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1 – 10 of 524Rania Abdel Gwad Eloriby, Wael Sabry Mohamed and Hamdy Mohamed Mohamed
The purpose of this study is to evaluate the effectiveness of nanocontainer solutions in removing deteriorated and aged polymers commonly used in coating and consolidating…
Abstract
Purpose
The purpose of this study is to evaluate the effectiveness of nanocontainer solutions in removing deteriorated and aged polymers commonly used in coating and consolidating archaeological glass.
Design/methodology/approach
This study focused on characterizing glass surfaces coated with two commonly used polymeric materials in archaeological glass preservation. Furthermore, the study evaluates the elimination of these coatings from the surfaces by using innovative aqueous systems composed of micellar solutions (MS) and oil-in-water (O/W) Texapon-P microemulsions (TEX). Glass samples coated with selected polymers were subjected to thermal and photochemical aging to simulate natural degradation conditions. This study aimed to evaluate the effectiveness of nanocontainer aqueous systems compared to acetone (Ac), a conventional solvent commonly used for removal procedures. The characterization procedures involved transmission electron microscopy, USB digital microscopy, scanning electron microscopy, color alteration and gravimetric measurement.
Findings
The findings indicate that the effectiveness of novel techniques using aqueous nanocontainer systems is quite promising when considering a “green approach” to preserving cultural heritage. Microscopic examination demonstrated the efficacy of MS in effectively removing acrylic and vinyl polymers from the glass surface. Furthermore, TEX proved effective in removing polyvinyl acetate (PVA) over Paraloid B72 (B-72). In addition, the measurement of color alteration values revealed a decrease after using MS compared to the standard sample before applying the polymers, with values of ΔE = 1.48 and 1.82 for B-72 polymer and PVA, respectively.
Originality/value
This research provides nanocontainer solutions for removing aged polymers from the glass surface. This makes the current study a promising step for treating archaeological glass.
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Gomaa Abdel-Maksoud, Aya Abdallah, Rana Youssef, Doha Elsayed, Nesreen Labib, Wael S. Mohamed and Medhat Ibrahim
This study aims to evaluate the efficiency of using some polymers at different concentrations in the consolidation of vegetable-tanned leather artifacts.
Abstract
Purpose
This study aims to evaluate the efficiency of using some polymers at different concentrations in the consolidation of vegetable-tanned leather artifacts.
Design/methodology/approach
New vegetable-tanned leather samples were prepared. The consolidants used were polyacrylamide (PAM) and polymethyl methacrylate/hydroxyethyl methacrylate (MMA-HEMA). Accelerated heat aging was applied to the untreated and treated samples. Analytical techniques used were Fourier transform infrared spectroscopy (FTIR), digital microscope, scanning electron microscope (SEM), change of color and mechanical properties.
Findings
The characteristic FTIR bands showed the effect of accelerated heat aging on the molecular structure of the studied samples, but treated and aged treated samples used were better than aged untreated samples. Microscopic investigations (digital and SEM), and mechanical properties proved that 2% was the best concentration for polymers used. The change in the total color difference of the treated and aged treated samples was limited.
Originality/value
This study presents the important results obtained from PAM and poly(MMA-HEMA) used for the consolidation of vegetable-tanned leather artifacts. The best results of the studied polymers can be applied directly to protect historical vegetable-tanned leathers.
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Self-crosslinked long fluorocarbon acrylate polymer latex has good hydrophobic and oleophobicity, weather resistance, aging resistance, stability and other excellent properties…
Abstract
Purpose
Self-crosslinked long fluorocarbon acrylate polymer latex has good hydrophobic and oleophobicity, weather resistance, aging resistance, stability and other excellent properties, which make the polymer be widely used in coatings, dyes, adhesives and other products. The purpose of this study is to prepare self-crosslinked long fluorocarbon acrylate polymer latex via semi-continuous seeded emulsion technology and carry out comparative study on two different cross-linked monomers.
