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Article
Publication date: 2 January 2018

V.V. Ravikumar and S. Kumaran

The purpose of this paper is to study the corrosion behaviour of Al-12Zn-3Mg-2.5Cu alloy by cast, precipitation hardening and non-isothermal step rolling cum cold/cryo rolling

Abstract

Purpose

The purpose of this paper is to study the corrosion behaviour of Al-12Zn-3Mg-2.5Cu alloy by cast, precipitation hardening and non-isothermal step rolling cum cold/cryo rolling (−80 and −196°C) in 3.5 per cent NaCl solution.

Design/methodology/approach

Aluminium alloy with high alloying concentration (Zn: 12 per cent, Mg: 3 per cent, Cu: 2.5 per cent) was prepared by squeeze casting method with controlled process parameters. The cast alloy was solution treated at 450°C for 24 h and aged at 120°C with varying time intervals. Initially, the alloy also underwent non-isothermal step rolling from 6 mm to 3 mm at 400-100°C at the step of 100ºC with 15% reduction in thickness. Non-isothermal rolled alloy (3 mm thickness) was the starting material for further rolling at three different temperatures, such as room temperature, −80 and −190°C with 85 per cent reduction. Microstructural evolution during precipitation and thermo-mechanical processing was studied with the help of optical microscopy and electron microscopy. A potentio-dynamic polarization study was performed to evaluate the corrosion behaviour of Al-12Zn-3Mg-2.5Cu alloy processed in different conditions in 3.5 per cent NaCl solution.

Findings

There is a distinct evidence that the alloy exhibits varying corrosion resistance by changing its structural features. In fact, the alloy with ultra-fine grained structure exhibits good corrosion resistance than that of alloy in cast. This is attributed to a greater grain boundary region with high dislocation density, and plastic strain adversely affects the corrosion resistance.

Originality/value

The results obtained by this investigation help in understanding the effect of precipitation hardening and non-isothermal step rolling cum cold/cryo rolling (−80 and −196°C) on corrosion behaviour.

Details

Anti-Corrosion Methods and Materials, vol. 65 no. 1
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 20 August 2019

G. Yoganjaneyulu, Y. Phaneendra, V.V. Ravikumar and C. Sathiya Narayanan

The purpose of this paper is to investigate the void coalescence and corrosion behaviour of titanium Grade 4 sheets during single point incremental forming (SPIF) process with…

Abstract

Purpose

The purpose of this paper is to investigate the void coalescence and corrosion behaviour of titanium Grade 4 sheets during single point incremental forming (SPIF) process with various spindle rotational speeds. The development of corrosion pits in 3.5 (%) NaCl solution has also been studied during SPIF process.

Design/methodology/approach

In this current research work, the void coalescence analysis and corrosion behaviour of titanium Grade 4 specimens were studied. A potentio-dynamic polarization (PDP) study was conducted to investigate the corrosion behaviour of titanium Grade 4 processed samples with various spindle speeds in 3.5 (%) NaCl solution. The scanning electron microscope and transmission electron microscope analysis was carried out to study the fracture behaviour and corrosion morphology of processed samples.

Findings

The titanium Grade 4 sheets obtained better formability and corrosion resistance by increasing the CNC spindle rotational speeds. In fact that, the significant plastic deformation affects the corrosion rate with various spindle speeds were recorded.

Originality/value

The spindle rotational speeds and vertical step depths increases then the titanium Grade 4 sheets showed better formability, void coalescence and corrosion behaviour as the same is evidenced in forming limit diagram and PDP curves.

Details

Anti-Corrosion Methods and Materials, vol. 66 no. 6
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 16 June 2022

Jun Zhu, Wei Luo, Wentao Xv, Shuigen Xv, XinYang Zhang and Jiefang Zhao

This paper aims to study the electrochemical corrosion performance of ultrafine-grained (UFG) Cu bulk in 0.5 M NaCl solution.

Abstract

Purpose

This paper aims to study the electrochemical corrosion performance of ultrafine-grained (UFG) Cu bulk in 0.5 M NaCl solution.

Design/methodology/approach

UFG Cu bulk were prepared by impacting at −196°C and following heat treatment. The electrochemical corrosion behaviors of coarse-grained (CG), impacted and subsequently annealed at 190°C Cu bulks were studied.

Findings

All the bulks displayed typical active-passive-transpassive behaviors (dual passive films without stable passive regions). The resistance to corrosion of impacted Cu bulk was notably superior to that of CG Cu bulk, and subsequently annealing further improved its corrosion resistance.

Social implications

Except for mechanical properties, corrosion performance has been considered to be one of the most important aspects in bulk UFG metallic materials research for the prospective engineering applications.

Originality/value

Cryogenic impacting could effectively reduce grain size of CG Cu bulk to UFG scale and induce high density dislocation. Subsequent annealing resulted in a further decrease of grain size even to nanoscale, as well as nanometer twins. The grain refinement, high density dislocation and annealing twins effectively enhance the passivation capability, resulting in an increase in the corrosion resistance.

Details

Anti-Corrosion Methods and Materials, vol. 69 no. 5
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 12 January 2010

K. Sivaprasad, V. Swarnalatha, V.V. Ravikumar and V. Muthupandi

The purpose of this paper is to study the corrosion behavior of as‐cryorolled and cryorolled‐short annealed commercially pure aluminum (CP‐Al) in 3.5 percent NaCl solution.

Abstract

Purpose

The purpose of this paper is to study the corrosion behavior of as‐cryorolled and cryorolled‐short annealed commercially pure aluminum (CP‐Al) in 3.5 percent NaCl solution.

Design/methodology/approach

Cast and homogenized CP‐Al samples are cryorolled from 7 to 0.7 mm at −80°C. Samples are short annealed at 125, 150 and 175°C for 3 min. Transmission electron microscope studies are performed to understand the effect of cryorolling and short annealing on microstructure. Corrosion behavior of these samples in 3.5 percent NaCl solution is evaluated by potentiodynamic polarization studies.

Findings

Though cryorolling adversely affects corrosion resistance of CP‐Al, short annealing can restore the loss in corrosion resistance partially by the recovery process. The extent of restoration of loss in corrosion resistance by short annealing is influenced by the texture.

Originality/value

The results obtained by this investigation help in understanding the effect of cryorolling and short annealing on corrosion behavior of CP‐Al.

Details

Anti-Corrosion Methods and Materials, vol. 57 no. 1
Type: Research Article
ISSN: 0003-5599

Keywords

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