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1 – 10 of 168Hong-Feng Li, Jun Sun, Xiao-Yong Wang, Lei-Lei Xing and Guang-Zhu Zhang
The purpose of this paper is to add expanded perlite (EP) immobilized microorganisms that replace part of the standard sand in mortar to improve the self-healing ability of mortar…
Abstract
Purpose
The purpose of this paper is to add expanded perlite (EP) immobilized microorganisms that replace part of the standard sand in mortar to improve the self-healing ability of mortar cracks and reduce the water absorption of mortar after healing.
Design/methodology/approach
Bacillus pseudofirmus spores were immobilized with EP particles as self-healing agents. The effects of adding self-healing agents on the compressive strength of mortar specimens were observed. The ability of mortar specimens to heal cracks was evaluated using crack microscopic observation and water absorption experiments. The filler at the cracks was microscopically analyzed by scanning electron microscope and X-ray diffraction experiments.
Findings
First, the internal curing effect of EP promotes the hydration of cement in mortar, which generates more amount and denser crystal structure of Ca(OH)2 at mortar cracks and improves the self-healing ability of mortar. Second, the self-healing ability of mortar improves with the increase of self-healing agent admixture. Adding a self-healing agent of high admixture makes the planar undulation of calcite crystal accumulation at mortar cracks more significant. Finally, the initial crack widths that can be completely healed by adding EP and self-healing agents to the mortar are 200 µm and 600 µm, respectively.
Originality/value
The innovation points of this study are as follows. (1) The mechanism of the internal curing effect of EP particles on the self-healing ability of mortar cracks was revealed by crack microscopic observation tests and microscopic experiments. (2) The effect of different self-healing agent amounts on the self-healing ability of mortar cracks has been studied. (3) The effects of EP particles and self-healing agents on healing different initial widths were elucidated by crack microscopic observation tests.
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Saeed Bastani, Mojtaba Jalili, Mehdi Ghahari and Parand Banihashem
This study aims to investigate the effect of trisodium nitrilotriacetic acid (NTA) on the physical and luminescence emission properties of NaLuF4:Yb, Tm Upconversion (UC…
Abstract
Purpose
This study aims to investigate the effect of trisodium nitrilotriacetic acid (NTA) on the physical and luminescence emission properties of NaLuF4:Yb, Tm Upconversion (UC) particles and compared with trisodium citrate (CA). Upconversion materials have been remarkably considered in many applications in the past decades. However, the morphology of the UC particles affects their emission properties, depending on the synthesis situation.
Design/methodology/approach
The UC particles were synthesized by the hydrothermal method. Properties such as crystal phase, particle morphology, particle size, smoothness and uniformity of particle surface and their emission intensity in the UV–Vis region were studied.
Findings
Observations showed that pH is an essential factor in determining the crystalline phase. In addition, quality factors affect the morphology, particle size and surface smoothness of crystalline facets. It was also found that the UC particles synthesized in the presence of trisodium NTA have a much higher emission intensity than those synthesized in the presence of CA. The use of UC particles in security inks to maintain the brand was also investigated.
Originality/value
To the best of the authors’ knowledge, for the first time, the effect of trisodium NTA as a chelating agent was investigated on morphology and UC intensity of NaLuF4:Yb,Tm phosphor.
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He Lu, Yuhou Wu, Zijin Liu, He Wang, Guangyu Yan, Xu Bai, Jiancheng Guo and Tongxiang Zheng
Preparing CrAlN coatings on the surface of silicon nitride bearings can improve their service life in oil-free lubrication. This paper aims to match the optimal process parameters…
Abstract
Purpose
Preparing CrAlN coatings on the surface of silicon nitride bearings can improve their service life in oil-free lubrication. This paper aims to match the optimal process parameters for preparing CrAlN coatings on silicon nitride surfaces, and reveal the microscopic mechanism of process parameter influence on coating wear resistance.
Design/methodology/approach
This study used molecular dynamics to analyze how process parameters affected the nucleation density, micromorphology, densification and internal stress of CrAlN coatings. An orthogonal test method was used to examine how deposition time, substrate temperature, nitrogen-argon flow rate and sputtering power impacted the wear resistance of CrAlN coatings under dry friction conditions.
Findings
Nucleation density, micromorphology, densification and internal stress have a significant influence on the surface morphology and wear resistance of CrAlN coatings. The process parameters for better wear resistance of the CrAlN coatings were at a deposition time of 120 min, a substrate temperature of 573 K, a nitrogen-argon flow rate of 1:1 and a sputtering power of 160 W.