Design/methodology/approach
Methyl methacrylate (MMA) and butyl acrylate (BA) were used as the main monomers, dodecafluoroheptyl methacrylate (DFMA) as the fluoromonomer, hydroxypropyl methacrylate (HPMA) and N-methylol acrylamide (NMA) as cross-linked monomers, and 1-allyloxy-3–(4-nonylphenol)-2-propanol polyoxyethylene (10) ether (ANPEO10) and 1-allyloxy-3–(4-nonylphenol)-2-propanol polyoxyethylene (10) ether ammonium sulfate (DNS-86) as compound emulsifiers via the semicontinuous-seeded emulsion polymerization.
Findings
The properties of the polymer emulsions, which are prepared with two different cross-linked monomers, are compared and discussed, and it is concluded that HPMA is more suitable for the preparation of self-crosslinked polymer emulsions. The formula of the polymer latex is ANPEO10: DNS-86 = 1:1, and the mass ratio of the monomers used in the polymer is MMA: BA: DFMA: HPMA = 14.40:14.40:0.60:0.60.
Practical implications
Self-crosslinked long fluorocarbon acrylate polymer latex can be used in many fields such as coatings, dyes, adhesives and other products.
Originality/value
The self-crosslinked long fluorocarbon acrylate polymer latex is prepared by mixing the nonionic emulsifier ANPEO10 and the anionic emulsifier DNS-86 when potassium persulfate is used as the thermal decomposition initiator and the semicontinuous-seeded emulsion technology is adopted and the comparative study on two different cross-linked monomer is carried out, which is not reported in the open literatures.
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Megavannan Mani, Thiyagu Murgaiyan and Pradeep Kumar Krishnan
This study focuses on the structural performance assessment of hybrid polymer composites for pick-and-place robot grippers used in critical infrastructure. This research involved…
Abstract
Purpose
This study focuses on the structural performance assessment of hybrid polymer composites for pick-and-place robot grippers used in critical infrastructure. This research involved the creation of composite materials with different nanoparticle concentrations, followed by extensive testing to assess the mechanical properties of the materials, such as strength, stiffness and durability.
Design/methodology/approach
The composites comprised bidirectional interply inclined carbon fibers (C), S-glass fibers (SG), E-glass (EG), an epoxy matrix and silica nanoparticles (SNiPs). During construction, the composite materials must be carefully layered using quasi-static sequence techniques (45°C1/45°SG2/45°EG2/45°C1/45°EG2/45°SG2/45°C1) to obtain the epoxy matrix reinforcement and bonding using 0, 2, 4 and 6 wt. % of silica nanoparticles.
Findings
According to various test findings, the 4 wt. % of SNiPs added to polymer plates exhibits the maximum strength outcomes. The average results of the tensile and flexural tests for the polymer composite plates with 4 wt. % addition SNiPs were 127.103 MPa and 223.145 MPa, respectively. The average results of the tensile and flexural tests for the plates with 0 wt.% SNiPs were 115.457 MPa and 207.316 MPa, respectively.
Originality/value
The authors hereby attest that the research paper they have submitted is the result of their own independent and unique labor. All of the sources from which the thoughts and passages were derived have been properly credited. The work has not been submitted for publication anywhere and is devoid of any instances of plagiarism.
Highlights
The study enhances the engineering materials for innovative applications.
The study explores the mechanical behavior of carbon/S-glass/E-glass fiber composites.
Silica nanoparticles were enhancing mechanical characteristics of the composite structure.
The study enhances the engineering materials for innovative applications.
The study explores the mechanical behavior of carbon/S-glass/E-glass fiber composites.
Silica nanoparticles were enhancing mechanical characteristics of the composite structure.
