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The purpose of this study is to present a finite element (FE) implementation of phenomenological three-dimensional viscoelastic and viscoplastic constitutive models for long term behaviour prediction of polymers.

The method is based on the small strain assumption but is extended to large deformation for materials in which the stress-strain relation is nonlinear and the concept of incompressibility is governing. An empirical approach is used for determining material parameters in the constitutive equations, based on measured material properties. The modelling process uses a spring and dash-pot and a power-law approximation function method for viscoelastic and viscoplastic nonlinear behaviour, respectively. The model improvement for long term behaviour prediction is done by modifying the material parameters in such a way that they account for the current test time. The determination of material properties is based on the non-separable type of relations for nonlinear materials in which the material properties change with stress coupled with time.

The proposed viscoelastic and viscoplastic models are implemented in a user material algorithm of the FE general-purpose program ABAQUS and the validity of the models is assessed by comparisons with experimental observations from tests on high-density polyethylene samples in one-dimensional tensile loading. Comparisons show that the proposed constitutive model can satisfactorily represent the time-dependent mechanical behaviour of polymers even for long term predictions.

The study provides a new approach in long term investigation of material behaviour using FE analysis.

The purpose of this paper is to provide a computational procedure for a novel damage‐coupled material law for semicrystalline polyethylene. Using a damage mechanics approach, the model seeks to gain insight into the mechanical behaviour of polyethylene considering the microstructure and degradation processes occurring under uniaxial tension.

The material morphology is modelled as a collection of inclusions. Each inclusion consists of crystalline material lying in a thin lamella attached to an amorphous layer. The interface region interconnecting the two phases is the plane through which loads are carried and transferred by the tie molecules. It is assumed that the constitutive model contains complete information about the mechanical behaviour and degradation processes of each constituent. After modelling the two phases independently, the inclusion behaviour is found by applying some compatibility and equilibrium restrictions along the interface plane.

The model provides a rational representation of the damage process of the intermolecular bonds holding crystals and of the tie‐molecules connecting neighbouring crystallites. The model is also used to analyze the degree of relationship between some of the material properties and the mechanical responses.

In practice, the numerical model clearly helps to understand the influence of the different microstructure properties on the tensile mechanical behaviour of semicrystalline polyethylene – an issue of particular interest in improving material processability and product performance.

To the authors’ knowledge, a phenomenon such as microstructural degradation of polyethylene has not received much attention in the literature. The proposed model successfully captures aspects of the material behaviour considering crystal fragmentation and tie‐molecule rupture.

The purpose of this paper is to formulate an algorithm for a novel damage‐coupled material law for crystalline polyethylene at finite inelastic strains followed by investigation of the influence of the aggregate representation and material parameters on the material response.

The constitutive equations are developed within the framework of continuum damage mechanics to describe crystal fragmentation caused by atomic debonding of the crystallographic planes. The material is assumed initially isotropic and homogeneous and is represented as an aggregate of randomly oriented crystals with an orthorhombic lattice. For the velocity gradient, an additive decomposition into symmetric and skew‐symmetric components is applied, where the skew‐symmetric part (spin) is decoupled from the lattice shear by means of a damage variable. Structural features such as lattice parameters and orientations, slip systems, and kinematic constraints are incorpo‐rated.

The proposed model is implemented to predict stress‐strain behaviour under uniaxial tension and damage accumulation and texture development at the different stages of deformation. In the numerical examples, the effects of the aggregate size, crystal orientations, and material parameters on the model estimates are analyzed.

The model used herein is a first attempt to analyze the influence of crystal fragmentation caused by the debonding of the crystallographic planes on the predicted mechanical behaviour and texture development of polyethylene prior to failure.

The purpose of this paper is to prepare nano size micro-emulsion co-polymer particles based on butyl acrylate (BA)/acrylic acid (AAc) with high monomer/surfactant ratio. The study involved the application of the prepared micro-emulsions co-polymers as textile pigment printing binders.

