over a total head of 20 meters. The PVWP system is the low-cost option when diesel prices are above $0.90/liter and total installed PV array costs are fixed at $2.00/Watt peak power or total installed PV array costs are below $1.50/Watt peak power and diesel prices are fixed at $0.65/liter.

Because the approach is not dependent on the shapes of the sampling distributions for regional climate factors and can be adapted to consider different types of crops, it is highly portable and applicable for precisely determining array sizes for standalone, direct pumping PVWP systems for irrigating diverse crop types in diverse regions.

Diesel has traditionally been considered the best-suited and most widely used fuel in various sectors, including manufacturing industries, power production, automobiles and transportation. However, with the ongoing crisis of fossil fuel inadequacy, the search for alternative fuels and their application in these sectors has become increasingly important. One particularly interesting and beneficial alternative fuel is biodiesel derived from bio sources.

In this research, an attempt was made to use biodiesel in an unconventional micro gas turbine engine. It will remove the concentric use of diesel engines for power production by improving fuel efficiency as well as increasing the power production rate. Before the fuel is used enormously, it has to be checked in many ways such as performance, emission and combustion analysis experimentally.

In this paper, a detailed experimental study was made for the use of Spirulina microalgae biodiesel in a micro gas turbine. A small-scale setup with the primary micro gas turbine and secondary instruments such as a data acquisition system and AVL gas analyser. The reason for selecting the third-generation microalgae is due to its high lipid and biodiesel production rate. For the conduction of experimental tests, certain conditions were followed in addition that the engine rotating rpm was varied from 4,000, 5,000 and 6,000 rpm. The favourable and predicted results were obtained with the use of microalgae biodiesel.

The performance and combustion results were not exactly equal or greater for biodiesel blends but close to the values of pure diesel; however, the reduction in the emission of CO was at the appreciable level for the used spirulina microalgae biodiesel. The emission of nitrogen oxides and carbon dioxide was a little higher than the use of pure diesel. This experimental analysis results proved that the use of spirulina microalgae biodiesel is both economical and effective replacement for fossil fuel.

This paper aims to examine the cross-quantile correlation and causality-in-quantiles between green investments and energy commodities during the outbreak of COVID-19. To be specific, the authors aim to address the following questions: Is there any distributional predictability among green bonds and energy commodities during COVID-19? Is there exist any directional predictability between green investments and energy commodities during the global pandemic? Can green bonds hedge the risk of energy commodities during a period of the financial crisis.

The authors use the nonparametric causality in quantile and cross-quantilogram (CQ) correlation approaches as the estimation techniques to investigate the distributional and directional predictability between green investments and energy commodities respectively using daily spot prices from January 1, 2020, to March 26, 2021. The study uses daily closing price indices S&P Green Bond Index as a representative of the green bond market. In the case of energy commodities, the authors use S&P GSCI Natural Gas Spot, S&P GSCI Biofuel Spot, S&P GSCI Unleaded Gasoline Spot, S&P GSCI Gas Oil Spot, S&P GSCI Brent Crude Spot, S&P GSCI WTI, OPEC Oil Basket Price, Crude Oil Oman, Crude Oil Dubai Cash, S&P GSCI Heating Oil Spot, S&P Global Clean Energy, US Gulf Coast Kerosene and Los Angeles Low Sulfur CARB Diesel Spot.

From the CQ correlation results, there exists an overall negative directional predictability between green bonds and natural gas. The authors find that the directional predictability between green bonds and S&P GSCI Biofuel Spot, S&P GSCI Gas Oil Spot, S&P GSCI Brent Crude Spot, S&P GSCI WTI Spot, OPEC Oil Basket Spot, Crude Oil Oman Spot, Crude Oil Dubai Cash Spot, S&P GSCI Heating Oil Spot, US Gulf Coast Kerosene-Type Jet Fuel Spot Price and Los Angeles Low Sulfur CARB Diesel Spot Price is negative during normal market conditions and positive during extreme market conditions. Results from the non-parametric causality in the quantile approach show strong evidence of asymmetry in causality across quantiles and strong variations across markets.

The quantile time-varying dependence and predictability results documented in this paper can help market participants with different investment targets and horizons adopt better hedging strategies and portfolio diversification to aid optimal policy measures during volatile market conditions.

The outcome of this study will promote awareness regarding the environment and also increase investor’s participation in the green bond market. Further, it allows corporate institutions to fulfill their social commitment through the issuance of green bonds.

This paper differs from these previous studies in several aspects. First, the authors have included a wide range of energy commodities, comprising three green bond indices and 14 energy commodity indices. Second, the authors have explored the dependency between the two markets, particularly during COVID-19 pandemic. Third, the authors have applied CQ and causality-in-quantile methods on the given data set. Since the market of green and sustainable finance is growing drastically and the world is transmitting toward environment-friendly practices, it is essential and vital to understand the impact of green bonds on other financial markets. In this regard, the study contributes to the literature by documenting an in-depth connectedness between green bonds and crude oil, natural gas, petrol, kerosene, diesel, crude, heating oil, biofuels and other energy commodities.

This study aims to explore the possibility of using magnetic biochar composite (MBCC) derived from Heglig tree bark (HTB) powder (agricultural solid waste) and cobalt ferrite (CoFe₂O₄, CFO) for oil spill removal from seawater surface.