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Jianqing Hu, Hongjun He, Feiliang Dai, Xingyu Gong and Haowei Huang
The purpose of this paper is to develop the efficiency of styrene-acrylate (SA) emulsions for polymer cement waterproof coatings with improved bacteria resistance and mechanical…
Abstract
Purpose
The purpose of this paper is to develop the efficiency of styrene-acrylate (SA) emulsions for polymer cement waterproof coatings with improved bacteria resistance and mechanical properties.
Design/methodology/approach
For effective bacteria resistance and excellent mechanical properties, various concentrations of methacryloxyethylhexadecyl dimethylammonium bromide (MHDB) were synthesised and incorporated into SA emulsions. The properties of SA emulsions modified with MHDB were characterised and compared with those of unmodified ones according to the formulations of polymer cement waterproof coatings.
Findings
The SA emulsions modified with MHDB exhibited significant enhancement of bacteria resistance and mechanical properties over the unmodified ones. The positive quaternary nitrogen and long-chain alkyl groups of MHDB in SA emulsions could attract phospholipid head groups of bacterial and insert them into the cell wall, which results in biomass leak and bactericidal effect. Moreover, MHDB as a softened monomer was beneficial to the synthesis of SA copolymer with low glass-transition temperature (Tg), then the copolymer and cement would form a more compact film which was the main reason for the enhancement of mechanical properties.
Research limitations/implications
The modifier MHDB was synthesised from diethylaminoethyl methacrylate (DEAM) and 1-bromohexadecane. Besides, the congeners of MHDB could be synthesised from DEAM and 1-bromododecane, 1-tetradecyl dromide, 1-octadecyl bromide, etc. In addition, the efficiency of other modifications into SA emulsions for antibacterial polymer cement waterproof coatings could be studied as well.
Practical implications
The method provided a practical solution for the improvement of water-based antibacterial acrylate polymer cement waterproof coatings.
Originality/value
The method for enhancing bacteria resistance and mechanical properties of the waterproof coating was novel and valuable.
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Linghuan Li, Shibin Sun, Ronghua Zhuang, Bing Zhang, Zeyu Li and Jianying Yu
This study aims to develop a polymer cement-based waterproof coating with self-healing capability to efficiently and intelligently solve the building leakage caused by cracking of…
Abstract
Purpose
This study aims to develop a polymer cement-based waterproof coating with self-healing capability to efficiently and intelligently solve the building leakage caused by cracking of waterproof materials, along with excellent durability to prolong its service life.
Design/methodology/approach
Ion chelators are introduced into the composite system based on ethylene vinyl acetate copolymer emulsion and ordinary Portland cement to prepare self-healing polymer cement-based waterproof coating. Hydration, microstructure, wettability, mechanical properties, durability, self-healing performance and self-healing products of polymer cement-based waterproof coating with ion chelator are investigated systematically. Meanwhile, the chemical composition of self-healing products in the crack was examined.
Findings
The results showed that ion chelators could motivate the hydration of C2S and C3S, as well as the formation of hydration products (C-S-H gel) of the waterproof coating to improve its compactness. Compared with the control group, the waterproof coating with ion chelator had more excellent water resistance, alkali resistance, thermal and UV aging resistance. When the dosage of ion chelator was 2%, after 28 days of curing, cracks with a width of 0.29 mm in waterproof coating could fully heal and cracks with a width of 0.50 mm could achieve a self-healing efficiency of 72%. Furthermore, the results reveal that the self-healing product in the crack was calcite crystalline CaCO3.
Originality/value
A novel ion chelator was introduced into the composite coating system to endow it with excellent self-healing ability to prolong its service life. It has huge application potential in the field of building waterproofing.
