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Article
Publication date: 7 December 2020

Kesavan Devarayan, Kopperundevi Sivakami Nagaraju and Padmavathi Pandiyan

The present study aims to describe the development of halochromic thin film sensors using mixed indicator dyes for monitoring the spoilage of packed seer fish.

Abstract

Purpose

The present study aims to describe the development of halochromic thin film sensors using mixed indicator dyes for monitoring the spoilage of packed seer fish.

Design/methodology/approach

Thin film was prepared using renewable polysaccharide incorporated with mixed indicator dyes. The thin film was characterized using ultraviolet visible and Fourier transform-infrared spectroscopy. The characteristics of the thin film were studied by analyzing the CIELAB and Red Green Blue values and biodegradability. The thin films were evaluated for real-time monitoring of the spoilage of packed seer fish.

Findings

The thin film sensors were found to exhibit excellent halochromism. The color changes were visible and distinguishable. The sensors responded efficiently for real-time monitoring of spoilage of fish by showing unique color changes.

Originality/value

This study provides promising mixed indicator that exhibits different colors in the alkaline pH. Also the present study reveals a potential combination of materials for preparation of halochromic sensors that can be used for monitoring the spoilage of packed seer fish in real time.

Details

Pigment & Resin Technology, vol. 50 no. 6
Type: Research Article
ISSN: 0369-9420

Keywords

Abstract

Purpose

This study aims to describe on-site determination of pH in aquaculture using a portable colorimeter.

Design/methodology/approach

A basic and inexpensive portable colorimeter having light sources of different wavelength has been optimized for the determination of pH. A chromic reagent is optimized to develop colors depending on different pHs. Then, the color is measured using portable colorimeter in terms of resistance. Using the resistance to absorbance relationship, the resistance values are converted to absorbance. The performance of the developed colorimetric system is compared with commercially available colorimeter and pH meter. Eighty brackish water aquaculture samples were tested using the developed colorimetric system to check its adaptability in aquaculture farms.

Findings

A chromic reagent optimized in this study exhibited linear relationship with the pH changes of pH standards. Portable colorimeter having three different light sources is optimized using this chromic agent for determination of pH. Colorimeter possessing yellow light revealed more linear results than the others. The developed colorimetric system determines the pH of aquaculture water with an accuracy of ±0.14 in comparison with commercial colorimeter at the pH range of 6.0−9.0.

Originality/value

pH plays a pivotal role in aquaculture, impacting not only productivity but also profitability. The colorimetric system introduced in this research is promising for pH measurement in the field of brackish water aquaculture. The on-site pH assessment facilitated by this colorimetric system holds significant potential for adoption within the aquaculture sector, owing to its precision, portability, simplicity of use and user-friendly nature.

Details

Pigment & Resin Technology, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 18 May 2021

Kesavan Devarayan, Padmavathi P. and Kopperundevi Sivakami Nagaraju

Development of thin film sensors with pH function for noninvasive real-time monitoring of spoilage of packed seafood such as fish, crab and shrimp are described in this study. It…

49

Abstract

Purpose

Development of thin film sensors with pH function for noninvasive real-time monitoring of spoilage of packed seafood such as fish, crab and shrimp are described in this study. It is also the purpose of this study to enhance the leaching resistance of the sensors by using a suitable strategy and to quantitatively correlate the sensor’s halochromism with the total volatile amine.

Design/methodology/approach

To prepare halochromic sensors with better leaching resistance, biocompatible materials such as starch, agar, polyvinyl alcohol and cellulose acetate along with a halochromic dye were used to prepare the thin film sensors. These thin films were evaluated for monitoring the spoilage of packed seafood at room temperature, 4°C and −2°C up to 30 days. The halochromic sensors were characterized using UV-visible and FT-IR spectroscopy.

