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The main purpose of the present study is to introduce new Schiff bases as corrosion inhibitor for carbon steel in 1 M HCl. The inhibitory activity of Schiff base was also assessed.

2,2′-((1Z,1′Z)-((2,2-dimethylpropane-1,3-diyl)bis(azanylylidene))bis(methanylylidene))diphenol was synthesized and it’s performance as an inhibitor was then investigated in 1 M HCl. The inhibition of this compound was studied and evaluated by the chemical methods of electrochemical impedance spectroscopy, electrochemical potential dynamic polarization and Atomic Force microscopy (AFM) method. The thermodynamics parameters were investigated for corrosion of carbon steel in both the absence and presence of Schiff base.

The results of the tests showed that this compound has a good performance as an inhibitor and the percentage of inhibition on steel corrosion will increase with increasing concentration and it will reach 70% in the presence of 2 × 10⁻³ M of this inhibitor. Polarization tests indicated that this compound will act as a mixed inhibitor. Nyquist curves showed that the addition of this substance to the solution increased the charge transfer resistance and decreased the capacity of the double layer. The absorption of the new Schiff base on steel follows Langmuir adsorption isotherm, and the amount of free energy of adsorption indicates the spontaneous adsorption of this inhibitor. Using AFM investigations, the results of electrochemical methods were confirmed.

Incorporation of a new Schiff base into 1 M HCl is a promising approach for protecting the carbon steel against corrosive solution.

The purpose of this paper is to study the corrosion behavior of Q235 steel in saturated acidic red and yellow soils.

The corrosion behavior of Q235 steel in saturated red and yellow soils was compared by weight-loss, SEM/EDS, 3D ultra-depth microscopy and electrochemical measurements.

R_p of the steel gradually increases and i_corr gradually decreases in both the red and yellow soils with time. The R_p of the steel in the red soil is lower, but its i_corr is higher than that in the yellow soil. The uniform corrosion rate, diameter and density of the corrosion pit on the steel surface in the red soil are greater than those in the yellow soil. Lower pH, higher contents of corrosive anions and high-valence Fe oxides in the red soil are responsible for its higher corrosion rates and local corrosion susceptibility.

This paper investigates the difference in corrosion behavior of carbon steel in saturated acidic red and yellow soils, which can help to understand the mechanism of soil corrosion.

The aim of this paper is to study the effect of laser shock peening (LSP) on mechanical behaviour of the laser-directed energy deposition (LDED)-based printed 15-5 PH stainless steel with U and V notches. The study specifically concentrates on the evaluation of effect of scan strategy, machining and LSP processing on microstructural, texture evolution and fatigue behaviour of LDED-printed 15-5 PH steel.

For LSP treatment, 15-5 PH steel was printed using LDED process with bidirectional scanning strategy (XX [θ = 0°) and XY [θ = 90°]) at optimised laser power of 600 W with a scanning speed of 300 mm/min and a powder feed rate of 3 g/min. Furthermore, LSP treatment was conducted on the V- and U-notched fatigue specimens extracted from LDED-built samples at laser energy of 3.5 J with a pulse width of 10 ns using laser spot diameter of 3 mm. Post to the LSP treatment, the surface roughness, fatigue life assessment and microstructural evolution analysis is performed. For this, different advanced characterisation techniques are used, such as scanning electron microscopy attached with electron backscatter diffraction for microstructure and texture, X-ray diffraction for residual stress (RS) and structure information, Vicker’s hardness tester for microhardness and universal testing machine for low-cycle fatigue.

It is observed that both scanning strategies during the LDED printing of 15-5 PH steel and laser peening have played significant role in fatigue life. Specimens with the XY printing strategy shows higher fatigue life as compared to XX with both U- and V-notched conditions. Furthermore, machining and LSP treatment led to a significant improvement of fatigue life for both scanning strategies with U and V notches. The extent of increase in fatigue life for both XX and XY scanning strategy with V notch is found to be higher than U notch after LSP treatment, though without LSP samples with U notch have a higher fatigue life. As fabricated sample is found to have the lowest fatigue life as compared to machines and laser peened with both scan strategies.

This study presents an innovative method to improve the fatigue life of 15-5 PH stainless steel by changing the microstructure, texture and RS with the adoption of a suitable scanning strategy, machining and LSP treatment as post-processing. The combination of preferred microstructure and compressive RS in LDED-printed 15-5 PH stainless steel achieved with a synergy between microstructure and RS, which is responsible to improve the fatigue life. This can be adopted for the futuristic application of LDED-printed 15-5 PH stainless steel for different applications in aerospace and other industries.

The purpose of this study is to characterize the galvanic corrosion behavior of a simulated X80 pipeline steel welded joint (PSWJ) reconstructed by the wire beam electrode (WBE) and numerical simulation methods.

