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This study aims to fabricate the acrylic-based polymeric composite coating with a hydrophobic surface associated with natural oil polyol (NOP) and polydimethylsiloxane with the incorporation of 3 Wt.% SiO₂ nanoparticle (SiO₂np) against the corrosive NaCl media.

The structural properties of the formulated polymeric composite coatings were investigated by using Fourier transform infrared spectroscopy, ultraviolet-visible spectroscopy, water contact angle (WCA) and cross-hatch (X-Hatch) tests. The WCA measurement was used to study the surface wettability of the formulated polymeric composite coatings. The corrosion protection performance of the nanocomposite coated on the mild steel substrate was studied by immersing the samples in 3.5 Wt.% NaCl solution for 30 days using electrochemical impedance spectroscopy.

The enhanced polymeric composite coating system performed with an excellent increase in the WCA up to 111.1° which is good hydrophobic nature and very high coating resistance in the range of 10¹⁰ Ω attributed to the superiority of SiO₂np.

The incorporation of SiO₂np into the polymeric coating could enhance the surface roughness and hydrophobic properties that could increase corrosion protection. This approach is a novel attempt of using NOP along with the addition of SiO₂np.

Polyurethane (PUR) foam parts are traditionally manufactured using metallic molds, an unsuitable approach for prototyping purposes. Thus, rapid tooling of disposable molds using fused filament fabrication (FFF) with polylactic acid (PLA) and glycol-modified polyethylene terephthalate (PETG) is proposed as an economical, simpler and faster solution compared to traditional metallic molds or three-dimensional (3D) printing with other difficult-to-print thermoplastics, which are prone to shrinkage and delamination (acrylonitrile butadiene styrene, polypropilene-PP) or high-cost due to both material and printing equipment expenses (PEEK, polyamides or polycarbonate-PC). The purpose of this study has been to evaluate the ease of release of PUR foam on these materials in combination with release agents to facilitate the mulding/demoulding process.

PETG, PLA and hardenable polylactic acid (PLA 3D870) have been evaluated as mold materials in combination with aqueous and solvent-based release agents within a full design of experiments by three consecutive molding/demolding cycles.

PLA 3D870 has shown the best demoldability. A mold expressly designed to manufacture a foam cushion has been printed and the prototyping has been successfully achieved. The demolding of the part has been easier using a solvent-based release agent, meanwhile the quality has been better when using a water-based one.

The combination of PLA 3D870 and FFF, along with solvent-free water-based release agents, presents a compelling low-cost and eco-friendly alternative to traditional metallic molds and other 3D printing thermoplastics. This innovative approach serves as a viable option for rapid tooling in PUR foam molding.

For the sake of sustainable development and environmental preservation, it is crucial to develop UV-curable coatings composed of renewable resources. Castor oil, being both bio-based and economical, serves as the focal point of this research paper. The purpose of this research paper is to synthesize, formulate and apply a UV-curable biobased oligomer ECOSAGMA as a wood coating, with a focus on sustainable development and environmental preservation. Castor oil, being both bio-based and economical, serves as the focal point of this research paper.

ECOSAGMA was prepared by reacting epoxidized castor oil with sebacic acid, followed by reaction with glycidyl methacrylate through ring opening reaction. The chemical structure of ECOSAGMA was confirmed by Fourier-Transform infrared spectroscopy, 13C-NMR and 1H-NMR spectroscopy. The synthesized oligomer was used for UV-curable coating formulations by combining it with varying amounts of TMPTA from 10 to 40 wt.% and studied for their rheological properties. The UV curable formulations were co-photopolymerized into thin coatings and were thoroughly examined based on thermal, chemical and mechanical properties.

The UV-cured coating containing ECOSAGMA and TMPTA exhibits exceptional mechanical, chemical and thermal properties, underscoring their potential for deployment in real-world application. It is observed that an increase in the concentration of TMPTA is associated with a notable enhancement in the properties of the UV-cured coatings. The UV-cured wood coating, composed of 40 wt.% TMPTA, demonstrates remarkable stain resistance properties.

In conclusion, by embracing eco-friendly and economically conscious principles., it is evident that this synthesized novel castor oil-based oligomer offers a range of valuable properties to the coating such as stain resistance and thermal stability as well as characteristics such as gloss, hardness, adhesion and chemical resistance.

This study aims to prepare thymol-based deep eutectic solvents (DESs) and use them as lubricates for friction and wear tests to simulate the wear conditions of hybrid bearings.

Through the characterization and analysis of the morphology of wear scars and the elemental composition of friction films, the tribological behavior and wear mechanism of sample materials as lubricants were investigated and the anti-wear mechanism of thymol-based DESs was discussed.

The findings demonstrate that because of the formation of a fluid lubrication film and excellent kinematic viscosity, the lubrication effect of the prepared DES is improved by about 50% compared to the base lubricating oil. The prepared [Ch]Cl-thymol DES has a better anti-friction and lubrication effect than citric-thymol, EG-thymol and urea-thymol DESs, with an average friction coefficient of about 0.04.

In this work, the friction reduction properties of thymol-based DESs were studied as lubricants for the first time, and the lubrication mechanism of sample materials was investigated.

