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The effects of ultrasonication on the epoxy resin and its emulsion were investigated to find out the changes in the M_η and molecular structure of epoxy, as well as its room temperature storage stability, centrifugal stability, particle size and its distribution and particle morphology more importantly with the influence of different ultrasonic irradiation time, power and temperature.

The emulsion was prepared using an emulsifier with epoxy resin and by using phase inversion after subjecting to ultrasound irradiation with a power of 200 W at 50°C for 60 min. The changes in the epoxy resin and its emulsion induced by ultrasound were characterized by Ubbelohde viscometer, FT-IR, ¹³C-NMR, high-speed desktop centrifuge, laser particle size analyzer and transmission electron microscope.

The molecular weight of the epoxy resin was initially decreased and then stabilized by the increasing of ultrasonic irradiation time. The mole rate of the epoxy groups in epoxy molecular were decreased by about 14 per cent, resulting from ultrasonic irradiation. The particle size of the emulsion was decreased, while the particle size distribution became uniform in a certain time. The narrow distribution, stable and uniform of waterborne epoxy resin emulsion with more than 60 days room temperature storage period, 80 per cent of the supernatant volume, about 220 nm average particle size was gained with a power of 200 W at 50°C for 60 min.

To overcome the problems commonly encountered with an epoxy emulsion, for example, short storage period and wider particle size, which limit its practical application, the effects of ultrasonic irradiation on the epoxy resin and its emulsion, were investigated. As the stability of emulsion was improved with the introduction of ultrasonic irradiation, the application of epoxy emulsion was improved.

The room temperature storage stability and centrifugal stability of the emulsion were decreased by the mechanical method, and thus, the benefit of an in-depth understanding of the influence of ultrasonic treatment on epoxy resin and its emulsion could further promote the development of water-based coatings.

The dispersity of graphene oxide (GO) has an important effect on the properties of epoxy resin (EP) composites. Many modification and dispersion methods require the use of inert solvents which do not participate in the modification reaction, although GO can be uniformly dispersed in water and alcohol solvents. Based on this requirement, several inert solvents were selected as dispersion solvents to find out the suitable inert solvent for GO dispersion into EP matrix.

Several inert solvents with different solubility parameters were selected as dispersion solvents to prepare GO/EP composite. The microstructure, mechanical properties, insulation properties, dielectric properties and thermal property of the composite were characterized, which was due to find suitable inert solvent for GO dispersion into EP matrix.

The dispersity of N, N-dimethylformamide (DMF) was the best stable suspension state when it was used as solvent instead of occurring sedimentation and agglomeration. Moreover, DMF was further confirmed as a suitable inert solvent for the dispersion of GO into EP according to the mechanical properties, insulation properties and thermal conductivity characterization.

The dispersion of GO in solvents has already been researched, but the traditional solvents, such as alcohols and water, has shown their limitations with the increase of modification methods, which were not suitable for the modification environment such as cyanate graft modification. Therefore, it was very important to choose a kind of inert solvent for dissolving EP matrix and dispersing GO better.

Several inert solvents were used to disperse GO into EP, and the influence of different dispersing solvents on the adhesive was discussed through the analysis of the mechanical properties, insulation properties and thermal conductivity, which was due to explore the inert solvent suitable for GO dispersion.

The purpose of this paper was to comprehensively understand the effects of imidization process on the structure and properties of polyimide (PI) films through the preparation and characterization of a variety of PI/aluminium oxide (Al₂O₃) nanocomposite films by using several imidization-based strategies.

Poly(amic acid) (PAA) containing different amounts of inorganic materials (namely, 0 Wt.%, 4 Wt.%, 8 Wt.%, 12 Wt.% and 16 Wt.%) was synthesized by using pyromellitic dianhydride and 4,4-diaminodiphenyl ether as raw material and N,N-dimethylacetamide as solvent. Subsequently, the solution obtained was casted on a glass substrate and dried by the means of various curing processes. The micro-structure, Fourier transform–infrared spectral features, breakdown field strength, dielectric properties and the corona-resistant time parameters of films were achieved.

The imidization process influences substantially the properties of composite films. Therefore, as the imidization rate is increased, the corona-resistant time and the electrical breakdown strength of composite films are also improved, while the dielectric constant faces a+ decreasing.

In this paper, the impact of imidization process on the performance of PI/nano-Al₂O₃ three-layered composite film is reported. However, there are multiple factors governing these systems (such as, interlayer thickness ratio and humidity), which are not discussed herein.

The current study expounds the relationship between imidization ratios as well as the effect of imidization ratio on the performance of the film.

