Search results

The purpose of this paper is to analyse structure and measure hardness of Co-Cr dental alloy samples made with two different technologies, conventional casting method (CCM samples) and additive direct metal laser sintering technology (DMLS samples), and to compare the results.

CCM samples were made in a conventional casting machine, using remanium 800+ Co-Cr dental alloy (Dentaurum, Ispringen, Germany). DMLS samples were fabricated out of EOS CC SP2 Co-Cr alloy (EOS, GmbH, Munich, Germany) using DMLS technology. Samples for structural analysis were plate-shaped (10 × 10 × 1.5 mm3) and for the hardness test were prismatic-shaped (55 × 10.2 × 11.2 mm3). Structure was analysed via an inverting microscope and colour metallography method.

CCM samples have a dense, irregular dendritic mesh, which is typical for the metallic phase of the Co-Cr dental alloy. DMLS alloy has a more homogenous and more compact structure, compared to CCM. Metals, the alloy basis consists of, form semilunar stratified layers, which are characteristic for the additive manufacturing (AM) technique. Hardness values of DMLS (mean value was 439.84 HV10) were found to be higher than those of CCM (mean value was 373.76 HV10).

There are several reports about possible use of AM technologies for manufacturing dental devices, and investigation of mechanical properties and biocompatibility behaviour of AM-produced dental alloys. Microstructure of Co-Cr alloy made with DMLS technology has been introduced for the first time in the present paper.

Rapid manufacture‐produced cobalt chromium alloys are beginning to be used in dentistry but there are few published results relating to their properties. The purpose of this paper is to determine the corrosion resistance of a rapid manufacture‐produced dental alloy and compare it to a standard dental casting alloy.

In accordance with ISO 22674, ten samples of each alloy were fabricated in approximately 45 mm×10 mm×2 mm rectangular prisms, a sample number in excess of the standard requirements. The groups were further divided into those with highly polished surfaces and those with electrobrightened surfaces. Each sample was immersed in artificial saliva, suspended by a nylon thread for 42 days at 37°C. Readings for cobalt, chromium and molybdenum ions released into solutions were obtained using an atomic absorption spectrometer at 1, 4, 7, 14, 21, 28, 35, and 42 day intervals at a detection limit of one part per million.

Ion release of cobalt, chromium and molybdenum was well within the threshold prescribed by the standard. The alloys were safe for use as dental devices with respect to the above metals. The rapid manufacture alloy however performed better. In addition the data indicated that for both alloys, there was no discernable difference between a polished and an electrobrightened surface.

The rapid manufacture alloy studied shows a safe level of corrosion resistance with respect to cobalt, chromium and molybdenum according to ISO definitions. Further biocompatibility tests are recommended.

This in vitro study aims to explore the effects of selective laser melting (SLM) process parameters on the accuracy of the intaglio surface of cobalt–chromium alloy (Co–Cr), commercially pure titanium (CP Ti) and titanium alloy (Ti–6Al–4V) maxillary removable partial denture (RPD) frameworks and optimize these process parameters.

Maxillary RPD framework specimens designed on a benchmark model were built. The process parameters, including contour scan speed and laser power, infill scan speed and laser power, hatch space, build orientation and metallic powder type, were arranged through the Taguchi design. Three-dimensional deviations of the clasps area, connector area and overall area of maxillary RPD frameworks were analyzed by using root mean square (RMS) as a metric. One-way analyses of variance with the above RMSs as the dependent variable were carried out (α = 0.05).

Maxillary RPD frameworks built horizontally had a more accurate intaglio surface than those built at other orientation angles; CP Ti or Ti–6Al–4V maxillary RPD frameworks had a more accurate intaglio surface than Co–Cr ones; the Maxillary RPD framework built with a higher infill scan speed and lower infill laser power had the more accurate intaglio surface than the one built with other levels of these two process parameters.

A novel benchmark model for evaluating the accuracy of the intaglio surface of maxillary RPD frameworks manufactured by SLM is proposed. The accuracy of the intaglio surface of maxillary RPD frameworks can be improved by adjusting SLM process parameters. The optimal setting of process parameters concerning the accuracy of the intaglio surface of maxillary RPD frameworks was given.