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Thameem Hayath Basha, Sivaraj Ramachandran and Bongsoo Jang
The need for precise synthesis of customized designs has resulted in the development of advanced coating processes for modern nanomaterials. Achieving accuracy in these processes…
Abstract
Purpose
The need for precise synthesis of customized designs has resulted in the development of advanced coating processes for modern nanomaterials. Achieving accuracy in these processes requires a deep understanding of thermophysical behavior, rheology and complex chemical reactions. The manufacturing flow processes for these coatings are intricate and involve heat and mass transfer phenomena. Magnetic nanoparticles are being used to create intelligent coatings that can be externally manipulated, making them highly desirable. In this study, a Keller box calculation is used to investigate the flow of a coating nanofluid containing a viscoelastic polymer over a circular cylinder.
Design/methodology/approach
The rheology of the coating polymer nanofluid is described using the viscoelastic model, while the effects of nanoscale are accounted for by using Buongiorno’s two-component model. The nonlinear PDEs are transformed into dimensionless PDEs via a nonsimilar transformation. The dimensionless PDEs are then solved using the Keller box method.
Findings
The transport phenomena are analyzed through a comprehensive parametric study that investigates the effects of various emerging parameters, including thermal radiation, Biot number, Eckert number, Brownian motion, magnetic field and thermophoresis. The results of the numerical analysis, such as the physical variables and flow field, are presented graphically. The momentum boundary layer thickness of the viscoelastic polymer nanofluid decreases as fluid parameter increases. An increase in mixed convection parameter leads to a rise in the Nusselt number. The enhancement of the Brinkman number and Biot number results in an increase in the total entropy generation of the viscoelastic polymer nanofluid.
Practical implications
Intelligent materials rely heavily on the critical characteristic of viscoelasticity, which displays both viscous and elastic effects. Viscoelastic models provide a comprehensive framework for capturing a range of polymeric characteristics, such as stress relaxation, retardation, stretching and molecular reorientation. Consequently, they are a valuable tool in smart coating technologies, as well as in various applications like supercapacitor electrodes, solar collector receivers and power generation. This study has practical applications in the field of coating engineering components that use smart magnetic nanofluids. The results of this research can be used to analyze the dimensions of velocity profiles, heat and mass transfer, which are important factors in coating engineering. The study is a valuable contribution to the literature because it takes into account Joule heating, nonlinear convection and viscous dissipation effects, which have a significant impact on the thermofluid transport characteristics of the coating.
Originality/value
The momentum boundary layer thickness of the viscoelastic polymer nanofluid decreases as the fluid parameter increases. An increase in the mixed convection parameter leads to a rise in the Nusselt number. The enhancement of the Brinkman number and Biot number results in an increase in the total entropy generation of the viscoelastic polymer nanofluid. Increasing the strength of the magnetic field promotes an increase in the density of the streamlines. An increase in the mixed convection parameter results in a decrease in the isotherms and isoconcentration.
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Karel Dvorak, Lucie Zarybnicka, Radek Ševčík, Michal Vopalensky and Irena Adamkova
The purpose of this paper is to clarify the relationship between the use of different polymer matrices for the preparation of composite materials, namely, polyethylene…
Abstract
Purpose
The purpose of this paper is to clarify the relationship between the use of different polymer matrices for the preparation of composite materials, namely, polyethylene terephthalate-glycol (PET-G) and polyamide (PA), using Composite Fiber Co-Extrusion technology with the application of two types of carbon fibers, short and continuous. The aim of the study is also to extend the knowledge of the production of composite materials with a defined structure from the point of view of their influence on the microstructure and their physical-mechanical properties.
Design/methodology/approach
As part of the experiment, four types of samples were prepared, namely, two types of samples with PA polymer matrix and two types with PET-G polymer matrix. All types contained short carbon fibers and always one set from each polymer matrix in addition to continuous carbon fibers. All types were prepared using the same 3D printing parameters to avoid any further influence. The samples were then tested for microstructure using microCT, mechanical properties using a tensile test and dilatation characteristics from the point of view of aerospace applications. Finally, the raw materials themselves were tested.