Originality/value
Simulation analysis and experimental results of this paper can provide data to assist in setting process parameters for applying CrAlN coatings to silicon nitride bearings.
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Khishn Kumar Kandiah, Vengadaesvaran Balakrishnan, Amirul Syafiq, Nasrudin Abd Rahim, Adarsh Kumar Pandey, Yee Seng Tan, Sanjay J Dhoble, Ramesh Kasi and Ramesh Subramaniam
There is a strong inducement to develop new inorganic materials to substitute the current industrial pigments, which are known for their poor ultraviolet absorbent and low…
Abstract
Purpose
There is a strong inducement to develop new inorganic materials to substitute the current industrial pigments, which are known for their poor ultraviolet absorbent and low photoluminescence (PL) properties. The purpose of this paper is to invent a better rare-earth-based pigment material as a spectral modifier with good luminescence properties to enhance the spectral response for photovoltaic panel application.
Design/methodology/approach
Different phosphor samples made of nano-calcium carbonate (CaCO3) with varied wt.% of the dopant Dysprosium doped calcium borophosphate (CBP/Dy) as (W0 – 0%, W1 – 3,85%, W2 – 7.41%, W3 –10.71% and W4 –13.79%) were prepared via the solid-state diffusion method at 600 °C for 6 h using a muffle furnace. The structural, morphological and luminescence properties of the CaCO3:CBP/Dy powder samples were examined using scanning electron microscopy (SEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) and PL test.
Findings
The XRD, SEM and FTIR results verified the crystalline formation, morphological behaviour and vibration bonds of synthesized CBP/Dy-doped CaCO3 powder samples. XRD pattern revealed that the synthesized powder samples exhibit crystalline structured materials, and SEM results showed irregular shape and porous-like structured morphologies. FTIR spectrum shows prominent bands at 712, 874 and 1,404 cm−1, corresponding to asymmetric stretching vibrations of CO32− groups and out-of-plane bending. PL characterization of CBP/Dy-doped CaCO3 (sample W) shows emission at 427 nm (λmax) under the excitation of 358 nm. The intensity of PL emission spectra drops due to the concentration quenching effect, while the maximum PL intensity is observed in the W3 phosphor powder system.
Research limitations/implications
This phosphor powder is expected to find out the potential application such as a spectral modifier which is applied to match the energy of photons with solar cell bandgap to improve spectral absorption and lead to better efficiency.
Originality/value
The introduction of a nano-CaCO3:CBP/Dy hybrid powder system with good luminescence properties to be used as spectral modifiers for solar cell application has been synthesized in the lab, which is a novel attempt.
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Junyu Shi, Shengli Ling, Yinjie Kuang, Yonggang Tong, Yongle Hu and Dunying Deng
The purpose of this paper is to reveal the effect of microstructure on the corrosion behavior of CoCrNi alloy in 3.5 Wt.% NaCl solution.
Abstract
Purpose
The purpose of this paper is to reveal the effect of microstructure on the corrosion behavior of CoCrNi alloy in 3.5 Wt.% NaCl solution.
Design/methodology/approach
The as-cast CoCrNi alloy was prepared by arc melting, and the cold-rolled and annealed alloys were prepared by processing the as-cast alloy.
Findings
The experimental results showed that a protective passivation film was formed on the surfaces of these CoCrNi MEA, and the stability and compactness of alloys increased in the sequence of cold-rolled, as-cast and annealed CoCrNi alloys. The annealed CoCrNi alloys had the best pitting resistance.
Originality/value
This study proposes the effect of the microstructure of CoCrNi alloy on corrosion resistance.
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Jianqing Hu, Hongjun He, Feiliang Dai, Xingyu Gong and Haowei Huang
The purpose of this paper is to develop the efficiency of styrene-acrylate (SA) emulsions for polymer cement waterproof coatings with improved bacteria resistance and mechanical…
Abstract
Purpose
The purpose of this paper is to develop the efficiency of styrene-acrylate (SA) emulsions for polymer cement waterproof coatings with improved bacteria resistance and mechanical properties.
Design/methodology/approach
For effective bacteria resistance and excellent mechanical properties, various concentrations of methacryloxyethylhexadecyl dimethylammonium bromide (MHDB) were synthesised and incorporated into SA emulsions. The properties of SA emulsions modified with MHDB were characterised and compared with those of unmodified ones according to the formulations of polymer cement waterproof coatings.
Findings
The SA emulsions modified with MHDB exhibited significant enhancement of bacteria resistance and mechanical properties over the unmodified ones. The positive quaternary nitrogen and long-chain alkyl groups of MHDB in SA emulsions could attract phospholipid head groups of bacterial and insert them into the cell wall, which results in biomass leak and bactericidal effect. Moreover, MHDB as a softened monomer was beneficial to the synthesis of SA copolymer with low glass-transition temperature (Tg), then the copolymer and cement would form a more compact film which was the main reason for the enhancement of mechanical properties.