Effects of corrosion are very dire and mitigation of corrosion holds prime importance. Protective coatings play major role in preventing corrosion of metals and coating application is the most convenient, economical and quick solution. The purpose of the study is development of protective coatings to effectively mitigate corrosion of metal components.

A high-performance anticorrosion coating was prepared using multiple monomers and paste of functional and reinforcing fillers with extenders to protect metal components from corrosion in aggressive environmental conditions. The structures of copolymers synthesized with multiple monomers were studied by the NMR and FT-IR spectroscopic techniques. The percentage conversion of different proportions of various monomers was estimated using gas chromatography technique. The functional paste to impart superior anticorrosion properties was prepared using various functional and reinforcing fillers. The final coatings were prepared by mixing these resins with functional paste in various proportions.

The prepared anticorrosion coating was tested for high-performance mechanical and chemical properties and it was witnessed that the said coating offered desired performance properties needed for protecting metal components from corrosion.

As such it is overcoming drawbacks of two pack systems and thus has almost no limitations or implications for application on metal substrate.

Being formulated as a single pack, it is free from drawbacks otherwise involved in two pack system of conventional paints. The coating system developed is very easy to apply using conventional tools, namely, brush, spray and roller techniques. The formulation is made in such a way that it has fast-drying properties. Makes painting or coating operations cost effective and confirm the performance.

The findings of the research have anticorrosion nature that can enhance the life span of the substrates. It is specially designed for metal substrate and can protect metal substrate from corrosion in most aggressive conditions. Thus, it helps to reduce losses due corrosion and increase safety of metal structures and human being as well. As it is based on conventional material but with new formulation and technology, it has commercial possibilities to explore.

Unlike conventional protective coating systems, the said coating offered disruptive features like single pack systems and fast drying at ambient temperature along with high-performance properties. The coating formulation was observed to have a great importance in industry for effective corrosion mitigation and to reduce losses due to corrosion.

The investigation aims to improve Nd: YAG laser technology for precision cutting of carbon fiber reinforcing polymers (CFRPs), specifically those containing newly created resin (NDR) from the polyethylene and polyurea group, is the goal of the study. The focus is on showing how Nd: YAG lasers may be used to precisely cut CFRP with NDR materials, emphasizing how useful they are for creating intricate and long-lasting components.

The study employs a systematic approach that includes complicated factorial designs, Taguchi L27 orthogonal array trials, Gray relational analysis (GRA) and machine learning predictions. The effects of laser cutting factors on CFRP with NDR geometry are investigated experimentally, with the goal of optimizing the cutting process for greater quality and efficiency. The approach employs data-driven decision-making with GRA, which improves cut quality and manufacturing efficiency while producing high-quality CFRP composites. Integration of machine learning models into the optimization process significantly boosts the precision and cost-effectiveness of laser cutting operations for CFRP materials.

The work uses Taguchi L27 orthogonal array trials for systematically explore the effects of specified parameters on CFRP cutting. The cutting process is then optimized using GRA, which identifies influential elements and determines the ideal parameter combination. In this paper, initially machining parameters are established at level L3P3C3A2, and the optimal machining parameters are determined to be at levels L3P2C3A3 and L3P2C1A2, based on predictions and experimental results. Furthermore, the study uses machine learning prediction models to continuously update and optimize kerf parameters, resulting in high-quality cuts at a lower cost. Overall, the study presents a holistic method to optimize CFRP cutting processes employing sophisticated techniques such as GRA and machine learning, resulting in better quality and efficiency in manufacturing operations.

The novel concept is in precisely measuring the kerf width and deviation in CFRP samples of NDR using sophisticated imaging techniques like SEM, which improves analysis and precision. The newly produced resin from the polyethylene and polyurea group with carbon fiber offers a more precise and comprehensive understanding of the material's behavior under different cutting settings, which makes it novel for kerf width and kerf deviation in their studies. To optimize laser cutting settings in real time while considering laser machining conditions, the study incorporates material insights into machine learning models.

The objective was to investigate the utility of cottonseed oil (CSO) as a raw material for the synthesis of CSO water-based alkyd resin. The synthesis involved the polymerization of CSO, trimethylolpropane, phthalic anhydride (PA) and trimellitic anhydride (TMA). The prepared resin coating material was subsequently applied to the surface of steel structure material.

This study aimed to synthesize water-based alkyd resins using CSO. Therefore, the alkyd resin was introduced with TMA containing carboxyl groups and neutralized with triethylamine (TEA) to form a water-soluble salt. Then, the esterification kinetics of CSO water-based alkyd resin were investigated, and finally, the basic properties of CSO water-based alkyd resin coating were evaluated.

It was demonstrated that CSO water-based alkyd resin exhibited excellent water solubility and that the esterification kinetic of the synthesis reaction could be described by a second-order reaction. The coating properties of the material were investigated and found to have good basic properties, with 40% resin addition having the best corrosion resistance. Consequently, it could be effectively applied to the surface of steel structural materials.

