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Article
Publication date: 26 March 2024

Haichao Wang, Xiaoqiang Liu, Zhanjiang Li, Li Chen, Pinqiang Dai and Qunhua Tang

The purpose of this paper is to study the high temperature oxidation behavior of Ti and C-added FeCoCrNiMn high entropy alloys (HEAs).

Abstract

Purpose

The purpose of this paper is to study the high temperature oxidation behavior of Ti and C-added FeCoCrNiMn high entropy alloys (HEAs).

Design/methodology/approach

Cyclic oxidation method was used to obtain the oxidation kinetic profile and oxidation rate. The microstructures of the surface and cross section of the samples after oxidation were characterized by X-ray diffraction (XRD) and scanning electron microscope (SEM).

Findings

The results show that the microstructure of the alloy mainly consisted of FCC (Face-centered Cubic Structure) main phase and carbides (M7C3, M23C6 and TiC). With the increase of Ti and C content, the microhardness, strength and oxidation resistance of the alloy were effectively improved. After oxidation at a constant temperature of 800 °C for 100 h, the preferential oxidation of chromium in the chromium carbide determined the early formation of dense chromium oxide layers compared to the HEAs substrate, resulting in the optimal oxidation resistance of the TC30 alloy.

Originality/value

More precipitated CrC can preferentially oxidize and rapidly form a dense Cr2O3 layer early in the oxidation, which will slow down the further oxidation of the alloy.

Details

Anti-Corrosion Methods and Materials, vol. 71 no. 3
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 16 February 2024

Xiaowen Chen, Wanlin Xie, Song Tang, Meng Zhang, Hao Song, Qingzheng Ran and Defen Zhang

The purpose of this study is to examine the impact of MoS2 on the microstructure and characteristics of micro-arc oxidized (MAO) ceramic coatings created on ZK60 magnesium alloy…

Abstract

Purpose

The purpose of this study is to examine the impact of MoS2 on the microstructure and characteristics of micro-arc oxidized (MAO) ceramic coatings created on ZK60 magnesium alloy through the addition of varying concentrations of MoS2 particles to the electrolyte, aiming to enhance the corrosion resistance of magnesium alloy.

Design/methodology/approach

The surface morphology, roughness and phase composition of the coatings were analyzed using scanning electron microscopy, a hand-held roughness tester and an X-ray diffractometer, respectively, and the corrosion resistance of the MAO coatings prepared by the addition of different contents of MoS2 particles was tested and analyzed using an electrochemical workstation.

Findings

The results demonstrate that MoS2/MgO composite coatings have been successfully prepared on the surface of magnesium alloys through micro-arc oxidation. Furthermore, the corrosion resistance of the ZK60 magnesium alloy prepared with the addition of 1.0 g/L MoS2 was the best compared to the other samples.

Originality/value

MoS2 particles were able to penetrate the coatings successfully during the micro-arc oxidation process, acting as a barrier in the micropores to prevent the corrosion medium from touching the surface, thus improving the corrosion resistance of the sample. The electrochemical workstation was used to study the corrosion resistance of the MoS2/MAO coating on the ZK60 magnesium alloy.

Details

Anti-Corrosion Methods and Materials, vol. 71 no. 2
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 29 January 2024

Meigui Yin, Lei Zhang and Longxiang Huang

The purpose of this paper is to study the effect of surface salt spray duration on the fretting wear and electrochemical corrosion behaviors of Inconel 690 alloy.

Abstract

Purpose

The purpose of this paper is to study the effect of surface salt spray duration on the fretting wear and electrochemical corrosion behaviors of Inconel 690 alloy.

Design/methodology/approach

A high-temperature steam generator was applied to salt spray test samples, a fretting wear rig was used to realize the damage behavior tests, an electrochemical workstation was applied to analysis the changes of each sample’s corrosion dynamic response before and after fretting wear.

Findings

The thickness of the oxide film that formed on sample surface was increased with the salt spray duration, and somewhat it could act as lubrication during the fretting wear process; however, the corrosive chloride would accelerate the fretting mechanical damage behavior.

Originality/value

In a salt steam spray condition, the fretting tribo-corrosion behaviors of Inconel 690 alloy surface was studied.

