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1 – 10 of 976Human selection of periodical references from the full text, for inclusion in the Mass Spectrometry Bulletin, is compared with the retrieval from the same source material by the…
Abstract
Human selection of periodical references from the full text, for inclusion in the Mass Spectrometry Bulletin, is compared with the retrieval from the same source material by the mechanized current awareness SDI services of CT and ASCA. Results show human selection to have retrieved substantially more references than SDI using brief, high relevance profiles. Experiments with CT using a larger profile show an increase in recall but a drop in precision. Precision is assessed in relation to the selection/rejection policy for the Bulletin, which is briefly discussed. The effectiveness of the SDI services as a means of indicating references in periodicals outside the range of those examined in detail is also discussed.
Chinwuba Victor Ossia, Kong Hosung and Lyiubov V. Markova
The purpose of this paper is to present an optical technique for the condition monitoring of synthetic hydraulic oil; a deviation from the current techniques based on electrical…
Abstract
Purpose
The purpose of this paper is to present an optical technique for the condition monitoring of synthetic hydraulic oil; a deviation from the current techniques based on electrical principles which could be masked by wear particles and polar contaminants in oil.
Design/methodology/approach
Color‐change detecting device was developed using light‐emitting diodes, optic fibers and photodiodes of three‐color‐sensing elements. Color ratio (CR) and total contamination parameters based on transmitted light intensity in red, green, and blue wavelengths were used for oil chemical and particulate contamination assessment.
Findings
CR criterion was found independent of the particulate contamination of oil; but depended on chemical degradation. Total contamination index of the device depended on both the chemical degradation and particulate contamination of the oil, being most sensitive in blue wavelength, and least in the red. Test results for synthetic hydraulic oils monitored corroborated with results of viscosity, total acid number, RDE emission spectrometry, particulate counts and UV‐Vis photospectrometry. CR showed a clearer indication of oil degradation, compared to key monitoring parameters such as total acid number, viscosity, RDE emission spectrometry and particle counts.
Originality/value
This paper demonstrates how oil chemical degradation and total contamination could be detected through the device, before incipient wear occurs at tribological interfaces. The results showed that the color‐change parameters are effective criteria for the condition monitoring of synthetic hydraulic oils.
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Sabina Licen, Elija Muzic, Sara Briguglio, Arianna Tolloi, Pierluigi Barbieri and Pasquale Giungato
Methods to assess the authenticity and traceability of wines have been extensively studied as enhancers of food quality, allowing producers to obtain market recognition and…
Abstract
Purpose
Methods to assess the authenticity and traceability of wines have been extensively studied as enhancers of food quality, allowing producers to obtain market recognition and premium prices. Among analytical techniques, the volatilome profile attained by gas chromatography coupled with mass spectrometry is acquiring more and more attention by the scientific community, together with the use of chemometrics
Design/methodology/approach
The volatilome profile of three varieties of blanc wines from the Collio area (namely Ribolla Gialla, Malvasia and Friulano) between Italy and Slovenia, was determined by head space-solid phase micro extraction-gas chromatography-mass spectrometry, enhancing the carbonyl compounds identification with O-(2, 3, 4, 5, 6-pentafluorobenzyl)-hydroxylamine with the aim of identifying the autochthonous Friulano variety.
Findings
A two-step chemometric approach based on an unsupervised technique (PCA) followed by a supervised one (PLS-DA) allowed to identify possible markers for discriminating the Friulano Collio variety from the others, in particular two chemical classes were identified by PCA (ketones and long chain esters). PLS-DA showed 87% accuracy in classification. A correct classification (i.e. non-Friulano Collio) of a group of wines obtained from the same grape variety but produced in an extra-Collio area was obtained as well. The results confirmed the benefits of using a derivatization step prior to volatile organic compounds analysis.
Research limitations/implications
Among methods to assess the authenticity and traceability of wines, volatilome profile of wines determined by head space-solid phase micro extraction-gas chromatography-mass spectrometry, enhanced by the carbonyl compound identifications with O-(2, 3, 4, 5, 6-pentafluorobenzyl)-hydroxylamine, may have a key role in conjunction with chemometrics and, in particular with principal component analysis and partial least square discriminant analysis.
Practical implications
Among methods to assess the authenticity and traceability of Friulano wine, volatilome profile of wines determined by head space-solid phase micro extraction-gas chromatography-mass spectrometry, enhanced by the carbonyl compound identifications with O-(2, 3, 4, 5, 6-Pentafluorobenzyl)Hydroxylamine hydrochloride, may have a key role in conjunction with chemometrics.
Originality/value
Few works investigated both wine traceability with a volatilome enhancer and chemometrics of the Friulano wine variety obtaining such an improvement in this wine variety discrimination.
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Abstract
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This report describes the Crystallographic Data Centre, the Engineering Sciences Data Unit and the Mass Spectrometry Data Centre, under headings covering scope and general…
Abstract
This report describes the Crystallographic Data Centre, the Engineering Sciences Data Unit and the Mass Spectrometry Data Centre, under headings covering scope and general description, input acquisition and processing, outputs, distribution mechanisms, staff training and recruitment, user aspects, cost‐benefit considerations and future developments. It is based on information collected from published literature, extended interviews conducted at each centre, materials made available by the centres and a limited amount of telephone contact with users. The study was carried out between 17–28 January 1983, on behalf of the Office of Arts and Libraries, to provide input for the Library and Information Services Council Working Party on Centres of Information Excellence. Each of the three centres studied produces high‐quality specialised data, organised and validated to suit the requirements of specialist groups. All have been in existence for at least fifteen years, and all have enjoyed Government support at some time. Two are now profit‐seeking and one is non‐profit; one is university‐based, one is a private company and one is part of the Royal Society of Chemistry.