This study not only met the requirement of environmentally friendly development but also expanded the application of CSO through the synthesis of CSO water-based alkyd resin via alcoholysis. Compared to fatty acid process, the alcoholysis reduced the need for fatty acid pre-extraction, simplifying the alkyd resin synthesis process. Thus, economic costs are effectively reduced.

After reading and analyzing the case study, the students will be able to recognize the role of the mega environment in shaping business strategy, explore the challenges and opportunities in a mature industry (Foam), understand the business context of a family-owned firm and assess the implications and recommend managerial strategies.

In July 2019, Unifoam, a leading foam manufacturer, found itself at a crossroads as the company leadership grappled with diverging vision and future course of action. The newly appointed chief executive, Mr Faraz Khalid Shaikh, had overseen significant investments in expanding production capacity, and the time had come to reap the rewards. However, a series of unexpected events had unfolded, presenting the company with a unique set of challenges. Unifoam relied heavily on imported raw materials from China. Unifoam had high hopes of capitalizing on the opportunities presented by the China Pakistan Economic Corridor. However, the newly formed government had made significant policy changes regarding currency valuation and borrowing rates. This had increased the company’s working capital cost by 40%. This unexpected development had divided the board on the future direction and had forced the leadership to confront a crucial question: Should they hit the brakes or accelerate their growth strategies? This case study explored into the dynamic interplay between external factors, internal divisions and the family-owned nature of Unifoam. The analysis recognized the influence of the mega environment on the company’s strategy, exploring the challenges and opportunities within the mature foam industry and assessing the implications of conflicting approaches. This case study also offered valuable insights and managerial recommendations to guide the company’s path forward. Through embracing discomfort and confronting strategic dilemmas head-on, Unifoam sought to navigate uncharted waters and emerge as a resilient player in the evolving foam industry.

This is suitable for BBA or at the very start of MBA in the strategy courses, mainly business strategy and strategic management, and the case study can be positioned during the initial weeks in the course to provide a quick review of the basic analysis frameworks used in strategic decision-making.

Teaching notes are available for educators only.

CSS 11: Strategy.

The purpose of this study is to create sustainable additives for future vehicles, characterized by low levels of sulfated ash, sulfur and phosphorus (SAPS) or even SAPS-free alternatives. These newly developed additives must not only match or outperform the current commercial benchmarks in terms of tribological performance, but also align with the emerging sustainability trends. It is anticipated that this innovative technology will yield promising outcomes in the realm of hybrid and electric vehicles.

This research primarily focused on chemical synthesis, performance evaluation and characterizations. These aspects were studied through collaboration between Syensqo, Southwest Research Institute (the USA) and the Lab of the Future in France. The data was generated and analyzed by a team of research scientists, internship students and technical specialists.

Two types of additives have been specifically designed and synthesized in accordance with sustainable requirements. Both technologies have exhibited exceptional frictional and wear-resistant properties. Moreover, the leading candidates exhibit a lower rate of copper corrosion, stable electric conductivity and outstanding thermal stability when compared to commercial benchmarks. This study is expected to open a new research avenue for developing next-generation additives for lubricants, with wide potential applications including hybrid electric vehicle and electric vehicle markets.

In the current lubricant market, there is a lack of effective low-SAPS or SAPS-free additives. This research aims to address this gap by designing sustainable additives for next-generation vehicles that not only meet specific requirements but also maintain optimal lubrication performance.

The peer review history for this article is available at: https://publons.com/publon/10.1108/ILT-01-2024-0033/

Globally, consumer’s inclination towards functional foods had noticed due to their greater health consciousness coupled with enhanced health-care cost. The fact that probiotics could promote a healthier gut microbiome led projection of probiotic foods as functional foods and had emerged as an important dietary strategy for improved human health. It had established that ice cream was a better carrier for probiotics than fermented milked due to greater stability of probiotics in ice cream matrix. Global demand for ice cream boomed and probiotic ice cream could have been one of the most demanded functional foods. The purpose of this paper was to review the technological aspects and factors affecting probiotic viability and to standardize methodology to produce functional probiotic ice cream.

Attempt was made to search the literature (review and researched papers) to identify diverse factors affecting the probiotic viability and major technological challenge faced during formulation of probiotic ice cream. Keywords used for data searched included dairy-based functional foods, ice cream variants, probiotic ice cream, factors affecting probiotic viability and health benefits of probiotic ice cream.

Retention of probiotic viability at a level of >10⁶ cfu/ml is a prerequisite for functional probiotic ice creams. Functional probiotic ice cream could have been produced with the modification of basic mix and modulating technological parameters during processing and freezing. Functionality can be further enhanced with the inclusion of certain nutraceutical components such as prebiotics, antioxidant, phenolic compounds and dietary fibres. Based upon reviewed literature, suggested method for the manufacture of functional probiotic ice cream involved freezing of a probiotic ice cream mix obtained by blending 10% probiotic fermented milk with 90% non-fermented plain ice cream mix for higher probiotic viability. Probiotic ice cream with functional features, comparable with traditional ice cream in terms of technological and sensory properties could be produced and can crop up as a novel functional food.

Probiotic ice cream with functional features may attract food manufacturers to cater health-conscious consumers.