Details

Anti-Corrosion Methods and Materials, vol. 71 no. 2
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 5 December 2023

Yuting Lv, Yaojie Liu, Rui Wang, Hongyao Yu, Zhongnan Bi, Guohao Liu and Guangbao Sun

This paper aims to design a novel TiC/GTD222 nickel-based high-temperature alloy with excellent hot corrosion resistance by incorporating appropriate amounts of C, Al and Ti…

Abstract

Purpose

This paper aims to design a novel TiC/GTD222 nickel-based high-temperature alloy with excellent hot corrosion resistance by incorporating appropriate amounts of C, Al and Ti elements into GTD222 alloy.

Design/methodology/approach

The composite material was prepared using the selective laser melting (SLM) technology, followed by a hot isostatic pressing (HIP) treatment. Subsequently, the composite underwent a hot corrosion test in a 75% Na2SO4 + 25% NaCl mixed salt environment at 900 °C.

Findings

The HIP-SLMed TiC/GTD222 composite exhibits a relatively low weight loss rate. First, the addition of alloying elements facilitates the formation of multiple protective oxide films rich in Al, Ti and Cr. These oxide films play a crucial role in enhancing the material’s resistance to hot corrosion. Second, the HIP treatment results in a reduction of grain size in the composite and an increased number of grain boundaries, which further promote the formation of protective films.

Originality/value

The hot corrosion behavior of the TiC/GTD222 nickel-based composite material prepared through SLM and HIP processing has not been previously studied. This research provides a new approach for designing nickel-based superalloys with excellent hot corrosion resistance.

Details

Anti-Corrosion Methods and Materials, vol. 71 no. 1
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 9 February 2024

Rizk Mostafa Shalaby and Mohamed Saad

The purpose of the present work is to study the impacts of rapid cooling and Tb rare-earth additions on the structural, thermal and mechanical behavior of Bi–0.5Ag lead-free…

Abstract

Purpose

The purpose of the present work is to study the impacts of rapid cooling and Tb rare-earth additions on the structural, thermal and mechanical behavior of Bi–0.5Ag lead-free solder for high-temperature applications.

Design/methodology/approach

Effect of rapid solidification processing on structural, thermal and mechanical properties of Bi-Ag lead-free solder reinforced Tb rare-earth element.

Findings

The obtained results indicated that the microstructure consists of rhombohedral Bi-rich phase and Ag99.5Bi0.5 intermetallic compound (IMC). The addition of Tb could effectively reduce the onset and melting point. The elastic modulus of Tb-containing solders was enhanced to about 90% at 0.5 Tb. The higher elastic modulus may be attributed to solid solution strengthening effect, solubility extension, microstructure refinement and precipitation hardening of uniform distribution Ag99.5Bi0.5 IMC particles which can reasonably modify the microstructure, as well as inhibit the segregation and hinder the motion of dislocations.

Originality/value

It is recommended that the lead-free Bi-0.5Ag-0.5Tb solder be a candidate instead of common solder alloy (Sn-37Pb) for high temperature and high performance applications.

Details

Soldering & Surface Mount Technology, vol. 36 no. 2
Type: Research Article
ISSN: 0954-0911

Keywords

Article
Publication date: 12 April 2024

Nibu Babu Thomas, Lekshmi P. Kumar, Jiya James and Nibu A. George

Nanosensors have a wide range of applications because of their high sensitivity, selectivity and specificity. In the past decade, extensive and pervasive research related to…

Abstract

Purpose

Nanosensors have a wide range of applications because of their high sensitivity, selectivity and specificity. In the past decade, extensive and pervasive research related to nanosensors has led to significant progress in diverse fields, such as biomedicine, environmental monitoring and industrial process control. This led to better and more efficient detection and monitoring of physical and chemical properties at better resolution, opening new horizons in the development of novel technologies and applications for improved human health, environment protection, enhanced industrial processes, etc.

Design/methodology/approach

In this paper, the authors discuss the application of citation network analysis in the field of nanosensor research and development. Cluster analysis was carried out using papers published in the field of nanomaterial-based sensor research, and an in-depth analysis was carried out to identify significant clusters. The purpose of this study is to provide researchers to identify a pathway to the emerging areas in the field of nanosensor research. The authors have illustrated the knowledge base, knowledge domain and knowledge progression of nanosensor research using the citation analysis based on 3,636 Science Citation Index papers published during the period 2011 to 2021.