Findings
The paper provides insight into the influence of polymer matrix types on the physico-mechanical properties of 3D printed composites. The analysis confirmed that the physico-mechanical results varied with respect to the interface between the polymer matrix and the carbon fiber. The implications of the conclusions can be extended to the development of products in the aerospace and automotive sectors.
Originality/value
This study provides information for composite applications in the aerospace industry, focusing on evaluating dilatation characteristics within very low temperatures (−60 °C) when using carbon fibers (continuous carbon fibers, short carbon fibers and a combination of both) in two types of thermoplastic matrices. This perspective on materials characterisation for aerospace applications is a very important and unpublished approach within the 3D printing of composites. These characteristics are important parameters in the design of prototypes and functional samples with regard to the resulting behaviour in real conditions.
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Kristijan Breznik, Naraphorn Paoprasert, Klara Novak and Sasitorn Srisawadi
This study aims to identify research trends and technological evolution in the polymer three-dimensional (3D) printing process that can effectively identify the direction of…
Abstract
Purpose
This study aims to identify research trends and technological evolution in the polymer three-dimensional (3D) printing process that can effectively identify the direction of technological advancement and progress of acceptance in both society and key manufacturing industries.
Design/methodology/approach
The Scopus database was used to collect data on polymer 3D printing papers. This study uses bibliometric approach along with network analytic techniques to identify and discuss the most important countries and their scientific collaboration, compares income groups and analyses keyword trends.
Findings
It was found that top research production results from heavy investments in research and development. The USA has the highest number of papers among the high-income countries. However, scientific production in the other two income groups is strongly dominated by China and India. Keyword analysis shows that countries with lower incomes in certain areas, such as composite and bioprinting, have fallen behind other groups over time. International collaborations were suggested as mechanisms for those countries to catch up with the current research trends. The evolution of the research field, which started with a focus on 3D printing processes and shifted to printed part designs and their applications, was discussed. The advancement of the research topic suggests that translational research on polymer 3D printing has been led mainly by research production from higher-income countries and countries with large research and development investments.
Originality/value
Previous studies have conducted performance analysis, science mapping and network analysis in the field of 3D printing, but none have focused on global research trends classified by country income. This study has conducted a bibliometric analysis and compared the outputs according to various income levels according to the World Bank classification.
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Burcu Küçükoğlu Doğan, Abdurrahim Dal, Görkem Ağören and Tuncay Karaçay
In industry applications, polymer hybrid bearings have become widespread in recent years owing to the lack of lubricant requirements, particularly in areas requiring hygiene. The…
Abstract
Purpose
In industry applications, polymer hybrid bearings have become widespread in recent years owing to the lack of lubricant requirements, particularly in areas requiring hygiene. The additive manufacturing method gives significant advantages to have complex machinery parts, and it has become popular in the industry in recent years. However, it has some inherent disadvantages caused by layered deposition/addition of the materials, and the probability of the localized defect is much higher than in the conventional manufacturing methods. This study aims to investigate the effect of the outer race defect on the characteristics of vibration and service lifetime of hybrid polymer ball bearings produced with the stereolithography (SLA) additive manufacturing method.
Design/methodology/approach
In this study, polymer bearings’ races were produced with the additive manufacturing SLA method, and the outer race defect was analyzed with measured vibrations.
Findings
The results show that the additive manufacturing method suggests a practical solution for producing a polymer hybrid ball bearing. On the other hand, the hybrid three-dimensional-printed bearing, which has an outer race defect, worked for approximately 8 h without any problems under a 1 kg load and a shaft speed of around 1,000 rpm. In addition, when there is a defect in the outer and/or inner race of the ball bearing, the crest factor and kurtosis of the vibration are higher than faultless ball bearing, as expected.
Originality/value
This paper provides valuable information on the lifetime and vibration characteristics of polymer hybrid ball bearing produced by means of additive manufacturing.
Peer review
The peer review history for this article is available at: https://publons.com/publon/10.1108/ILT-06-2023-0183/
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