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Article
Publication date: 8 August 2016

Bharathiraja Balasubramanian, Praveen Kumar Ramanujam, Ranjith Ravi Kumar, Chakravarthy Muninathan and Yogendran Dhinakaran

The purpose of this paper is to speak about the production of biodiesel from waste cooking oil which serves as an alternate fuel in the absence of conventional fuels such as…

Abstract

Purpose

The purpose of this paper is to speak about the production of biodiesel from waste cooking oil which serves as an alternate fuel in the absence of conventional fuels such as diesel and petrol. Though much research work was carried out using non-edible crops such as Jatropha and Pongamia, cooking oil utilized in bulk quantity is discarded as a waste. This is reused again as it contains more of esters that when combined with an alcohol in presence of an enzyme as a catalyst yields triglycerides (biodiesel).

Design/methodology/approach

The lipase producing strain Rhizopus oryzae and pure enzyme lipase is immobilized and treated with waste cooking oil for the production of FAME. Reaction parameters such as temperature, time, oil to acyl acceptor ratio and enzyme concentration were considered for purified lipase and in the case of Rhizopus oryzae, pH, olive oil concentration and rpm were considered for optimization studies. The response generated through each run were evaluated and analyzed through the central composited design of response surface methodology and thus the optimized reaction conditions were determined.

Findings

A high conversion (94.01 percent) was obtained for methanol when compared to methyl acetate (91.11 percent) and ethyl acetate (90.06 percent) through lipase catalyzed reaction at oil to solvent ratio of 1:3, enzyme concentration of 10 percent at 30°C after 24 h. Similarly, for methanol a high conversion (83.76 percent) was obtained at an optimum pH of 5.5, olive oil concentration 25 g/L and 150 rpm using Rhizopus oryzae when compared to methyl acetate (81.09 percent) and ethyl acetate (80.49 percent).

Originality/value

This research work implies that the acyl acceptors methyl acetate and ethyl acetate which are novel solvents for biodiesel production can also be used to obtain high yields as compared with methanol under optimized conditions.

Details

Management of Environmental Quality: An International Journal, vol. 27 no. 5
Type: Research Article
ISSN: 1477-7835

Keywords

Article
Publication date: 1 March 1972

Industrial cellulose nitrate, sometimes called pyroxylin, collodion cotton or nitrocotton, is made by treating cellulose in the form of cotton (inters (threads) or woodpulp with a…

Abstract

Industrial cellulose nitrate, sometimes called pyroxylin, collodion cotton or nitrocotton, is made by treating cellulose in the form of cotton (inters (threads) or woodpulp with a large excess of mixed nitric and sulphuric acid controlled to fine limits as regards strength of acid and the time and temperature of the nitration. Following a water washing process, the nitrocellulose is partially dried and the remaining water displaced by the selected damping medium — industrial methylated spirit, isopropanol or butanol. For certain purposes the nitrocellulose is damped with water.

Details

Pigment & Resin Technology, vol. 1 no. 3
Type: Research Article
ISSN: 0369-9420

Article
Publication date: 1 July 1974

A new cellulose acetate butyrate ester‐designated EAB‐555–0.2‐that can be dispersed in water, has been developed by the Coating Chemical Technical Service Laboratory of Eastman…

Abstract

A new cellulose acetate butyrate ester‐designated EAB‐555–0.2‐that can be dispersed in water, has been developed by the Coating Chemical Technical Service Laboratory of Eastman Chemical Products, Inc., Kingsport, Tennessee, U.S.A.

Details

Pigment & Resin Technology, vol. 3 no. 7
Type: Research Article
ISSN: 0369-9420

Article
Publication date: 1 June 1963

For many years now food and drugs authorities (and the public) have been complaining about the low meat content of meat pies on sale and the need of a standard is self‐evident…

Abstract

For many years now food and drugs authorities (and the public) have been complaining about the low meat content of meat pies on sale and the need of a standard is self‐evident. The pie filling is not visible to the purchaser and often consists of a mixture of meat and cereal from the appearance of which it is impossible to assess the amount of meat present. The sale of made up cooked foods has increased among all such products in recent years, but for meat pies the increase has been phenomenal.

Details

British Food Journal, vol. 65 no. 6
Type: Research Article
ISSN: 0007-070X

Article
Publication date: 1 January 1972

P.G. Garrett

Although the technique of electron curing has been well developed, there are very few suitable coatings available.

Abstract

Although the technique of electron curing has been well developed, there are very few suitable coatings available.

Details

Pigment & Resin Technology, vol. 1 no. 1
Type: Research Article
ISSN: 0369-9420

Article
Publication date: 1 May 1974

Americus

Nineteen hundred and seventy‐three saw the introduction of a variety of new proprietary products resulting, for the most part, from technology which is well familiar to the paint…

Abstract

Nineteen hundred and seventy‐three saw the introduction of a variety of new proprietary products resulting, for the most part, from technology which is well familiar to the paint industry. The continued introduction of proprietary products is one measure of the health of the industry. There are, of course, many other yardsticks but on this basis it is safe to say that the industry is a vigorous one and is trying continually to achieve improvements which will make its products more useful and more functional.