Findings

Among these papers, the bibliographic study identified 809 significant research publications, 11 clusters, 556 research sector keywords, 1,296 main authors, 139 referenced authors, 63 nations, 206 organizations and 42 journals. The authors have identified single quantum dot (QD)-based nanosensor for biological applications, carbon dot-based nanosensors, self-powered triboelectric nanogenerator-based nanosensor and genetically encoded nanosensor as the significant research hotspots that came to the fore in recent years. The future trend in nanosensor research might focus on the development of efficient and cost-effective designs for the detection of numerous environmental pollutants and biological molecules using mesostructured materials and QDs. It is also possible to optimize the detection methods using theoretical models, and generalized gradient approximation has great scope in sensor development.

Research limitations/implications

The future trend in nanosensor research might focus on the development of efficient and cost-effective designs for the detection of numerous environmental pollutants and biological molecules using mesostructured materials and QDs. It is also possible to optimize the detection methods using theoretical models, and generalized gradient approximation has great scope in sensor development.

Originality/value

This is a novel bibliometric analysis in the area of “nanomaterial based sensor,” which is carried out in CiteSpace software.

Details

Sensor Review, vol. 44 no. 3
Type: Research Article
ISSN: 0260-2288

Keywords

Article
Publication date: 13 December 2023

Zhenyu Ma, Yupeng Zhang, Xuguang An, Jing Zhang, Qingquan Kong, Hui Wang, Weitang Yao and Qingyuan Wang

The purpose of this study is to investigate the effect of nano ZrC particles on the mechanical and electrochemical corrosion properties of FeCrAl alloys, providing a beneficial…

Abstract

Purpose

The purpose of this study is to investigate the effect of nano ZrC particles on the mechanical and electrochemical corrosion properties of FeCrAl alloys, providing a beneficial reference basis for the development of high-performance carbide reinforced FeCrAl alloys with good mechanical and corrosion properties in the future.

Design/methodology/approach

Nano ZrC reinforced FeCrAl alloys were prepared by mechanical alloying and spark plasma sintering. Phases composition, tensile fractography, corrosion morphology and chemical composition of nano ZrC reinforced FeCrAl alloys were analyzed by X-ray diffraction, scanning electron microscopy and energy dispersive X-ray spectroscopy, respectively. Microhardness and tensile properties of nano ZrC reinforced FeCrAl alloys were investigated by mechanical testing machine and Vickers hardness tester. Electrochemical corrosion properties of nano ZrC reinforced FeCrAl alloys were investigated by electrochemical workstation in 3.5 wt.% NaCl solution.

Findings

The results showed that addition of nano ZrC can effectively improve the mechanical and corrosion properties. However, excessive nano ZrC could decrease the mechanical properties and reduce the corrosion resistance. In all the FeCrAl alloys, FeCrAl–0.6 wt.% ZrC alloy exhibits the optimum mechanical properties with an ultimate tensile strength, elongation and hardness of 990.7 MPa, 24.1% and 335.8 HV1, respectively, and FeCrAl–0.2 wt.% ZrC alloy has a lower corrosion potential (−0.179 V) and corrosion current density (2.099 µA/cm2) and larger pitting potential (0.497 V) than other FeCrAl–ZrC alloys, showing a better corrosion resistance.

Originality/value

Adding proper nano ZrC particles can effectively improve the mechanical and corrosion properties, while the excessive nano ZrC is harmful to the mechanical and corrosion properties of FeCrAl alloys, which provides an instruction to develop high-performance FeCrAl cladding materials.

Details

Anti-Corrosion Methods and Materials, vol. 71 no. 1
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 29 November 2023

Devendra Pratap Singh, Vijay Kumar Dwivedi and Mayank Agarwal

The purpose of this study is to investigate and evaluate the impact of varying proportions of reinforcement on the mechanical properties of a modified Al2O3-LM6 cast composite…

Abstract

Purpose

The purpose of this study is to investigate and evaluate the impact of varying proportions of reinforcement on the mechanical properties of a modified Al2O3-LM6 cast composite under self-pouring temperature conditions. This study aims to determine the optimal mixture proportion of fine powders of Al, Si and xAl2O3 (with x values of 2%, 3% and 4%) through the application of design of experiment (DoE) and statistical analysis using the Minitab software. This study also involved evaluating the microstructural estimation and other physical properties of the cast composite to understand the combined effect of the reinforcement proportion on the material’s properties.