In this paper, boric acid was loaded on the surface of expandable graphite (EG), polyvinyl alcohol (PVA) and silane coupling agent (KH550) served as a bridge. The purpose of this study was to improve the flame retardant properties of semi-rigid polyurethane, meanwhile, the mechanical properties of the foam got ameliorated.

PVA was dissolved in hot water. EG was added to this solution. After stirring for 0.5 h at 85°C in ultrasonic agitation, the system was put at room temperature to cool. The silane coupling agent KH550 was added dropwise into the solution system, stirring to fully hydrolyze. Boric acid was added into the system, placing it in an oven at 90°C to dry after filtration. Changing of flame retardant properties and mechanical properties of semi-rigid polyurethane adding modified EG were characterized.

The flame retardant performance of the foam with EG has been improved, whereas the tensile strength decreased with an increase in the content of EG. After adding modified EG, compared to semi-rigid polyurethane with EG, flame retardant performance and tensile strength of the foam improved.

In the study reported here, the surface of EG was modified by boric acid. The modified EG was added into semi-rigid polyurethane foam. The flame retardant performance and tensile strength of the foam after adding modified EG were discussed. Results of this research could benefit in-depth study of the influence of adding modified EG to semi-rigid polyurethane. The study could promote the application of flame-retardant polyurethane foam.

The flame retardant performance and tensile strength of the semi-rigid polyurethane were improved by adding modified EG. The effects of modified EG on the flame retardant performance and tensile strength of semi-rigid polyurethane were discussed in detail.

Phenolic epoxy vinyl ester resin (PEVER) is an advanced resin matrix, which has excellent heat resistance, electrical insulation. However, the brittleness and poor toughness of its curing product limited its application, so this paper aims to modify the PEVER with hyperbranched polyimide (HBPI), so as to enhance the toughness, heat resistance and dielectric properties of PEVER.

Hexamethylene diisocyanate trimer was used as the central reactant. Methyl tetrahydrophthalic anhydride was used as the branching unit, stannous octoate was used as the catalyst and hydroquinone was prepared as the inhibitor. Then, the hyperbranched structure of HBPI was characterized by Fourier transform infrared spectrometer and ¹³C-NMR. Next, PEVER was mixed with different contents of HBPI, and then the authors tested its curing product.

It is found that with the addition of HBPI, the free volume of the system was increased and the content of polar groups was decreased in each unit space, so the dielectric constant (ε) and the dielectric loss (tanδ) were decreased. In addition, PEVER could be well toughened by HBPI and the thermal stability of PEVER was improved.

HBPI has excellent heat resistance. The addition of hyperbranched polymer increases the free volume of the system so it can slow down the transfer of stress and its nearly circular structure can absorb the impact energy from all directions. Moreover, an appropriate amount of free volume can decrease the dielectric constant of PEVER by reducing the content of polar groups.

Epoxy resin (EP) is a kind of thermosetting resin, and its application is usually limited by poor toughness. In this case, a type of new flexible chain blocking hyperbranched polyester (HBP) was designed and synthesized. The purpose of this study is to enhance the toughness and dielectric properties of EP.

P-toluene sulfonic acid was used as the catalyst, with dimethy propionic acid as the branch unit and pentaerythritol as the core in the experiment. Then, n-hexanoic acid and n-caprylic acid were, respectively, put to gain HBP with a n-hexanoic acid and n-caprylic acid capped structure. The microstructure, mechanical properties, insulation properties and dielectric properties of the composite were characterized for the purpose of finding the appropriate proportion of HBP.

HBP enhanced the toughness of epoxy-cured products by interpenetrating polymer network structure between the flexible chain of HBP and the EP molecular chain. Meanwhile, HBP reduced the ε and tgδ of the epoxy anhydride-cured product by reducing the number of polar groups per unit volume of the EP through free volumes.

Yet EP is a kind of thermosetting resin, which is widely used in coating, aerospace, electronics, polymer composites and military fields, but it is usually limited by poor toughness. In a word, it is an urgent priority to develop new EP with better toughness and mechanical properties.

