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Nowadays, ample industries are fascinated to look for high strength and light weight materials for the development of robust parts. Because of light weight and high stiffness to weight ratio; usage of aluminum parts is growing rapidly, especially in automotive engineering. Process improvement of Al alloys and their grain structure refinement is the current area of interest in casting companies. In this research work, an investigation has been carried out to enhance the process improvement of die casting by optimization of various significant parameters and their refinement of grains by the effect of Nb-C novel grain refiner.

L27 orthogonal array (OA) has been considered to optimize the preferred casting input parameters such as molten metal temperature (°C), die temperature (°C), injection pressure (bar), Al-3.5Nb-1.5 C novel grain refiner and Ni alloying additions as key process parameters in order to increase the quality and efficiency of Al-9Si-3Cu aluminum alloy die casting by reducing the porosity formation.

It was observed that the porosity values have significantly decreased from 0.88% to 0.25% particularly at 0.1 wt.% of new grain refiner and 0.5 wt. % of Al-6Ni master alloy. As per the ANOVA results, it was observed that Al-3.5FeNb-1.5 C grain refiner (F value 2609.22), Al-6Ni alloying addition (F value 1329.13), molten metal temperature (F value 1002.43) and, injection pressure (F value 448.06) are the factors that significantly affects the porosity, whereas die temperature was found to be insignificant. The results show that new grain refiner is one the most significant factor among the other selected parameters. The contribution of the new grain refiner to the variation of mean casting porosity is around 57.74%. confidence interval (CI) has also been estimated as 0.013 for 95% consistency level to validate the predicted range of optimum casting porosity of aforesaid alloy.

To the best of the authors' knowledge, no study has been conducted in the past to investigate the combined effect of these die casting parameters and composition factors for the development of Al-Si robust cast parts. The paper represents original research and provides new information for the fabrication of die casting parts.

Phosphonic acids are good complexing agents. However, they are not good as inhibitors except for a very few. Synergistic inhibition is offered in the presence of metal cations like Ca²⁺, Mg²⁺, Zn²⁺ and others in neutral media. The zinc ion is an ideal choice. The part of zinc ions are now replaced by polymers, azoles to prepare eco‐friendly inhibitor formulations. They are also used as corrosion inhibitors in concrete, coatings, rubber blends, acid cleaners, anti‐freeze coolants, etc. Discusses the various applications of phosphonic acids and their action mechanisms.

This paper aims to reduce environment pollution caused by benzotriazole. The authors chose one of the best inhibitors from 2-aminobenzimidazole, 2-methylbenzimidazol, 2-mercaptobenzimidazole and benzimidazole in combination with benzotriazole.

The electrochemical measurement indicated that 2-methylbenzimidazol had the best inhibition behavior. Then, it was mixed with benzotriazole. Techniques such as field emission scanning electron microscopy, atomic force microscopy, Raman spectroscopy and optical contact angle measurements were used.

The results showed that the inhibition efficiency was up to 99.98%, when the mixture concentration was 20 mmol/L and the molar ratio 1:1.

1-benzotriazole was mixed with 2-methylbenzimidazol for the first time. During the exist of methyl, 2-methylbenzimidazol has the better inhibition; this point was ignored by researchers.

The purpose of this paper is to construct a self-assembled double layer of organosilane on the surface of stainless steel and to investigate its corrosion inhibitive capability.

A monolayer of 3-glycidoxypropyltrimethoxysilane (GPTMS) was grafted onto an oxidized AISI 430SS (AISI 430 stainless steel) surface substrate from dry toluene solution. The hydrolysis of 1H,1H,2H,2H-perfluorodecyltriethoxysilane (PFDS) molecules was used to anchor a second organic layer from mixed water-ethanol solution. The adsorption behavior and corrosion inhibition properties of the monolayer and also the bilayer were investigated by potentiodynamic polarization, scanning electron microscope (SEM), Fourier transformed infrared spectroscopy (FTIR) and contact angle measurements.

The GPTMS/PFDS bilayer was successfully deposited onto the oxidized AISI 430SS surface. The optimal assembling time for the filming of the first GPTMS monolayer is 6 hours. Suitable values of pH and temperature of the PFDS self-assembly solution were pivotal to the successful deposition of the second layer. Compared to the GPTMS monolayer, the GPTMS/PFDS bilayer exhibited a significant enhancement of the corrosion inhibition performance of AISI 430SS in NaCl solution.

The contact angle value measured on the bilayer-modified surface was somewhat lower than the reported value of a complete fluorinated surface. However, further optimization of the assembling condition is needed to obtain more orderly and denser films.

This paper provides useful information regarding the preparation of an organosilane bilayer on the surface of stainless steel and its corrosion inhibition properties in NaCl solution. It illustrates potential application prospects of GPTMS/PFDS bilayers for surface treatment of stainless steel.