Design/methodology/approach

The researchers initially mixed the powders through ball milling and then compacted the moisture-free powder mix in a closed steel die. The resulting preforms were heated at the self-pouring temperature in an inert environment to fabricate the final cast composite. By applying DoE and performing an analysis of variance (ANOVA), the researchers sought to optimize the mixture proportion that would yield the best mechanical properties.

Findings

The experimental results indicated that a mixture combination of 83.5% Al blended with 12.5% Si and 4% Al2O3 led to the greatest improvement in mechanical properties, specifically in terms of increased density, hardness and impact strength. The ANOVA further supported the interaction effect of each processing parameter on the observed results. The results of this study offer valuable insights for the fabrication of modified Al2O3-LM6 cast composites under self-pouring temperature conditions. The identified optimal mixture proportion provides guidance for manufacturing processes and material selection to achieve improved mechanical properties in similar applications.

Originality/value

This study focuses on a specific composite material consisting of modified Al2O3 and LM6. Although Al2O3 and LM6 have been studied individually in various contexts, the combination of these materials and their impact on mechanical properties under self-pouring temperature conditions is a novel aspect of this research. The researchers use DoE methodology, along with statistical analysis using Minitab software, to optimize the mixture proportion and analyze the data. This systematic approach allows for a comprehensive exploration of the parameter space and the identification of significant factors that influence the mechanical properties of the composite.

Details

World Journal of Engineering, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 1708-5284

Keywords

Article
Publication date: 26 April 2024

Bo Zhang, Yuqian Zheng, Zhiyuan Cui, Dongdong Song, Faqian Liu and Weihua Li

The impact of rolling on the performance of micro arc oxidation (MAO) coatings on ZM5 alloy has been underreported. The purpose of this study is to explore the correlation between…

Abstract

Purpose

The impact of rolling on the performance of micro arc oxidation (MAO) coatings on ZM5 alloy has been underreported. The purpose of this study is to explore the correlation between rolling and the failure mechanism of MAO coatings in greater depth.

Design/methodology/approach

The influence of rolling on the corrosion and wear properties of MAO coating was investigated by phase structure, bond strength test (initial bond strength and wet adhesion), electrochemical impedance spectroscopy and wear test. The change of the surface electrochemical properties was studied by first principles analysis.

Findings

The results showed that the MAO coating on rolled alloy had better corrosion and wear resistance compared to cast alloy, although the structure and component content of two kinds of MAO coating are nearly identical. The difference in interface bonding between MAO coating and Mg substrate is the primary factor contributing to the disparity in performance between the two types of samples. Finally, the impact of the rolling process on MAO coating properties is explained through first-principle calculation.

Originality/value

A comprehensive explanation of the impact of the rolling process on MAO coating properties will provide substantial support for enhancing the application of Mg alloy anticorrosion.

Graphical abstract

Details

Anti-Corrosion Methods and Materials, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 1 December 2023

Amir Rezaei

This paper aims to study the feasibility of using machine learning in hot corrosion prediction of Inconel 617 alloy.

Abstract

Purpose

This paper aims to study the feasibility of using machine learning in hot corrosion prediction of Inconel 617 alloy.

Design/methodology/approach

By examination of the experimental studies on hot corrosion of Inconel 617, a data set was built for machine learning models. Apart from the alloy composition, this paper included the condition of hot corrosion like time and temperature, and the composition of the saline medium as independent features, while the specific mass change is set as the target feature. In this paper, linear regression, random forest and XGBoost are used to predict the specific mass gain of Inconel 617.

Findings

XGBoost yields the coefficient of determination (R2) of 0.98, which was highest among models. Also, this model recorded the lowest value of mean absolute error (0.20). XGBoost had the best performance in predicting specific mass gain of the alloy in different times at temperature of 900°C. In sum, XGBoost shows highest accuracy in predicting specific mass gain for Inconel 617.

Originality/value

Using machine learning to predict hot corrosion in Inconel 617 marks a substantial progress in this domain and holds promise for simplifying the development and evaluation of novel materials featuring enhanced hot corrosion resilience.

Details

Anti-Corrosion Methods and Materials, vol. 71 no. 1
Type: Research Article
ISSN: 0003-5599

Keywords

1 – 10 of 144