Search results

Gourd fibres (GF) are a natural biodegradable fibre material with excellent mechanical properties and high tensile strength. The use of natural fibres in composite materials has gained popularity in recent years due to their various advantages, including renewability, low cost, low density and biodegradability. Gourd fibre is one such natural fibre that has been identified as a potential reinforcement material for composites. However, it has low surface energy and hydrophobic nature, which makes it difficult to bond with matrix materials such as polyester. To overcome this problem, chemically adapted gourd fibre has been proposed as a solution. Chemical treatment is one of the most widely used methods to improve the properties of natural fibres. This research evaluates the feasibility and effectiveness of incorporating chemically adapted gourd fibre into polyester composites for industrial fabrication. The purpose of this study is to examine the application of chemically modified GF in the production of polyester composite engineering materials.

This work aims to evaluate the effectiveness of chemically adapted gourd fibre in improving the adhesion of gourd fibre with polyester resin in composite fabrication by varying the GF from 5 to 20 wt.%. The study involves the preparation of chemically treated gourd fibre through surface modification using sodium hydroxide (NaOH), permanganate (KMnO₄) and acetic acid (CH₃COOH) coupling agents. The mechanical properties of the modified fibre and composites were investigated. It was then characterized using scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FTIR) to determine the changes in surface morphology and functional groups.

FTIR characterization showed that NaOH treatment caused cellulose depolymerization and caused a significant increase in the hydroxyl and carboxyl groups, showing improved surface functional groups; KMnO₄ treatment oxidized the fibre surface and caused the formation of surface oxide groups; and acetic acid treatment induced changes that primarily affected the ester and hydroxyl groups. SEM study showed that NaOH treatment changed the surface morphology of the gourd fibre, introduced voids and reduced hydrophilic tendencies. The tensile strength of the modified gourd fibres increased progressively as the concentration of the modification chemicals increased compared to the untreated fibres.

This work presents the designed composite with density, mechanical properties and microstructure, showing remarkable improvements in the engineering properties. An 181.5% improvement in tensile strength and a 56.63% increase in flexural strength were got over that of the unreinforced polyester. The findings from this work will contribute to the understanding of the potential of chemically adapted gourd fibre as a reinforcement material for composites and provide insights into the development of sustainable composite materials.

Past and current uses of chemical treatments to control or eradicate fungal infections and/or insect infestations in buildings have led to a number of reported cases where occupants and users of these buildings have suffered various physical symptoms. The role of chemical treatments, whether as biocides, fungicides, insecticides or wood preservatives, has therefore come under scrutiny and various countries are now reviewing their use in favour of a more benign approach to the management of decay in buildings. Growing concern for the environment and the health of those treating or living in treated buildings has also led to changes in the way we perceive and deal with buildings and building defects. As a result, the conventional approach to survey, defect diagnosis and remediation has to be re‐thought and placed in the context of a wider environmental agenda. This paper provides evidence for how historic chemical treatments can have effects on the health of the building and its occupants, and considers the implications of such treatments for those charged with specifying or undertaking works to the fabric of affected buildings.

Chemical treatability of dairy wastewater originating from a dairy and dairy products plant at Istanbul was investigated on the basis of chemical oxygen demand (COD) parameter as a pre‐treatment alternative. FeCl₃, FeSO₄ and alum were used as coagulants in the jar‐test experiments of four sets of daily composite wastewater samples taken once every month. The effect of acid cracking has also been searched through acid addition and pH adjustment. Characterisation studies demonstrated that wastewater characteristics varied within a wide range in spite of no significant production changes at the plant during the experimentation period. Optimum coagulant dosage has been determined as 200mg l^–1 for all the coagulants with the optimum pH values between 4 and 4.5 for FeCl₃ and FeSO₄, and 5‐6 for alum. Maximum overall COD removal efficiencies were obtained as 72 per cent, 59 per cent and 54 per cent for FeCl₃, FeSO₄ and alum, respectively. Nevertheless, COD removal efficiencies were found to be inadequate to meet the current discharge standards of Greater Metropolitan Istanbul to sewer systems indicating that chemical treatment is insufficient for discharging chemically pre‐treated dairy wastewater to a sewage system, which was actually the main objective of the study. The results showed that the wastewater composition greatly influences the maximum removal efficiencies and also the conditions for optimum coagulation. However, attention to such chemical treatment studies on dairy wastewater has started to accelerate within the last decade in various countries of the world, such as United Arabic Emirates and Scandinavian countries where the targets of applying chemical treatment varied. In Scandinavian countries, biodegradable coagulants have been applied to use the sludge arising from the system for livestock feeding, leading to reuse of sludge. In Arabic Emirates, chemically treated dairy effluents are utilised for irrigation purposes. These recent studies point out that application of chemical treatment to dairy wastewater with various coagulants lead to a variety of utilities apart from being a pre‐treatment alternative.