The galvanic corrosion of an X80 PSWJ was studied using WBE and numerical simulation methods. The microstructures of the coarse-grained heat affected zone, fine-grained heat affected zone and intercritical heat affected zone were simulated in X80 pipeline steel via Gleeble thermomechanical simulation processing.

Comparing the corrosion current density of coupled and isolated weld metal (WM), base metal (BM) and heat-affected zone (HAZ), the coupled WM exhibited a higher corrosion current density than isolated WM; the coupled BM and HAZ exhibited lower corrosion current densities than isolated BM and HAZ. The results exhibited that the maximum anodic galvanic current fitted the Gumbel distribution. Moreover, the numerical simulation results agreed well with the experimental data.

This study provides insight into corrosion evaluation of heterogeneous welded joints by a combination of experiment and simulation. The method of reconstruction of the welded joint has been proven to be a feasible approach for studying the corrosion behavior of the X80 PSWJ with high spatial resolution.

Military and unmanned aerial vehicles (UAV) applications like rocket motor casings, missile covers and ship hulls use components that are made of maraging steel. Maraging steel has properties that are superior to other metals, making it more suitable for the fabrication of such components. A grey relational analysis (GRA) that is based on the Taguchi method has been utilised in the current study to optimise a laser beam welding (LBW) process. Further aspects such as GRA's optimum ranges and percentage contributions were also estimated.

A Taguchi L16 orthogonal array is utilised to design and conduct the experiments. Laser power (LP), welding speed (WS) and focal position (FP) are the three parameters are chosen for the process of welding. The output responses are the upper width of the heat-affected zone (HAZup), the upper width of the fusion zone (FZup) and the depth of penetration (DOP). The effect of the above key parameters on the responses was examined using an analysis of variance (ANOVA).

The results of ANOVA reveal that the parameter that has the most influence on the overall grey relational grade (GRG) is the FP. Finally, metallographic characterisation and a microstructural analysis are conducted on the weld bead geometry to demarcate the zone of HAZ and fusion zone (FZ).

As the most important criteria for LBW of maraging steels is the provision of higher DOP, higher FZ width and lower heat-affected zone, the study intended to prove the applicability of GRA technique in solving multi-objective optimisation problems in applications like defence and unmanned systems.

Although separate studies on the influence of corrosion and fire exposure on the constitutive relationship of concrete and steel have been done, there is still a gap in knowledge on the influence of corrosion-temperature superimposition as nonlinear phenomenon. The current study is focused to investigate the response of hot-rolled steel bars subjected to corrosion-temperature superimposition.

Using the accelerated corrosion-impressed-current technique, hot-rolled specimens with different levels of corrosion were obtained. The hot-rolled rebars were first corroded to target levels such as (6, 12, 18, 24, 30 and 36%) and subsequently subjected to target temperatures (250 °C, 400 °C, 550 °C, 800 °C and 950 °C), before tensile tests were carried out to evaluate the residual mechanical response.

The outcomes showed a significant decline in the parameters governing the mechanical properties of steel reinforcement due to the combined damage due to corrosion and fire. Corroded reinforcement still showed ductile failure after exposure to fire. Moreover, the combined loss of load-bearing characteristics due to corrosion and fire has little influence on the modulus of elasticity. The outcomes of this investigation provide a theoretical database for the assessment of aged structural elements exposed to combination after exposure to fire.

The information concerning structural material's response to corrosion-temperature combined damage is still limited. The cover of the reinforcement is designed to safeguard the reinforcing bars from foreign agencies but is often damaged and spalled off due to corrosion, rendering the reinforcing bars directly exposed. The study aims at the experimental production of fire conditions in a corrosion-damaged infrastructure to cover the aforementioned research gap. The effects of corrosion being superimposed by exposure to elevated temperatures on key parameters affecting mechanical behavior were examined.

1. Influence of corrosion-temperature superimposition on the mechanical properties of hot-rolled rebars.

2. Influence of corrosion-temperature superimposition on the macro and microstructure properties of hot-rolled rebars.

3. Influence of corrosion-temperature superimposition on stress-strain curves of hot-rolled rebars.

4. Influence of corrosion-temperature superimposition on tensile strength, modulus of elasticity and elongation of hot-rolled rebars.

Influence of corrosion-temperature superimposition on the mechanical properties of hot-rolled rebars.

Influence of corrosion-temperature superimposition on the macro and microstructure properties of hot-rolled rebars.

Influence of corrosion-temperature superimposition on stress-strain curves of hot-rolled rebars.

Influence of corrosion-temperature superimposition on tensile strength, modulus of elasticity and elongation of hot-rolled rebars.

This study aims to investigate the effects of process input parameters (welding current, welding time, electrode pressure and holding time) on the output responses (nugget diameter, peak load and indentation) that control the mechanical properties and quality of the joints in dissimilar resistance spot welding (RSW) for the third generation of advanced high-strength steel (AHSS) quenching and partitioning (Q&P980) and (SPFC780Y) high-strength steel spot welds.

