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The purpose of this study is to prepare Polystyrene grafted with Zeolite Y (Zeosty) for Uranyl ion [U(VI)] adsorption from aqueous solution. The adsorption mechanism has been explained by studying kinetic, isothermal and thermodynamic models.

Polystyrene was grafted with Zeosty by a simple hydrothermal technique. Zeosty was characterized by different techniques such as X-ray diffraction, scanning electron microscope, energy dispersive X-ray and Infrared spectroscopy to confirm its structure and its molecular composition. Zeosty was used for U(VI) adsorption from an aqueous solution in a series of batch experiments. The effects of pH, contact time, initial U(VI) concentration and temperature on the adsorption process were investigated.

The results showed that the adsorption of U(VI) on the prepared reached equilibrium at pH 6 with a removal efficiency of 98.9%. Adsorption kinetics and isotherms models are studied on the experimental data to estimate the mechanism of the adsorption reaction was chemisorption and homogenous reaction. The activity of Zeosty increased at high temperatures, resulting in the adsorption capacity increase. Thermodynamic parameters ΔGo, ΔHo and ΔSo indicate that the adsorption processes are spontaneous and endothermic. Zeosty has an effective surface and could be considered a valuable adsorbent for U(VI) removal from aqueous waste. A comparison study proves that the new adsorbent has high effective behavior in the adsorption process, and it is considered a new reliable adsorbent for U(VI) removal from wastewater.

This study is complementary to the previous study using the same technique to prove that the effective fine particle adsorbents need solid support to enhance their absorption capacities.

The purpose of this study is to prepare a new adsorbent activated carbon immobilized on polystyrene (ACPS) for uranium (VI) and thorium (IV) removal from an aqueous solution. Activated carbon (AC) was derived from biochar material by chemical activation to increase the active sites on its surface and enhance the adsorption capacity. Activated carbon (AC) was immobilized on polystyrene (PS) to improve the physical properties and facilitate separation from the working solution. A feasibility study for the adsorption of uranium (VI) and thorium (IV) on the new adsorbent (ACPS) has been achieved. Adsorption kinetics, isotherms, and thermodynamics models of the adsorption process were used to describe the reaction mechanism.

Activated carbon was synthesized from biochar charcoal by 2 M H₂SO₄. Activated carbon was immobilized on the pretreatment polystyrene by hydrothermal process forming new adsorbent (ACPS). Characterization studies were carried out by scanning electron microscope, energy-dispersive X-ray spectrometer, infrared spectroscopy and X-ray diffraction techniques. Different factors affect the adsorption process as pH, contact time, solid/liquid ratio, initial concentration and temperature. The adsorption mechanism was explained according to kinetic, isothermal and thermodynamic studies. Also, the regeneration of spent ACPS was studied.

The experimental results showed that pH and equilibrium time of the best adsorption were 6.0 and 60 min for U(VI), 4.0 and 90 min for Th(IV), (pH_PZC = 3.4). The experimental results fit well with pseudo-second order, Freundlich and Dubinin–Radushkevich models proving the chemisorption and heterogenous adsorption reaction. Adsorption thermodynamics demonstrated that the adsorption process is exothermic and has random nature of the solid/liquid interface. In addition, the regeneration of spent ACPS research showed that the adsorbent has good chemical stability. According to the comparative study, ACPS shows higher adsorption capacities of U(VI) and Th(IV) than other previous bio-adsorbents.

This study was conducted to improve the chemical and physical properties of bio-charcoal purchased from the local market to activated carbon by hydrothermal method. Activated carbon was immobilized on polystyrene forming new adsorbent ACPS for eliminating U(VI) and Th(IV) from aqueous solutions.

Today, the presence of unwanted activities threatening the safety of the field, which has negative effects on daily life and social psychology, is increasing day by day. There is no doubt that it is inevitable to avoid these threats, but it is possible to take some measures to reduce the destructive power of these threats. Nowadays, increasing terrorist attacks increase the importance of field safety design in urban areas. There is a loss of life in attacks around the world. The subject of this study is to investigate the design criteria related to the built environment and the measures to be taken in the case of bomb attacks in the built environment. In this study, a checklist will designed to measure the security design process around the building. The checklist titles are taken mainly from the “Safety design and Landscape Architecture” series of the Landscape Architecture Technical Information Series/LATIS publications by the American Society of Landscape Architects (ASLA) and the Risk Management Series of the Federal Emergency Management Agency/FEMA (FEMA, 2003, 2007; LATIS, 2016) and others. The checklist created as a result of literature review will be tested in Istanbul Sultanahmet Square. As a result of the study, it was determined that improvements should be made in the areas of vehicular and pedestrian access, parking lots, lighting and trash receptacle designs around Sultanahmet Square.

This chapter examined portrayals of the morality of organizations using the lens of Western films. The work explored six decades of film, analyzing the organizational contexts and their agents, in order to understand filmmakers’ and audiences’ perceptions of organizational settings. In order to examine the organization as an entity within film, this chapter provided a content analysis of plot summaries from a purposefully selected body of top grossing box office films spanning 60 years. The plot summaries constituted a strong basis for identifying the characteristics of the organization as they are largely descriptive in nature and as such do not offer any evaluation or analysis of the film. Any assumptions about the character of organizations (or their members/employees) are unconscious, and as such they constitute a verbal description of what competent observers would say has occurred within the film. The plots were coded to reveal perceptions of positive, neutral, or negative organizational contexts and actions. This approach exposed the filmmakers symbolic placing of the organization in order to provide backdrops for the narrative. The plot analysis revealed that throughout the decades there has been a sophisticated portrayal in film of the role of the organization and the agents therein. A generally negative view of organizational contexts was demonstrated, with only religion and education shown as positive within the films selected. It was recognized that there would be value in extending this research to analyze a larger body of works. The selection criteria resulted in a wide but not comprehensive corpus of film genres. The body of works was sufficient to reveal the complexity of attitudes to organizational values and delivery which has evolved through time. Different selection criteria and more substantial narrative text could serve to confirm these results. Further implications for future research were discussed. While in the real-life sphere, there has been an emphasis on organizational standards and “corporate governance” delivering ethical exemplars, the film contexts highlight the complexities of delivering trusted organizations. The reality that there remains the potential for organizational corruption is well understood by the general public and clearly depicted within the film world. The conceptual contribution is original as limited work has been conducted on the organizational context in films. This work revealed the possibility of using this approach to further develop a greater understanding of perceptions of organizations.