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In this paper, the authors aim to study the effect of hydrogen on the pitting corrosion behavior of Incoloy 825, a commonly used material for heat exchanger tubes in hydrogenated heat exchangers.

The pitting initiation and propagation behaviors were investigated by electrochemical and chemical immersion experiments and observed and analyzed by scanning electron microscope and energy dispersive spectrometer methods.

The results show that hydrogen significantly affects the electrochemical behavior of Incoloy 825; the self-corrosion potential decreased from −197 mV before hydrogen charging to −263 mV, −270 mV and −657 mV after hydrogen charging, and the corrosion current density increased from 0.049 µA/cm² before hydrogen charging to 2.490 µA/cm², 2.560 µA/cm² and 2.780 µA/cm² after hydrogen charging. The pitting susceptibility of the material increases.

Hydrogen is enriched on the precipitate, and the pitting corrosion also initiates at that location. The synergistic effect of hydrogen and precipitate destroys the passive film on the metal surface and promotes pitting initiation.

The restoration and strengthening of QT600 is an industry bottleneck challenge. The Co-12 cladding layer has great wear and corrosion resistance. The purpose of this paper is to quantitatively reveal the transient evolution law of the corrosion process of Co-12 cladding layer on QT600 surface.

In this paper, a three-dimensional numerical model of the corrosion process of Co-12 cladding layer by QT600 laser cladding is established. The interaction between pitting pits and corrosion medium is considered to reveal the transient evolution of ion concentration, electrode potential, pH and corrosion rate at different locations.

The calculation shows that the ion concentration in pitting pit changes Cl⁻>Co²⁺>Na⁺, pH value decreases from top to bottom and corrosion rate at bottom is greater than that at top. The electrochemical corrosion test of Co-12 cladding layer was carried out. It is shown that the current density of QT600 increases by an order of magnitude compared to the Co-12 cladding layer, and the corrosion rate is 4.862 times higher than that of the cladding layer.

The results show that Co-12 cladding layer has great corrosion resistance, which provides an effective way for QT600 protection.

The aim of this paper is to construct a device that simulated the seawater splash zone, dynamic waterline zone (splash zone) and full immersion zone. Localized corrosion of 2A12 aluminum alloy long-scale specimen was studied.

Corrosion morphologies before and after the corrosion product removal were used to identify corrosion intensity at full seawater immersion zone, dynamic waterline zone (splash zone) and atmospheric zone. The average depth and diameter of corrosion pits in the three zones were evaluated by three-dimensional optical microscopy. The impact of wetting time of the atmospheric zone on the localized corrosion was investigated.

Corrosion pits were observed on the surface on day 4 for the wetted atmospheric zone (Case 1), and on the surface on day 8 for the alternant wet/dry atmospheric zone (Case 2). The corrosion product layer on the surface for Case 1 was partially broken down while the layer on the surface for Case 2 was intact. Average pitting depth and pitting diameters for Case 1 were more serious than that for Case 2.

The above findings revealed that the humidity of the atmospheric zone had great impact on the localized corrosion of aluminum alloy at the seawater splash zone.

This paper aims to explore the influence of corrosion-deformation interactions (CDI) on the corrosion behavior and mechanisms of 316LN under applied tensile stresses.

Corrosion of metals would be aggravated by CDI under applied stress. Notably, the presence of nitrogen in 316LN austenitic stainless steel (SS) would enhance the corrosion resistance compared to the nitrogen-absent 316L SS. To clarify the CDI behaviors, electrochemical corrosion experiments were performed on 316LN specimens under different applied stress levels. Complementary analyses, including three-dimensional morphological examinations by KH-7700 digital microscope and scanning electron microscopy coupled with energy dispersive spectroscopy, were conducted to investigate the macroscopic and microscopic corrosion morphology and to characterize the composition of corrosion products within pits. Furthermore, ion chromatography was used to analyze the solution composition variations after immersion corrosion tests of 316LN in a 6 wt.% FeCl₃ solution compared to original FeCl₃ solution. Electrochemical experiment results revealed the linear decrease in free corrosion potential with increasing applied stress. Electrochemical impedance spectroscopy results indicated that high tensile stress level damaged the integrity of passivation film, as evidenced by the remarkable reduction in electrochemical impedance. Ion chromatography analyses proved the concentrations increase of NO₃⁻ and NH₄⁺ ion concentrations in the corrosion media after corrosion tests.

The enhanced corrosion resistance of 316LN SS is attributable to the presence of nitrogen.

The scope of this study is confined to the influence of tensile stress on the electrochemical corrosion of 316LN at ambient temperatures; it does not encompass the potential effects of elevated temperatures or compressive stress.

The resistance to stress electrochemical corrosion in SS may be enhanced through nitrogen alloying.

This paper presents a systematic investigation into the stress electrochemical corrosion of 316LN, marking the inaugural study of its impact on corrosion behaviors and underlying mechanisms.

This paper aims to examine dissimilar joints for various applications in chemical, petrochemical, oil, gas, shipbuilding, defense, rail and nuclear industry.

This study examined the effects of cold metal transfer welding on stainless steel welds for 316L austenitic and 430 ferritic dissimilar welds with ER316L, ER309L and without (autogenous) fillers. The microstructural observation was done with an optical microscope. The mechanical test was done to reveal the strength, hardness and toughness of the joint. The electrochemical polarization tests were done to reveal intergranular and pitting corrosion in the dissimilar joints.