Ding‐Rong Qu, Yu‐Gui Zheng, Xiu Jiang and Wei Ke
The objective of the present work was to study the influence of chemical compositions of five naphthenic acids (NAs) extracted from Liaohe crude oil on their corrosivity.
Abstract
Purpose
The objective of the present work was to study the influence of chemical compositions of five naphthenic acids (NAs) extracted from Liaohe crude oil on their corrosivity.
Design/methodology/approach
Fourier‐transform infrared spectrometry and electron impact mass spectrometry were used to characterize the chemical structures and compositions if five NAs. The corrosivities of the NAs were assessed by stagnant NA corrosion (NAC) tests. An attempt was made to identify any correlation between the chemical composition of the NAs and their corrosiveness.
Findings
The acidic species in all five NA samples were saturated aliphatic and naphthenic acids and the amount of aromatic and unsaturated acids was negligible. A relationship between the carboxylic acid distribution and the molecular weight was obtained. Most of the carboxylic acids in five NAs contained 0‐3 ring structures. NAs with lower molecular weight and fewer ring structures usually were more corrosive.
Originality/value
The findings have important implications for assessing the corrosivity of acidic crude oils from various resources.
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Wei Gao, Naiying Wu and Wenliang Sun
This paper aims to present a robust method for the determination of α- and ß-2, 7, 11-cembratriene-4, 6-diols (α, ß-CBT-diol) in tobacco samples which was developed and validated…
Abstract
Purpose
This paper aims to present a robust method for the determination of α- and ß-2, 7, 11-cembratriene-4, 6-diols (α, ß-CBT-diol) in tobacco samples which was developed and validated by using the self-made α, ß-CBT-diol with higher purity as the standard.
Design/methodology/approach
After the ultrasonic extraction and clean-up procedures, samples were analyzed by gas chromatography/mass spectrometry in selected ion monitoring mode and full scan mode at the same time. A 1-heptadecanol was used as an internal standard. The important parameters, such as extraction conditions and derivation conditions, were optimized.
Findings
Under the optimal conditions, good results in terms of linearity (R2 > 0.999) and recoveries (93.2-107 per cent) were achieved. The limits of detection were 0.120 and 0.180 μg/ml for α- and ß-CBT-diol, respectively. α, ß-CBT-diol level of analyzed tobacco was found in the range of 34.2-1.26 × 103 μg/g with relative standard deviations below 6 per cent.
Originality/value
Such a strategy opens a new door towards the development of a simple, robust and sensitive method for the determination of α, ß-CBT-diol in real samples.
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S. Taylor, J.R. Gibson and B. Srigengan
In the last 10 years there has been an increasing trend towards miniaturisation in mass spectrometry. Miniature versions of magnetic sector, time of flight (TOF) and quadrupole…
Abstract
In the last 10 years there has been an increasing trend towards miniaturisation in mass spectrometry. Miniature versions of magnetic sector, time of flight (TOF) and quadrupole mass spectrometers (QMS) have all been developed. Some of these systems use silicon microengineering technology, e.g. MEMS, to achieve the small geometries necessary, other systems use conventional engineering but on a reduced scale. The scientific advantages of miniaturisation include the ability to measure and monitor at higher vacuum pressures than hitherto (>10−2 mbar). Miniaturisation also offers advantages due to the reduced cost and resulting portable nature of the smaller instruments.
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Qiong Wang, Zeng-Lai Xu and Zhihong Cheng
The precise and sensitive methods for authentication and differentiation of natural and synthetic indigo dyes are required for assurance of textile safety and public health. This…
Abstract
Purpose
The precise and sensitive methods for authentication and differentiation of natural and synthetic indigo dyes are required for assurance of textile safety and public health. This study aims to develop a fast and simple method to distinguish natural indigo from synthetic one.
Design/methodology/approach
A static headspace gas chromatography-mass spectrometry (GC-MS) method was developed for identification of natural and synthetic indigo samples. Natural indigo samples prepared from three different plants and synthetic indigo samples from three famous manufacturers in China, were involved in this study, along with some nonindigo blue samples (such as direct blue, active blue and neutral blue). The yarns and fabrics dyed with natural and synthetic indigo were also analyzed by the GC-MS method.
Findings
High levels of aniline (21.87%–71.59%) or N-methylaniline (25.26%–38.73%) were detected only in synthetic indigo samples (1 g) using the static headspace GC-MS method. The yarns and fabrics dyed with the synthetic indigo were also detected with residual aniline (0.47%–14.86%) or N-methylaniline (6.59%–40.93%).
Originality/value
The results clearly demonstrated that aniline or N-methylaniline can be used a diagnostic marker for distinguishing natural indigo from synthetic indigo. The proposed static headspace GC-MS method is a rapid, simple and convenient approach for differentiation of natural and synthetic indigo, as well as for the yarns and fabrics dyed with synthetic indigo.
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