One-pot co-precipitation route was used to synthesize MBCC. The prepared materials were characterized by X-ray diffraction, scanning electron microscopy-energy dispersive X-ray spectroscopy, Fourier transform infrared spectroscopy. The densities of the prepared materials were also estimated. Crude, diesel engine and gasoline engine oils were used as seawater pollutant models. The gravimetric oil removal (GOR) method was used for removing oil spills from seawater using MBCC as a sorbent material.

The obtained results revealed that the prepared materials (CFO and MBCC) were able to remove the crude oil and its derivatives from the seawater surface. Besides, when the absorbent amount was 0.01 g, the highest GOR values for crude oil (31.96 ± 1.02 g/g) and diesel engine oil (14.83 ± 0.83 g/g) were obtained using MBCC as an absorbent. For gasoline engine oil, the highest GOR (27.84 ± 0.46 g/g) was attained when CFO was used as an absorbent.

Oil spill removal using MBCC derived from cobalt ferrite and HTB. Using tree bark as biomass (eco-friendly, readily available and low-cost) for magnetic biochar preparation also is a promising method for minimizing agricultural solid wastes (e.g. HTB) and obtaining value-added-products.

Kapok was well-known for its oleophilic properties, but its mechanical properties and morphology impeded it from forming suitable absorbent materials. This study aims to demonstrate the process of creating an oil-absorbent web from a blend of treated kapok and polypropylene fibers.

Kapok fibers were separated from dried fruits, then the wax was removed with an HCl solution at different concentrations. The morphological and structural changes of these fibers were investigated using scanning electron microscopy images. The blending ratios of kapok and polypropylene fibers were 60/40, 70/30 and 80/20, respectively. The fiber blends were fed to a laboratory carding machine to form a web and then consolidated using the heat press technique. The absorption behavior of the formed web was evaluated regarding oil absorption capacity and oil retention capacity according to ASTM 726.

The results showed that the HCl concentration of 1.0% (wt%) gave the highest wax removal efficiency without damaging the kapok fibers. This study found that oil absorbency is influenced by the fiber blending ratio, web tensile strength and elongation, porosity, oil type and environmental conditions. The oil-absorbency of the web can be re-used for at least 20 cycles.

This study only looked at three types of oils: diesel, kerosene and vegetable oils.

When the problem of oil spills in rivers and seas is growing and causing serious environmental and economic consequences, using physical methods to recover oil spills is the most effective solution.

This research adds to the possibility of using kapok fiber in the form of a web of non-woven fabric for practical purposes.

Studies on this topic have shown the remarkable lubricating properties, viz. friction-reducing and anti-wear, of certain nanoparticles. This makes them potential candidates for replacing the lubrication additives currently used in automobile lubricants, especially because the latter is known to be pollutants and less efficient in some specific conditions. This has not gone unnoticed to professionals in the sector, including those commercializing these additives, the oil companies and the car industry, all of whom are following this burgeoning research area with keen interest. All of them are faced with the problem of providing lubricants that meet the needs of the technological evolution of engines while respecting ever-stricter environmental norms.

The impact of copper oxide (CuO) and zinc oxide (ZnO) nanoparticles on the tribological properties of the SAE-40 pure diesel oil is studied in this paper. The two nanoparticles are not oxide or deteriorate with the base oil. The average size of CuO and ZnO nanoparticles is 40 and 20 nm, respectively. Nanoparticle concentrations of 0.1 Wt.%, 0.2 Wt.%, 0.3 Wt.%, 0.4 Wt.% and 0.5 Wt.% are tested using a pin-on-disk tribometer to evaluate their impact on friction and wear. The test is carried out at different loads and rotating speeds of 58.86 N and 300 rpm, 39.24 N and 500 rpm and 78.48 N and 900 rpm at room temperature, respectively.

The obtained results of the nanolubricants are compared with those of pure diesel oil in terms of % improvement in tribological properties. However, it is observed that an increase in the nanoparticle concentrations does not guarantee to enhance the tribological properties. Similarly, increasing the applied load and the rotating speed does not lead to improving the anti-friction and anti-wear properties. The results obtained revealed that the optimal improvements in the anti-friction and anti-wear properties of the pure oil are 69% and 77% when CuO nanoparticle concentrations of 0.3 Wt.% and the ZnO nanoparticle concentrations of 0.1 Wt.% are used, where the applied load and rotating speed are 39.24 N and 500 rpm, respectively. It has also been noticed that the CuO nanolubricants have a significant impact on the anti-friction property compared with ZnO nanolubricants.

All these nanoparticles have been the subject of detailed investigation in this research and many key issues have been tackled, such as the conditions leading to these properties, the lubrication mechanisms coming into play, the influence of parameters such as size, structure and morphology of the nanoparticles on their tribological properties/lubrication mechanisms and the interactions between the particles and the lubricant co-additives. To answer such questions, state-of-the-art characterization techniques are required, often in situ, and sometimes an extremely complex set up. Some of these can even visualize the behavior of a nanoparticle in real time during a tribological test. The research on this topic has given a good understanding of the way these nanoparticles behave, and we can now identify the key parameters to be adjusted when optimizing their lubrication properties.

The peer review history for this article is available at: https://publons.com/publon/10.1108/ILT-08-2022-0234/