Designers of critical devices and machines are frequently confronted with the need to compromise between available materials which will resist, simultaneously, mechanical wear by elements in contact and corrosion by a process environment. These two qualities have long been mutually exclusive from the materials selection point of view. Yet many severe environments, long life requirements, and precision designs require both. Research applied to this need at the E. I. du Pont de Nemours & Co., Inc. has identified alloys of a unique nature which are now available under the trade mark, Tribaloy.

The purpose of this paper is to outline some key aspects such as material systems used, phenomenological and statistical process modeling, techniques applied to monitor the process and optimization approaches reported. All these need to be taken into account for the ongoing development of the SLM technique, particularly in health care applications. The outcomes from this review allow not only to summarize the main features of the process but also to collect a considerable amount of investigation effort so far achieved by the researcher community.

This paper reviews four significant areas of the selective laser melting (SLM) process of metallic systems within the scope of medical devices as follows: established and novel materials used, process modeling, process tracking and quality evaluation, and finally, the attempts for optimizing some process features such as surface roughness, porosity and mechanical properties. All the consulted literature has been highly detailed and discussed to understand the current and existing research gaps.

With this review, there is a prevailing need for further investigation on copper alloys, particularly when conformal cooling, antibacterial and antiviral properties are sought after. Moreover, artificial intelligence techniques for modeling and optimizing the SLM process parameters are still at a poor application level in this field. Furthermore, plenty of research work needs to be done to improve the existent online monitoring techniques.

This review is limited only to the materials, models, monitoring methods, and optimization approaches reported on the SLM process for metallic systems, particularly those found in the health care arena.

SLM is a widely used metal additive manufacturing process due to the possibility of elaborating complex and customized tridimensional parts or components. It is corroborated that SLM produces minimal amounts of waste and enables optimal designs that allow considerable environmental advantages and promotes sustainability.

The key perspectives about the applications of novel materials in the field of medicine are proposed.

The investigations about SLM contain an increasing amount of knowledge, motivated by the growing interest of the scientific community in this relatively young manufacturing process. This study can be seen as a compilation of relevant researches and findings in the field of the metal printing process.

The purpose of this paper is to provide a practical review of the use of the minimum quantity lubrication (MQL) system in turning operations, focussing on the application of the technique in the turning of different kind of materials.

The use of the MQL system was analysed by several researchers in the past years. Thus, in the present paper, a relevant sample of the main experimental studies that can be found in the literature was analysed to come up with a review with relevant information for researchers and industry.

The use of the MQL system can help to improve the outcomes of the turning process in several issues like surface quality or tool life. However, it was also recognised that in some cases, other cooling/lubricating methods can provide better results than the MQL system. Thus, the decision, whether to use or not the MQL system in a specific process, is of great importance.

The work is conveniently focussed to serve as a quick reference on the issue. At the same time, the work analysed the use of the turning of some of the main engineering materials that makes it useful for a wider range of researchers and metalworking firms. Finally, the review could be useful to improve the performance of the industry, especially for the metalworking firms in terms of costs, environmental impact and safety.

In this paper, the mechanical properties and corrosion resistance of CoCr alloy fabricated by selective laser melting (SLM) were studied, and the changes of performance after porcelain sintering process were also analysed. This study is to point out the relationship between the microstructure, mechanical properties and corrosion resistance of CoCr alloys prepared by SLM after porcelain sintering process. In addition, the biosafety of the sintered CoCr alloy was evaluated.

The microscopic feature changes of CoCr alloy samples after porcelain sintering process were observed by DMI 5000 M inverted metallographic microscope and Nova Nano430 FE-SEM. Moreover, phase identification and determination were conducted by X-ray diffraction (XRD) using Smartlab X-ray diffractometer. The Vickers microhardness was measured on the HVS-30 microhardness tester, and tensile tests were carried out on a CM3505 electronic universal testing machine. The corrosion resistance was tested by a classical three-point electrode system electrochemical method, then the ion precipitation was measured by using an atomic absorption spectrometer of Z2000 7JQ8024.