The micro-emulsion co-polymerisations processes were carried out with different mixtures of BA and AAc using modified process. Sodium dodecyl sulphate (SDS) and potassium peroxy disulphate/glucose were used as emulsifier and redox initiator, respectively. The prepared emulsion co-polymer was characterized via spectroscopic measurements, FT-IR, 1H-NMR and transmission electron microscope (TEM), in addition to thermal analysis. The prepared micro-emulsion co-polymers were applied as binders for pigment printing process onto cotton fabric, polyester and cotton/polyester blend by using flat screen technique. The optimum curing conditions were determined, colour strength and fastness properties of pigment printed areas to light, washing, perspiration and rubbing were evaluated. In addition, stiffness of the prints was studied.

The achieved results indicated that particle size and homogeneity of the prepared micro-emulsions depend on monomers weight ratio, initiator and emulsifier concentrations. On the other hand, the prints obtained using the prepared binders with optimum conditions have satisfactory fastness, good handle and high colour yield.

Monomers were continuously and slowly added into the polymerising system with mild stirring to avoid disturbing the stability of the micro-emulsion. Also, emulsifier and initiator concentrations should be controlled to avoid coagulation.

The research provides textile pigment printing binder with nano particle size within the range of 24-48 nm. Using the prepared nano binders in pigment printing enhances the stiffness, handle, and fastnesses properties of the prints.

The prepared co-polymer binders showed high-performance physico-mechanical properties; in addition, the ultimate goal of this study is to prepare a nano size binder with high monomer/surfactant ratio using a modified micro-emulsion process.

The purpose of this paper is to explore the tribological properties of high-density polyethylene (HDPE) modified by carbon soot from the combustion of No. 0 diesel.

Carbon soot is characterized using X-ray diffraction, transmission electron microscopy and scanning electronic microscopy. The tribological properties of HDPE samples with carbon soot are investigated on a materials surface tester with a ball-on-disk friction pair.

The collected carbon soot mainly comprises amorphous carbon nanoparticles of 50-100 nm in diameter. The main wear behaviours of pure HDPE include abrasive wear and plastic deformation. After adding carbon soot nanoparticles to HDPE, HDPE wear decreases. The appropriate carbon soot content is 8 per cent in HDPE under the selected testing conditions. Compared with other HDPE samples, HDPE with 8 per cent carbon soot has higher melting temperature, lower abrasive wear and better wear resistance. The lubrication of HDPE with carbon soot is due to the formation of a transferring film composed of HDPE, amorphous carbon and graphite carbon.

The paper reveals the HDPE modification and lubrication mechanisms by using carbon soot from the combustion of diesel. Related research can perhaps provide a potential approach for the treatment of carbon soot exhaust emission.

The present research aims to manage the formulations of pigment-based inks containing aminopropyl/vinyl/silsesquioxane (APSV) as a pigment binding agent for inkjet printing of polyester as a commercial trial for the printing of polyester as a single-step process.

The proposed formulations incorporated APSV by using the mini-emulsion technique at a low relieving temperature under the thermal initiation or UV radiation of vinyl-terminated groups in APSV. In this study, the storage stability of inks with regard to physical properties was broadly examined. Moreover, the color performance, including colorimetric data, color fixation and fastness properties of printed fabrics was evaluated.

The results indicated that the inks containing APSV were formulated and were stable in terms of particle size, dispersion stability, surface tension and viscosity over a period of one month and for four freeze/thaw cycles. APSV successfully fixed the pigment-based inkjet inks on polyester fabric and could achieve a significantly higher color performance and degree of fixation than the formulated inks without APSV.

It could also fulfill all the physical properties of ink prerequisites over storing and eliminating all challenges in improving the performance and utilization of inkjet printing.

APSV can also be used as a pigment binding agent to formulate inks for inkjet printing of polyester fabrics as the authors’ past examination for inkjet printing of polyester fabrics post-treated with APSV.

This study eliminates the noteworthy challenges in formulating the pigment-based inks for textile applications by incorporation of a binder while keeping up the necessary viscosity profile for a specific print head.

This study addressed all the issues arising from the complex nature and very challenging requirements of inkjet inks.