Design of experiment approach with two level factors and center points was adopted. Destructive peel and shear tensile strengths were used to measure the responses. The significant factors were determined using analysis of variance implemented by Minitab 18 software. Finally, multiresponse optimization was carried out using the desirability function analysis method.

Holding time was the most significant factor influencing nugget diameter, whereas welding current had the greatest impact on peak load and indentation. Multiresponse optimization revealed that the optimal settings were a welding current of 12.5 KA, welding time of 18 cycles, electrode pressure of 420 Kgf and holding time of 10 cycles. These settings produced a nugget diameter of 8.0 mm, a peak load of 35.15 KN and an indentation of 22.5%, with a composite desirability function of 0.764.

This study provides an effective approach for multiple response optimization to the mechanical behavior of RSW joints, even though there have been few studies on the third generation of AHSS joints and none on the dissimilar joints of the materials used in this study.

Corrosion is a major concern for many industries that use metals as structural or functional materials, and the use of corrosion inhibitors is a widely accepted strategy to protect metals from deterioration in corrosive environments. Moreover, the toxic nature, non-biodegradability and price of most conventional corrosion inhibitors have encouraged the application of greener and more sustainable options, with natural and synthetic drugs being major actors. Hence, this paper aims to stress the capability of natural and synthetic drugs as manageable and sustainable, environmentally friendly solutions to the problem of metal corrosion.

In this review, the recent developments in the use of natural and synthetic drugs as corrosion inhibitors are explored in detail to highlight the key advancements and drawbacks towards the advantageous utilization of drugs as corrosion inhibitors.

Corrosion is a critical issue in numerous modern applications, and conventional strategies of corrosion inhibition include the use of toxic and environmentally harmful chemicals. As greener alternatives, natural compounds like plant extracts, essential oils and biopolymers, as well as synthetic drugs, are highlighted in this review. In addition, the advantages and disadvantages of these compounds, as well as their effectiveness in preventing corrosion, are discussed in the review.

This survey stresses on the most recent abilities of natural and synthetic drugs as viable and sustainable, environmentally friendly solutions to the problem of metal corrosion, thus expanding the general knowledge of green corrosion inhibitors.

This paper aims to examine dissimilar joints for various applications in chemical, petrochemical, oil, gas, shipbuilding, defense, rail and nuclear industry.

This study examined the effects of cold metal transfer welding on stainless steel welds for 316L austenitic and 430 ferritic dissimilar welds with ER316L, ER309L and without (autogenous) fillers. The microstructural observation was done with an optical microscope. The mechanical test was done to reveal the strength, hardness and toughness of the joint. The electrochemical polarization tests were done to reveal intergranular and pitting corrosion in the dissimilar joints.

This microstructural study shows the presence of austenitic and ferritic phases with vermicular ferrite for ER309L filler weld, and for ER316L filler weld specimen shows predominately martensitic phase in the weld region, whereas the autogenous weld shows lathy ferrite mixed with martensitic phase. Mechanical test results indicated that filler welded specimen (ER316L and ER309L) has relatively higher strength and hardness than the autogenous weld, whereas ER316L filler weld exhibited the highest impact toughness than ER309L filler weld and lowest in autogenous weld. The electrochemical corrosion results displayed the highest degree of sensitization (DOS) in without filler welded specimen (45.62%) and lower in case of filler welded specimen ER309L (4.95%) and least in case of ER316L filler welded specimen (3.51%). The high DOS in non-filler welded specimen is correlated with the chromium carbide formation. The non-filler welded specimen shows the highest pitting corrosion attack as compared to the ER316L filler weld specimen and relatively better in ER309L filler welded specimen. The highest pitting corrosion resistance is related with the high chromium content in ER309L composition.

This experimental study is original and conducted with 316L and 430 stainless steel with ER316L, ER309 and without fillers, which will help the oil, shipbuilding and chemical industries.

The purpose of this study is to optimize and improve conventional welding using EMF assisted technology. Current industrial production has put forward higher requirements for welding technology, so the optimization and improvement of traditional welding methods become urgent needs.

External magnetic field assisted welding is an emerging technology in recent years, acting in a non-contact manner on the welding. The action of electromagnetic forces on the arc plasma leads to significant changes in the arc behavior, which affects the droplet transfer and molten pool formation and ultimately improve the weld seam formation and joint quality.

In this paper, different types of external magnetic fields are analyzed and summarized, which mainly include external transverse magnetic field, external longitudinal magnetic field and external cusp magnetic field. The research progress of welding behavior under the effect of external magnetic field is described, including the effect of external magnetic field on arc morphology, droplet transfer and weld seam formation law.

However, due to the extremely complex physical processes under the action of the external magnetic field, the mechanism of physical fields such as heat, force and electromagnetism in the welding has not been thoroughly analyzed, in-depth theoretical and numerical studies become urgent.