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The purpose of this study is to provide a highly efficient method to obtain the kinetics of the hydrogen evolution reaction (HER) on metal electrodes in an alkaline solution and to analyze the effect of thiourea addition on HER under the same cathodic overpotential.

A novel method based on hydrogen permeation tests, potentiodynamic polarization tests and electrochemical impedance spectroscopy was put forward to characterize the HER kinetics on metal electrode.

The study found that adding thiourea accelerated the Volmer, Heyrovsky and Tafel reactions associated with HER. In addition, it reduced the hydrogen surface coverage and increased the hydrogen permeation steady-state current density. As a result, thiourea facilitated HER, promoted the diffusion of hydrogen atoms into iron and reduced the number of hydrogen atoms in the adsorbed state.

This work provides novel insights into the influence of thiourea on HER kinetics, demonstrating that thiourea addition can significantly enhance HER efficiency by altering reaction dynamics and promoting hydrogen atom diffusion into iron. This has implications for hydrogen energy applications, cathodic protection and understanding hydrogen embrittlement mechanisms.

The nickel-based alloys Inconel 625 and Inconel 718 stand out due to their high strength and corrosion resistance in important industries like aerospace, aviation and automotive. Even though they are widely used, current techniques of producing materials that are difficult to cut pose several problems from a financial, ecological and even health perspective. To handle these problems and acquire improved mechanical and structural qualities, laser powder bed fusion (LPBF) has been widely used as one of the most essential additive manufacturing techniques. The purpose of this article is to focus on the state of the art on LPBF parts of Inconel 625 and Inconel 718 for microstructure, mechanical behavior and postprocessing.

The mechanical behavior of LPBF-fabricated Inconel is described, including hardness, surface morphology and wear, as well as the influence of fabrication orientation on surface quality, biocompatibility and resultant mechanical properties, particularly tensile strength, fatigue performance and tribological behaviors.

The postprocessing techniques such as thermal treatments, polishing techniques for surface enhancement, mechanical and laser-induced peening and physical operations are summarized.

The highlighted topic presents the critical aspects of the advantages and challenges of the LPBF parts produced by Inconel 718 and 625, which can be a guideline for manufacturers and academia in practical applications.

The purpose of this study is the formation and growth of nanoscale intermetallic compounds (IMCs) when laser is used as a heat source to form solder joints.

This study investigates the Sn/Cu and Sn-0.1AlN/Cu structure using laser soldering under different laser power: (200, 225 and 250 W) and heating time: (2, 3 and 4 s).

The results show clearly that the formation of nano-Cu₆Sn₅ films is feasible in the laser heating (200 W and 2 s) with Sn/Cu and Sn-0.1AlN/Cu system. The nano-Cu₆Sn₅ films with thickness of 500 nm and grains with 700 nm are generally parallel to the Cu surface with Sn-0.1AlN. Both IMC films thickness of Sn/Cu and Sn-0.1AlN/Cu solder joints gradually increased from 524.2 to 2025.8 nm as the laser heating time and the laser power extended. Nevertheless, doping AlN nanoparticles can slow down the growth rate of Cu₆Sn₅ films in Sn solder joints due to its adsorption.

The formation of nano-Cu₆Sn₅ films using laser heating can provide a new method for nanofilm development to realize the metallurgical interconnection in electronic packaging.

The purpose of this study is to investigate the influence of varying concentrations of nano-SiO₂ particle doping on the structure and properties of the micro-arc oxidation (MAO) coating of 7075 aluminum alloy. This research aims to provide novel insights and methodologies for the surface treatment and protection of 7075 aluminum alloy.

The surface morphology of the MAO coating was characterized using scanning electron microscope. Energy spectrometer was used to characterize the elemental content and distribution on the surface and cross section of the MAO coating. The phase composition of the MAO coating was characterized using X-ray diffractometer. The corrosion resistance of the MAO coating was characterized using an electrochemical workstation.

The results showed that when the addition of nano-SiO₂ particles is 3 g/L, the corrosion resistance is optimal.

This study investigated the influence of different concentrations of nano-SiO₂ particles on the structure and properties of the MAO coating of 7075 aluminum alloy.