Early wetting and interfacial behavior of Sn-based solder on copper substrates with different roughness

Abstract

Purpose

This paper aims to investigate the effect of solder composition and roughness on early wetting behavior and interfacial reaction under atmospheric conditions.

Design/methodology/approach

High-speed photography is used to observe the early wetting and spreading process of the solder on the substrate in real time. The morphology of intermetallic compounds (IMCs) was observed by scanning electron microscopy, and the composition of IMCs micro bumps was determined by energy dispersive spectroscopy.

Findings

With a roughness range of 0.320–0.539 µm, the solder is distributed in an elliptical trilinear pattern along the grinding direction. With a roughness range of 0.029–0.031 µm, the solder spreads in the direction of grinding and perpendicular, forming a perfect circle (except in the case of Sn63Pb37 solder). The effect of three types of solder on early wettability is Sn63Pb37 > Sn96.5Ag3Cu0.5 > Sn. The wetting behavior is consistent with the Rn∼t model. The rapid spreading stage (Stage I) is controlled by the interfacial reaction with n1 values between 2.4 and 4. The slow spreading stage (stage II) is controlled by diffusion with n2 values between 4 and 6.7. The size of Cu6Sn5 formed on a rough substrate is greater than that produced on a smooth substrate.

Originality/value

Investigating the effect of solder composition and roughness on early wettability. This will provide a powerful guide in the field of soft brazing.

Citation

Han, Y., Chen, J., Zhang, S. and Yu, Z. (2023), "Early wetting and interfacial behavior of Sn-based solder on copper substrates with different roughness", Soldering & Surface Mount Technology, Vol. 35 No. 5, pp. 331-343. https://doi.org/10.1108/SSMT-07-2023-0041