Research limitations/implications
The modifier MHDB was synthesised from diethylaminoethyl methacrylate (DEAM) and 1-bromohexadecane. Besides, the congeners of MHDB could be synthesised from DEAM and 1-bromododecane, 1-tetradecyl dromide, 1-octadecyl bromide, etc. In addition, the efficiency of other modifications into SA emulsions for antibacterial polymer cement waterproof coatings could be studied as well.
Practical implications
The method provided a practical solution for the improvement of water-based antibacterial acrylate polymer cement waterproof coatings.
Originality/value
The method for enhancing bacteria resistance and mechanical properties of the waterproof coating was novel and valuable.
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Mu’taz AlTarawneh and Salloom AlJuboori
Studies on this topic have shown the remarkable lubricating properties, viz. friction-reducing and anti-wear, of certain nanoparticles. This makes them potential candidates for…
Abstract
Purpose
Studies on this topic have shown the remarkable lubricating properties, viz. friction-reducing and anti-wear, of certain nanoparticles. This makes them potential candidates for replacing the lubrication additives currently used in automobile lubricants, especially because the latter is known to be pollutants and less efficient in some specific conditions. This has not gone unnoticed to professionals in the sector, including those commercializing these additives, the oil companies and the car industry, all of whom are following this burgeoning research area with keen interest. All of them are faced with the problem of providing lubricants that meet the needs of the technological evolution of engines while respecting ever-stricter environmental norms.
Design/methodology/approach
The impact of copper oxide (CuO) and zinc oxide (ZnO) nanoparticles on the tribological properties of the SAE-40 pure diesel oil is studied in this paper. The two nanoparticles are not oxide or deteriorate with the base oil. The average size of CuO and ZnO nanoparticles is 40 and 20 nm, respectively. Nanoparticle concentrations of 0.1 Wt.%, 0.2 Wt.%, 0.3 Wt.%, 0.4 Wt.% and 0.5 Wt.% are tested using a pin-on-disk tribometer to evaluate their impact on friction and wear. The test is carried out at different loads and rotating speeds of 58.86 N and 300 rpm, 39.24 N and 500 rpm and 78.48 N and 900 rpm at room temperature, respectively.
Findings
The obtained results of the nanolubricants are compared with those of pure diesel oil in terms of % improvement in tribological properties. However, it is observed that an increase in the nanoparticle concentrations does not guarantee to enhance the tribological properties. Similarly, increasing the applied load and the rotating speed does not lead to improving the anti-friction and anti-wear properties. The results obtained revealed that the optimal improvements in the anti-friction and anti-wear properties of the pure oil are 69% and 77% when CuO nanoparticle concentrations of 0.3 Wt.% and the ZnO nanoparticle concentrations of 0.1 Wt.% are used, where the applied load and rotating speed are 39.24 N and 500 rpm, respectively. It has also been noticed that the CuO nanolubricants have a significant impact on the anti-friction property compared with ZnO nanolubricants.
Originality/value
All these nanoparticles have been the subject of detailed investigation in this research and many key issues have been tackled, such as the conditions leading to these properties, the lubrication mechanisms coming into play, the influence of parameters such as size, structure and morphology of the nanoparticles on their tribological properties/lubrication mechanisms and the interactions between the particles and the lubricant co-additives. To answer such questions, state-of-the-art characterization techniques are required, often in situ, and sometimes an extremely complex set up. Some of these can even visualize the behavior of a nanoparticle in real time during a tribological test. The research on this topic has given a good understanding of the way these nanoparticles behave, and we can now identify the key parameters to be adjusted when optimizing their lubrication properties.
Peer review
The peer review history for this article is available at: https://publons.com/publon/10.1108/ILT-08-2022-0234/
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Ahmed Jan, Muhammad F. Afzaal, Muhammad Mushtaq, Umer Farooq and Muzammil Hussain
This study investigates the flow and heat transfer in a magnetohydrodynamic (MHD) ternary hybrid nanofluid (HNF), considering the effects of viscous dissipation and radiation.
Abstract
Purpose
This study investigates the flow and heat transfer in a magnetohydrodynamic (MHD) ternary hybrid nanofluid (HNF), considering the effects of viscous dissipation and radiation.