Findings

CIELab analyses of the halochromism of the thin film sensors revealed that the color changes exhibited by the sensors in response to the spoilage of seafood are visually distinguishable. Further, the halochromic response of the thin films was directly proportional to the amount of total volatile base nitrogen that evolved from the packed seafood. Excellent leaching resistance was observed for the developed thin film sensors. The halochromic property of the sensors is reversible and thus the sensors are recyclable. Besides, the thin film sensors exhibited significant biodegradability.

Originality/value

This study provides insights for use of different biocompatible polymers for obtaining enhanced leaching resistance in halochromic sensors. Further, the color changes exhibited by the sensors are in line with the total volatile amines evolved from the packed seafood. These results highlight the importance of the developed halochromic thin film sensors for real-time monitoring of the spoilage of packed seafood.

Details

Pigment & Resin Technology, vol. 51 no. 2
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 21 May 2024

Kesavan Devarayan, Yazhiniyan Palanisamy, Gangeswar Mohan, Anand Theivasigamani, Sabariswaran Kandasamy, Vimaladevi Sekar, Evon Umesh Siluvai John, Monikandon Sukumaran, Ramar Marimuthu and Hema Anjappan

This study aims to develop a pH-functional thin-film sensor for non-invasive measurement of spoilage of packed fish.

Abstract

Purpose

This study aims to develop a pH-functional thin-film sensor for non-invasive measurement of spoilage of packed fish.

Design/methodology/approach

At first, polymers of natural origin such as hydroxy(propyl)methyl cellulose, potato dextrose agar and starch alongside a pH sensitive-mixed indicator formulation were used to produce thin film sensor. The developed thin film sensor was tested for monitoring the spoilage of seafood stored at 4°C. Using ultraviolet-visible and Fourier-transform infrared spectroscopy, the halochromic sensor was characterised. In addition, the halochromic response of the thin film was directly correlated to the total volatile base nitrogen emitted by the packaged fish, pH, microbial activity and sensory evaluation.

Findings

The results suggested the developed biopolymer-based thin film sensor showed different colours in line with the spoilage of the packed fish, which could be well correlated with the total volatile base nitrogen, microbial activity and sensory evaluation. In addition, the thin film sensors exhibited a high degree of biodegradability. The biopolymers-based thin film halochromic sensor has exhibited excellent biodegradability along with sensitiveness towards the spoilage of the packed fish.

Originality/value

In the future, consumers and retailers may prefer seafood containers equipped with such halochromic sensors to determine the degree of food deterioration as a direct indicator of food quality.

Details

Pigment & Resin Technology, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 25 May 2022

Kesavan Devarayan, Madhan Kathavarayan, Anand Theivasigamani, Monikandon Sukumaran and Sabariswaran Kandasamy

This study aims to describe the development of a battery-operated portable colorimeter for on-site determination of water quality in aquaculture.

Abstract

Purpose

This study aims to describe the development of a battery-operated portable colorimeter for on-site determination of water quality in aquaculture.

Design/methodology/approach

A simple and economical colorimeter is built using light sources of different wavelength and a light-dependent resistor combined with an electrical circuit. The whole system was fabricated as to fit into the pocket or palm for easy handling. The developed portable colorimeter was calibrated for estimation of nitrite. Further, the performance of developed portable colorimeters was compared with the commercially available colorimeter.

Findings

Three colorimeters with different light sources were developed and calibrated for determination of nitrite in water. Among them, colorimeter with yellow light source exhibited higher potential for determination of nitrite in the range of 0.5–3.5 ppm. Further, the results of the developed colorimeter are comparable with the commercial colorimeter.

Originality/value

The portable colorimeter developed in this study exhibits potential for determination of nitrite in aquaculture. Determination of nitrite at low concentrations is important for assessing the quality of culture as well as wastewater in aquaculture industry. The accuracy, portable nature, economy and simple operation of these portable colorimeters offer opportunity for on-site determination of water quality parameters in aquaculture.

Details

Pigment & Resin Technology, vol. 52 no. 6
Type: Research Article
ISSN: 0369-9420

Keywords

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