The purpose of this paper is to propose a process management framework for Chemical Waste Treatment Laboratories (CWTL) that can be used as a management tool to identify and manage critical process.

Proposition of a generic classification for categories of chemical waste; use of the ABC analysis as a tool for analysis of priority in relation to the inputs of an CWTL; use of the process matrix (variety vs volume) to identify the key resources required to perform the activities of a CWTL; and use of mapping process techniques to map the processes defined and calculate times.

The proposed framework was applied to a CWTL at University of São Paulo, Brazil, and showed that the high variability of demand is a significant factor in the management of this laboratory, requiring processes that are flexible to meet this demand. The results showed that the applicability of the production and operations management theories within the scope of process management of CWTLs, proved to be useful tools for improving the treatment efficiency of chemical waste in these facilities.

The novelty of this work is in the fact of using production and operations management tools in the management of CWTLs to propose diagnoses to improve the management of their processes. The proposition of a comprehensive classification for chemical wastes generated in CWTLs is also highlighted.

Examines the treatability of highly polluted wastewater from a dairy factory prior to its final disposal into the public sewerage system. Physical treatment of the dairy waste via aeration, followed by settling, resulted in a 25 per cent chemical oxygen demand (COD) reduction and elimination of odours. Chemical treatment achieved almost 50 per cent removal of COD. The chemical‐biological process using activated sludge/trickling filter resulted in 64 per cent and 90 per cent removal of the volatile organic matter value respectively. However, the quality of the waste produced does not meet with the National Regulatory Standards for wastewater disposal into the sewerage system. Chemical‐biological treatment using an upflow anaerobic reactor succeeded in reducing the pollutional parameters to coincide with the limits of the Egyptian Law 93/1962 and produces biogas as a source of energy at a rate of 0.39m³/kg COD removed.

Due to intrinsic limitations, fused deposition modelling (FDM) products suffer from the bad surface finish and inaccurate dimensional accuracies restricting its usage in many applications. Hence, there is a need for processing polymer patterns before, during and after their productions. This paper aims to highlight the importance of pre- and post-processing treatments on the FDM-based acrylonitrile butadiene styrene patterns improving its surface quality so, that it can be used in rapid investment casting process for making medical implants and other high precision components.

As a part of pre-processing treatment, the machine parameters affecting the surface quality were identified and optimised using design of experiments. The patterns developed after the first stage of optimisation were given different post-processing treatments, which included vapour smoothening, chemical treatment and sand paper polishing. The results were compared and the best ones were used for making patterns for making medical implants via rapid investment casting technique. The surface quality was checked while the dimensional changes happening during the stages of this hybrid technique were recorded using a three-dimensional optical scanner.

The surface roughness of the FDM based ABS patterns reduced from 21.63 to 14.40 µm with pre-processing treatments. Chemical treatment (post-processing treatment) turned to be the most suitable technique for reducing the surface roughness further down to 0.30 µm. Medical implants that used these pre- and post-processing treatments gave an average surface roughness of 0.68 µm. Cost and lead time comparisons showed that rapid investment casting technique can be a better method for low volume, customised and with specific requirements.

FDM parts/medical implants produced by rapid investment casting technique suffer from the inferior surface finish and inaccurate dimensional accuracies limiting its applications. A systematic approach to overcome this issue is presented in this research paper. This will directly help the end users and the manufacturers of medical implants, wherein, better surface finish and dimensionally accurate components are expected.

As the United States is making a significant move toward rejoining the Paris Agreement on climate change, there is a high demand for sustainable solutions across various industries, including construction and hospitality sectors. The aim of this project was to design and model an on-site greywater treatment system for a hotel building for the effective reuse of sewage water. The study considered Los Angeles, California, as a case study location and referred to respective climate conditions and construction standards.

This study considered various options of greywater treatment plants such as membrane bioreactor (MBR), sequencing batch reactor and reverse osmosis with upflow anaerobic sludge blanket which were carefully reviewed and modeled using the GPS-X software. The design and modeling results were verified by hand calculations and were followed by the estimation of capital and operational expenses required for the implementation of the plants.

Having relatively low capital and operational expenditure requirements as well as superior technical performance, the MBR plant proved to be the most effective solution for the considered location and standards and was recommended for use in hotel buildings.

Designing and modeling several greywater treatment plants allowed selecting the most optimal option which in the long run will help to preserve the eco-system, stay compliant with the government laws and regulations and be financially sustainable.