At present, HBP has been applied as a new kind of toughening strategy and as a modifier for EP. According to the toughening mechanism of HBP modified EP, the free volume of HBP creates a space for the EP molecule to move around when loaded. Moreover, the free volume could cause the dielectric constant of EP to diminish by reducing the content of polarizable groups. Meanwhile, the addition of HBP with flexible chains grafted to the EP could develop an interpenetrating network structure, thus further enhancing the toughness of EP

Five halogen-free amphiphilic Brønsted acidic ionic liquids (ILs) based on 3-(N, N-dimethylalkylammonium)-propanesulphonate quaternary ammonium zwitterions and p-toluene sulphonic acid monohydrate were synthesized. The IL structures were characterized using ¹H NMR, ¹³C NMR and (ESI)-MS. The IL thermal instability was characterized using TG-DSC. The ILs were used as dual-solvent catalysts for esterification of several carboxylic acids, with different alcohols under mild conditions to study relevant structure-activity relationships. Results showed that the miscibility of the acidic IL, which is affected by the length of the carbon chain in the cation, is an important factor influencing the activity of the catalyst for the esterification reaction. Post-processing steps were simple, and the catalyst could be reused easily.

The purpose of this paper is to mainly center on the touchless interaction between humans and robots in the real world. The accuracy of hand pose identification and stable operation in a non-stationary environment is the main challenge, especially in multiple sensors conditions. To guarantee the human-machine interaction system’s performance with a high recognition rate and lower computational time, an adaptive sensor fusion labeling framework should be considered in surgery robot teleoperation.

In this paper, a hand pose estimation model is proposed consisting of automatic labeling and classified based on a deep convolutional neural networks (DCNN) structure. Subsequently, an adaptive sensor fusion methodology is proposed for hand pose estimation with two leap motions. The sensor fusion system is implemented to process depth data and electromyography signals capturing from Myo Armband and leap motion, respectively. The developed adaptive methodology can perform stable and continuous hand position estimation even when a single sensor is unable to detect a hand.

The proposed adaptive sensor fusion method is verified with various experiments in six degrees of freedom in space. The results showed that the clustering model acquires the highest clustering accuracy (96.31%) than other methods, which can be regarded as real gestures. Moreover, the DCNN classifier gets the highest performance (88.47% accuracy and lowest computational time) than other methods.

This study can provide theoretical and engineering guidance for hand pose recognition in surgery robot teleoperation and design a new deep learning model for accuracy enhancement.

The purpose of this paper is to research the induced flashover laws of different insulation materials under electrostatic electromagnetic pulse, and the induced flashover characteristics of different electrode structures are further explored.

According to standard IEC 61000–4-2, an experimental system of electrostatic electromagnetic pulse flashover for insulation materials is established. The induction flashover laws of polytetrafluoroethylene, epoxy resin and polymethyl methacrylate surface-mounted finger electrodes under the different intensity of electrostatic electromagnetic pulse are researched. The influence of the finger electrode, needle–needle electrode and needle–plate electrode on insulation flashover was compared. Secondary electron emission avalanche (SEEA) and field superposition theory are used to analyze the experimental results of electrostatic electromagnetic pulse induced flashover.

The larger the dielectric strength of insulation materials, the more difficult flashover occurs on the surface. The field superposition enhances collision ionization between electrons and gas molecules, which leads to the insulation materials surface induced flashover easily by electrostatic electromagnetic pulse. The sharper the electrode shapes on the insulation materials surface, the stronger the electric field intensity at the cathode triple junction, more initial electrons are excited to form the discharge channel, which easily leads to flashover on the surface of the insulating material.

The proposed field superposition combined with the SEEA method provides a new study perspective and enables a more rational, comprehensive analysis of electrostatic electromagnetic pulse induced flashover of insulation materials. The work of this paper can provide a reference for the safety protection of spacecraft in orbit under a strong electromagnetic field environment, increase the service life of spacecraft and improve the reliability of spacecraft’s safe operation in orbit. It provides a basis for the selection of insulation materials for equipment under the different intensities of the external electromagnetic environment.

The purpose of this study is to develop a friction-type energy-harvesting device based on magnetic liquids (MLs). This MLs energy-harvesting device combines MLs with a triboelectric nanogenerator (TENG), reducing the friction thermal effect to improve the conversion efficiency and working frequency band.

First, the motion equation of the MLs is calculated using the Bernoulli and fluid continuity equations. Second, the sloshing process of an ML in a container is simulated using the finite element simulation method, and the magnetic field distribution of the permanent magnet in the MLs is calculated. Then, the output characteristic of the ML-TENG is deduced theoretically, and the influencing factors of the output voltage are analyzed. Finally, the output voltage of the MLs energy-harvesting device was tested experimentally, and the influence of the magnetic field on the output voltage was tested.

This study proposes a vibration energy harvesting device based on MLs. The output voltage of the device was obtained through simulation and experimental tests, and the effect of the magnetic field on the output voltage was obtained.

This study provides a method to convert vibration energy into electrical energy using the magnetic response and fluid characteristics of MLs, and the availability of the device is verified by simulation and experiment. This energy-harvesting device exhibits less loss and a more sensitive response.