The XRD results indicate that the transition of γ phase (FCC) to e phase (HCP) occurs during the porcelain sintering processing of CoCr alloy. Moreover, the Vickers microhardness of the upper surface and the side surface of the CoCr alloy sample was improved by more than 36%. In addition, the ultimate strength of CoCr alloy via porcelain sintering treatment was increase to 1,395.3 ± 53.0 MPa compared to 1,282.7 ± 10.1 MPa of unprocessed CoCr alloy. However, the corrosion resistance of CoCr alloy samples decreases after porcelain sintering process.

There are few studies on the relationship of microstructure, mechanical properties and corrosion resistance of CoCr alloys prepared by SLM after porcelain sintering process. In this study, the microstructure, mechanical properties and corrosion resistance of CoCr alloy after porcelain sintering process were studied, and the biosafety of the alloy was evaluated. The research found that it is feasible to apply CoCr alloy fabricated by SLM to dental medicine after porcelain sintering process.

This paper aims to discuss that a WC/Co-Cr alloy coating was applied to the surface of H13 steel by laser cladding.

The oxidation behavior of the WC/Co-Cr alloy coating at 600°C was investigated by comparing it with the performance of the steel substrate to better understand the thermal stability of H13 steel.

The results showed that the WC/Co-Cr alloy coating exhibited better high-temperature oxidation resistance and thermal stability than did uncoated H13 steel. The coated H13 steel had a lower mass gain rate and higher microhardness than did the substrate after different oxidation times.

The WC/Co-Cr alloy coating was composed of e-Co, CW3, Co6W6C, Cr23C6 and Cr7C3; this mixture offered good thermal stability and better high-temperature oxidation resistance.

The purpose of this research paper is to compare corrosion data obtained from additive-manufactured heat-treated (HRx) and non-heat-treated (NHRx) cobalt-chromium (Co–Cr) alloys. Heat treatments are indicated as necessary in complex intra-oral framework production by additive manufacturing to remove accumulated thermal stresses. However, heat treatments have been linked to corrosion in cast dental alloys. Currently, there are few publications on this subject for laser-sintered dental alloys required for academic review.

Five rectangular specimens (n = 5), each with a total surface area of 10.27 cm2, were fabricated for the two groups. Specimens were immersed in an artificial saliva solution suspended by a nylon thread for 42 days at 37°C. Readings for Co, Cr and molybdenum ions released into the solution were obtained using an atomic absorption spectrometer at 1-, 4-, 7-, 14-, 21-, 28-, 35- and 42-day intervals at a detection limit of one part per million. Test methods are in accordance with ISO 10271.

Results showed a higher ion release in the HRx sample, statistically significant at 99 per cent confidence level (p < 0.01). A two-way ANOVA test conducted showed that there was a main effect of day and a main effect of finish, and there was also a significant interaction between these factors.

The study concludes that, although ion release in both samples was within the safe level recommended by ISO for the three major alloying elements, heat treatment, indeed, contributed extensively to the reduced corrosion resistance in the laser-sintered Co–Cr alloy. Further biocompatibility tests are recommended.

The purpose of this paper is to examine the effect of internal pores on the tensile properties of a Co–Cr–Mo alloy fabricated by selective laser melting (SLM).

The size and volume fraction of pores were controlled through high temperature annealing (HTA) and hot isostatic pressing (HIP).

After HTA, the size and fraction of pores decreased compared with the as-built SLM sample, and no pores were observed after HIP. Tensile tests of the HTA and HIP samples showed nearly similar tensile deformation behavior. From the results, the authors found that the size of the internal pores formed in the SLM process had little effect on the tensile properties. The as-built SLM sample had less elongation than the HTA and HIP samples, which would not the effect of porosity, but rather the effect of the residual stress and the retained ε phase after the SLM process.

Although pores are a main factor that influence the mechanical properties, the effect of pores on the tensile properties of Co–Cr–Mo alloys fabricated by SLM has not been studied. Therefore, in this study, the effect of pores on the tensile properties of a Co–Cr–Mo alloy fabricated by SLM was studied.