Details

Pigment & Resin Technology, vol. 3 no. 5
Type: Research Article
ISSN: 0369-9420

Article
Publication date: 1 August 1972

Croda Polymers have extended their range of Crodalex textured surface coatings by the introduction of C.76, a stoving finish based on alkyd/MF resin. It is said to provide a…

Abstract

Croda Polymers have extended their range of Crodalex textured surface coatings by the introduction of C.76, a stoving finish based on alkyd/MF resin. It is said to provide a tough, attractive and highly decorative finish to a wide range of products, such as consumer durables, instrument and tool cases, office furniture, etc. A single coat application gives a uniform, consistent pattern.

Details

Pigment & Resin Technology, vol. 1 no. 8
Type: Research Article
ISSN: 0369-9420

Article
Publication date: 1 April 1968

We can think of those with a cynical turn of mind who might consider not a little of the present output of the parliamentary machine as “harem scarem” law, but the indecent haste…

Abstract

We can think of those with a cynical turn of mind who might consider not a little of the present output of the parliamentary machine as “harem scarem” law, but the indecent haste, the freak urgency of some politically inspired laws apart, it is only too obvious that law is being made under rush conditions, and the reasons are not far to seek. A hectic, over‐active party executive, feverishly pushing ahead with its policies produces impossible working conditions for the parliamentary draftsmen. Law, whether it is statute or regulation, has never been more complex than it is today; time allowed for parliamentary debate is completely inadequate; too many and varied interests have to be taken into account, to say nothing of the vast range of delegated legislation. The urgency of some legislation is doubtful; it is difficult to see the need for all the hurry; a little more time in proper debate would prevent some of the loopholes which subsequently appear and render the law more comprehensible; incomprehensibility and justice are rarely compatible. As Diplock L J., said in the Court of Appeal in Rex. v. Industrial Injuries Commissioner ex parte Cable (1968) 1 A.E.R., 9, a few months ago—“Judges have been at their wits' end to know what some of the provisions mean. It would be a good thing if time could be found to remedy the blemishes.”

Details

British Food Journal, vol. 70 no. 4
Type: Research Article
ISSN: 0007-070X

Open Access
Article
Publication date: 21 December 2022

Chaduvula Vijaya Lakshmi, Ch. Ravi Kiran, M. Gowrisankar, Shaik Babu and D. Ramachandran

The paper aims to throw light on the interactions taking place between the different chemical compositions at various temperatures. P-methylacetophenone is a polar dissolvable…

Abstract

Purpose

The paper aims to throw light on the interactions taking place between the different chemical compositions at various temperatures. P-methylacetophenone is a polar dissolvable, which is positively related by dipole–dipole co-operations and is exceptionally compelling a direct result of the shortfall of any critical primary impacts because of the absence of hydrogen bonds; hence, it might work an enormous dipole moment (μ = 3.62 D). Alcohols additionally assume a significant part in industries and research facilities as reagents and pull in incredible consideration as helpful solvents in the green innovation. They are utilized as pressure-driven liquids in drugs, beauty care products, aromas, paints removers, flavors, dye stuffs and as a germ-free specialist.

Design/methodology/approach

Mixtures were prepared by mass in airtight ground stopper bottles. The mass measurements were performed on a digital electronic balance (Mettler Toledo AB135, Switzerland) with an uncertainty of ±0.0001 g. The uncertainty in mole fraction was thus estimated to be less than ±0.0001. The densities of pure liquids and their mixtures were determined using a density meter (DDH-2911, Rudolph Research Analytical). The instrument was calibrated frequently using deionized doubly distilled water and dry air. The estimated uncertainty associated with density measurements is ±0.0003 g.cm−3. Viscosities of the pure liquids and their mixtures were determined by using Ostwald’s viscometer. The viscometer was calibrated at each required temperature using doubly distilled water. The viscometer was cleaned, dried and is filled with the sample liquid in a bulb having capacity of 10 ml. The viscometer was then kept in a transparent walled water bath with a thermal stability of ±0.01K for about 20 min to obtain thermal equilibrium. An electronic digital stop watch with an uncertainty of ±0.01 s was used for the flow time measurements for each sample at least four readings were taken and then the average of these was taken.

Findings

Negative values of excess molar volume, excess isentropic compressibility and positive values of deviation in viscosity including excess Gibbs energy of activation of viscous flow at different temperatures (303.15, 308.15 and 313.15 K) may be attribution to the specific intermolecular interactions through the hetero-association interaction between the components of the mixtures, resulting in the formation of associated complexes through hydrogen bond interactions.

Originality/value

The excess molar volume (VE) values were analyzed with the Prigogine–Flory–Patterson theory, which demonstrated that the free volume contribution is the one of the factors influencing negative values of excess molar quantities. The Jouyban–Acree model was used to correlate the experimental values of density, speed of sound and viscosity.

Details

Arab Gulf Journal of Scientific Research, vol. 41 no. 2
Type: Research Article
ISSN: 1985-9899

Keywords

Content available
Article
Publication date: 1 April 2002

317

Abstract

Details

Pigment & Resin Technology, vol. 31 no. 2
Type: Research Article
ISSN: 0369-9420

Keywords

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