Design/methodology/approach
The transport equations are transformed into nondimensional partial differential equations. The local nonsimilarity (LNS) technique is implemented to truncate nonsimilar dimensionless system. The LNS truncated equation can be treated as ordinary differential equations. The numerical results of the equation are accomplished through the implementation of the bvp4c solver, which leverages the fourth-order three-stage Lobatto IIIa formula as a finite difference scheme.
Findings
The findings of a comparative investigation carried out under diverse physical limitations demonstrate that ternary HNFs exhibit remarkably elevated thermal efficiency in contrast to conventional nanofluids.
Originality/value
The LNS approach (Mahesh et al., 2023; Khan et al., 20223; Farooq et al., 2023) that we have proposed is not currently being used to clarify the dynamical issue of HNF via porous media. The LNS method, in conjunction with the bvp4c up to its second truncation level, yields numerical solutions to nonlinear-coupled PDEs. Relevant results of the topic at hand, obtained by adjusting the appropriate parameters, are explained and shown visually via tables and diagrams.
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Xing Ai, Shuaishuai Wang, Fenghua Luo, Haiqing Pei and Zhenwei Li
The purpose of this study is to describe the mechanism of single-crystal high-temperature creep deformation, predict the creep life more accurately and study the creep…
Abstract
Purpose
The purpose of this study is to describe the mechanism of single-crystal high-temperature creep deformation, predict the creep life more accurately and study the creep constitutive and lifetime models with microstructure evolution.
Design/methodology/approach
The mechanical properties of nickel-based single-crystal superalloy are closely related to the γ' phase. Creep tests under four different temperature and stress conditions were carried out. The relationship between creep temperature, stress and life is fitted by numerical method, and the creep activation energy is obtained. The creep fracture surface, morphology and evolution of strengthening phase (γ') and matrix phase (γ) during different creep periods were observed by scanning electron microscope. With the increase of creep temperature, the rafting time is advanced. The detailed morphology and evolution of dislocations were observed by transmission electron microscope (TEM).
Findings
With the increase of creep temperature, the rafting time is advanced. The detailed morphology and evolution of dislocations were observed by TEM. Dislocations are mainly concentrated in the γ channel phase, especially at high temperature and low stress.
Originality/value
A creep constitutive model based on the evolution of γ' phase size and γ channel width was proposed. Compared with the experimental results, the predicted creep life is within 1.4 times error dispersion band.
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Mudasir Peerzada, Khan Adnan, Basrah Bilal, Riyaz Janees, Bazila Qazi and Naqash Ahmed Javed
The purpose of this paper is to study the effect of nano alumina (Al2O3) on the properties of fresh concrete, hardened concrete and microstructure of concrete incorporated with…
Abstract
Purpose
The purpose of this paper is to study the effect of nano alumina (Al2O3) on the properties of fresh concrete, hardened concrete and microstructure of concrete incorporated with high range water reducer (HRWR). This initiative was taken to improve characteristic properties of concrete using nano alumina because nano alumina can be easily be manufactured from a scrap of industrial aluminum products, so its incorporation in concrete will not only reduce industrial aluminum waste but will also change the morphology of concrete at the microstructural level.
Design/methodology/approach
To accomplish the objectives of the research, four different concrete mixes with the constant water–cement ratio (W/C) and superplasticizer (SP) content 0.4 and 0.6% by weight of cement, respectively, were prepared, whereas nano alumina content was altered by 0.3% and 0.4% by weight of cement. Fresh property of concrete was analyzed by using slump cone test, whereas hardened properties of concrete were analyzed through compression test and flexural strength test. The interaction of nano alumina with concrete composite was evaluated using an X-ray diffraction test.
Findings
It was observed that 0.6% superplasticizer by weight of cement increased workability by 22% but with the addition of 0.3%, nano alumina by weight of cement workability decreased by 31%. Compressive strength increased by 4.88% with the addition of 0.6% superplasticizer but with the addition of 0.3% nano alumina by weight of cement compressive strength increased by 18.60%. Also, flexural strength increased by 1.21% with the addition of 0.6% superplasticizer by weight of cement but with the addition of 0.3% nano alumina by weight of cement flexural strength increased by 8.76%. With the addition of superplasticizer, alite and belite phases remained un-hydrated but with the addition of nano alumina alite phase was hydrated while belite phase was un-hydrated. The size of belite crystals in mixes having nano alumina was less than that of mix having 0.6% superplasticizer. Also with the addition of nano alumina, a calcium aluminum silicate phase was formed which was responsible for the increment of strength in mixes having nano alumina.
Originality/value
Incorporation nano alumina (Al2O3) in concrete will not only reduce industrial aluminum waste but will also reduce CO2 emission. Nano alumina (Al2O3) also changes morphology of concrete at micro structural level.
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