This microstructural study shows the presence of austenitic and ferritic phases with vermicular ferrite for ER309L filler weld, and for ER316L filler weld specimen shows predominately martensitic phase in the weld region, whereas the autogenous weld shows lathy ferrite mixed with martensitic phase. Mechanical test results indicated that filler welded specimen (ER316L and ER309L) has relatively higher strength and hardness than the autogenous weld, whereas ER316L filler weld exhibited the highest impact toughness than ER309L filler weld and lowest in autogenous weld. The electrochemical corrosion results displayed the highest degree of sensitization (DOS) in without filler welded specimen (45.62%) and lower in case of filler welded specimen ER309L (4.95%) and least in case of ER316L filler welded specimen (3.51%). The high DOS in non-filler welded specimen is correlated with the chromium carbide formation. The non-filler welded specimen shows the highest pitting corrosion attack as compared to the ER316L filler weld specimen and relatively better in ER309L filler welded specimen. The highest pitting corrosion resistance is related with the high chromium content in ER309L composition.

This experimental study is original and conducted with 316L and 430 stainless steel with ER316L, ER309 and without fillers, which will help the oil, shipbuilding and chemical industries.

This paper aims to investigate the effect of characteristic parameters of pits on the mechanical properties and fracture model of cable steel wires.

The tensile test and finite element analysis of steel wires with corrosion damage were carried out. The stress development of corroded steel wire under corrosion morphology was studied by the 3D reverse reconstruction technology. The internal relationship between the stress triaxiality, equivalent plastic strain and pit depth, depth-width ratio of corroded steel wire was discussed.

With the increase of corrosion degree, the neck shrinkage phenomenon of steel wire was not significant, and the crack originated near the pit bottom and expanded to the section inside of specimen. The fiber area of corroded steel wire decreased while the radiation area increased, and the ductile fracture gradually changed to brittle fracture. The pit size significantly changed the triaxial degree and distribution of stress and accelerated the initiation and propagation of internal cracks at the neck shrinkage stage.

The proposed fracture model based on the void growth model could accurately simulate the fracture behavior of steel wires with corrosion damage.

The purpose of this paper is to study the interaction of main marine organisms on localized corrosion of 316L stainless steel in the Dalian Sea area.

The steel plate was immersed in the Dalian Sea area for nine months to observe the biofouling and localized corrosion. The local potential distribution on the steel plate covered by marine organisms was measured. The local electrochemical measurements were performed to facilitate understanding the interfacial status under different biofouling conditions. The local surface morphologies and corrosion products were characterized.

The localized corrosion of stainless steel is mainly induced by the attachment of barnacles on the steel. The mussels have no influence on the localized corrosion. The cover of sea squirts could mitigate the localized corrosion induced by barnacles. Both crevice corrosion and pitting corrosion were found beneath the barnacle without the covering of sea squirts. The pitting damage was more serious than the crevice corrosion in the Dalian Sea area. The probing of sulfur element indicates that the potential growth of sulfate-reducing bacteria at barnacle center.

The above findings revealed that the interaction of marine organisms has significant influences on the localized corrosion of stainless steel. The influences of macro-fouling and micro-fouling on localized corrosion are discussed.

This study aims to discuss the influences of surface severe plastic deformation (S²PD) on the electrochemical corrosion, pitting corrosion, intergranular corrosion, stress corrosion cracking of aluminum (Al) alloys and attempt to correlate the microstructural/compositional changes with the performances.

This study provides a novel gradient design of structure/composition caused by S²PD for the purpose of enhancing Al alloys’ corrosion resistance.

S²PD has a significant effect on corrosion behavior of Al alloys through tuning the grain size, residual stress, composition, grain boundary phase and second phase particle distribution.

Although Al alloys are known to form a protective Al₂O₃ film, corrosion is a major challenge for the longevity of Al structures across numerous industries, especially for the infrastructures made of high-strength Al alloys. Traditional strategies of improving corrosion resistance of Al alloys heavily relied on alloying and coatings. In this review, gradient design of structure/composition caused by S²PD provides a novel strategy for corrosion protection of Al alloys, especially in the enhancement of localized corrosion resistance.

The purpose of this paper is to reveal the effect of microstructure on the corrosion behavior of CoCrNi alloy in 3.5 Wt.% NaCl solution.

The as-cast CoCrNi alloy was prepared by arc melting, and the cold-rolled and annealed alloys were prepared by processing the as-cast alloy.

The experimental results showed that a protective passivation film was formed on the surfaces of these CoCrNi MEA, and the stability and compactness of alloys increased in the sequence of cold-rolled, as-cast and annealed CoCrNi alloys. The annealed CoCrNi alloys had the best pitting resistance.

This study proposes the effect of the microstructure of CoCrNi alloy on corrosion resistance.

The high specific strength makes magnesium alloys have a wide range of applications in aerospace, military, automotive, marine and construction industries. However, its poor corrosion resistance and weldability have limited its development and application. Friction stir welding (FSW) can effectively avoid the defects of fusion welding. However, the microstructure, mechanical properties and corrosion behavior of FSW joints in magnesium alloys vary among different regions. The purpose of this paper is to review the corrosion of magnesium alloy FSW joints, and to summarize the protection technology of welded joints.

The corrosion of magnesium alloy FSW joints includes electrochemical corrosion and stress corrosion. This paper summarizes corrosion protection techniques for magnesium alloys FSW joints, focusing on composition, microstructure changes and surface treatment methods.

Currently, this research is mainly focused on enhancing the corrosion resistance of magnesium alloy FSW joints by changing compositions, structural modifications and surface coating technologies. Refinement of the grains can be achieved by adjusting welding process parameters, which in turn minimizes the effects of the second phase on the alloy’s corrosion resistance.

This paper presents a comprehensive review on the corrosion and protection of magnesium alloys FSW joints, covering the latest research advancements and practical applications. It aims to equip researchers with a better insight into the field and inspire new studies on this topic.