The outcomes of the present study provide a detailed procedure for designing and modeling a greywater treatment plant for a hotel building that can be used for the localities with a similar climate. The most effective option selected as a result of cost-benefit analysis provides an efficient and viable solution for the relevant industry and the type of buildings.

Micropollutants in the aquatic environment pose threats to both ecosystems and human health. Traditional wastewater treatment plants (WWTP) reduce some micropollutants, especially those who adhere to sludge or suspended matter. The hydrophilic micropollutants, on the other side, which may be non-biodegradable and resistant to UV-treatment etc. are typically transported untreated into the water recipients. This paper contains a literature study on the state of the art of advanced wastewater treatment technologies for reducing micropollutants such as pharmaceutical degradation products, personal care products, surfactants and industrial chemicals including heavy metals.

This literature study is completed using the most extensive and expansive literature database in the World to date, Google Scholar (GS). Published papers in recognized scientific journals are sought out in GS, and for relevance for this literature study, papers published here from 2016 and onwards (the last 5 years) have been chosen to eliminate irrelevant studies.

The result of the study is that there are many promising technologies on the market or emerging; however, no one solution treats every micropollutant equally well. Since advanced technologies often require expensive investments for municipalities and companies, it is important to identify which micropollutants pose the highest risk towards human health and the environment, because choosing systems to eliminate them all is not economically wise, and even choosing a system combining the existing technologies can be more expensive than states, municipalities and private companies are capable of investing in.

The research is limited to published papers on GS, which may omit certain papers published in closed databases not sharing their work on GS.

The practical implications are that practitioners cannot find go-to solutions based on the conclusions of the research and thus need to use the results to investigate their own needs further in order to make the wisest decision accordingly. However, the paper outlines the state of the art in advanced wastewater treatment and explains the benefits and downsides of the technologies mentioned; however, more research in the field is required before practitioners may find a proper solution to their specific issues.

The social implications are that the consequences of introducing a removal of micropollutants from the water environment can ultimately effect the citizens/consumers/end-users through added costs to the tariffs or taxes on advanced wastewater treatment, added costs on everyday goods, wares and products and added costs on services that uses goods, wares and products that ultimately produces micropollutants affecting the water environment.

This paper presents a much needed state of the art regarding the current advanced technologies to mitigate micropollutants in wastewater. The overview the paper provides supports politics on national as well as international levels, where larger unions such as the EU has stated that advanced wastewater treatment will be the next step in regulating pollutants for aquatic outlet.

While aiming to create methods for fibre recycling, the question of colours in waste textiles is also in focus; whether the colour should be kept or should be removed while recycling textile fibre. More knowledge is needed for colour management in a circular economy approach.

The research included the use of different dye types in a cotton dyeing process, the process for decolourizing and the results. Two reactive dyes, two direct dyes and one vat dye were used in the study. Four chemical treatment sequences were used to evaluate colour removal from the dyed cotton fabrics, namely, HCE-A, HCE-P-A, HCE-Z-P-A and HCE-Y-A.

The objective was to evaluate how different chemical refining sequences remove colour from direct, reactive and vat dyed cotton fabrics, and how they influence the specific cellulose properties. Dyeing methods and the used refining sequences influence the degree of colour removal. The highest achieved final brightness of refined cotton materials were between 71 and 91 per cent ISO brightness, depending on the dyeing method used.

Only cotton fibre and three different colour types were tested.

With cotton waste, it appears to be easier to remove the colour than to retain it, especially if the textile contains polyester residues, which are desired to be removed in the textile refining stage.

Colour management in the CE context is an important new track to study in the context of the increasing amount of textile waste used as a raw material.

The purpose of this study is to prolong the service life of the Al–Si alloy cylinder and achieve the objective of energy saving and emission reduction by the composite treatments.

Chemical etching + laser texturing + filled MoS₂ composite treatment was applied to the friction surface of aluminum–silicon (Al–Si) alloy cylinder. The friction coefficient and wear loss were measured to characterize the tribology property of cylinders.

The composite-treated Al–Si alloy cylinder had the lowest friction coefficient and weight loss. The friction coefficient and weight loss of the composite treatment were approximately 27.08% and 54.17% lower than those of the untreated sample, respectively. The laser micro-textures control the release of solid lubricant to the interface of friction pairs slowly, which prolongs the service life of cylinders.

The synergistic effect of the chemical etching + laser texturing + filled MoS2 modified the tribology properties of Al–Si alloy cylinder. The chemical etching raised the silicon particles to bear the load, and laser micro-textures control the release of solid lubricant to improve the lubrication property.