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Article
Publication date: 20 December 2021

Xiang Qiu, Kun Zhang, Qin Kang, Yicheng Fan, Hongyu San, Yiqing Chen and Heming Zhao

This paper aims to study the mechanism of hydrogen embrittlement in 12Cr2Mo1R(H) steel, which will help to provide valuable information for the subsequent hydrogen embrittlement…

158

Abstract

Purpose

This paper aims to study the mechanism of hydrogen embrittlement in 12Cr2Mo1R(H) steel, which will help to provide valuable information for the subsequent hydrogen embrittlement research of this kind of steel, so as to optimize the processing technology and take more appropriate measures to prevent hydrogen damage.

Design/methodology/approach

The hydrogen diffusion coefficient of 12Cr2Mo1R(H) steel was measured by the hydrogen permeation technique of double electrolytic cells. Moreover, the influence of hydrogen traps in the material and experimental temperature on hydrogen diffusion behavior was discussed. The first-principles calculations based on density functional theory were used to study the occupancy of H atoms in the bcc-Fe cell, the diffusion path and the interaction with vacancy defects.

Findings

The results revealed that the logarithm of the hydrogen diffusion coefficient of the material has a linear relationship with the reciprocal of temperature and the activation energy of hydrogen atom diffusion in 12Cr2Mo1R(H) steel is 23.47 kJ/mol. H atoms stably exist in the nearly octahedral interstices in the crystal cell with vacancies. In addition, the solution of Cr/Mo alloy atom does not change the lowest energy path of H atom, but increases the diffusion activation energy of hydrogen atom, thus hindering the diffusion of hydrogen atom. Cr/Mo and vacancy have a synergistic effect on inhibiting the diffusion of H atoms in α-Fe.

Originality/value

This article combines experiments with first-principles calculations to explore the diffusion behavior of hydrogen in 12Cr2Mo1R(H) steel from the macroscopic and microscopic perspectives, which will help to establish a calculation model with complex defects in the future.

Details

Anti-Corrosion Methods and Materials, vol. 69 no. 1
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 11 August 2020

Qin Kang, Yicheng Fan, Kun Zhang, Xiaolang Chen, Hongyu San, Yiqing Chen and Heming Zhao

With excellent mechanic properties and hydrogen embrittlement (HE) resistance, 12Cr2Mo1R(H) steel is suitable to make hot-wall hydrogenation reactors. However, longtime exposure…

Abstract

Purpose

With excellent mechanic properties and hydrogen embrittlement (HE) resistance, 12Cr2Mo1R(H) steel is suitable to make hot-wall hydrogenation reactors. However, longtime exposure to a harsh environment of high-pressure hydrogen at medium temperature in practical application would still induce severe hydrogen uptake and eventually damage the mechanical properties of the steel. The study aims to evaluate the HE resistance of the steel under different tensile strain rates after hydrogen charging and analyze the hydrogen effect from atomic level.

Design/methodology/approach

This research studied the HE properties of 12Cr2Mo1R(H) steel by slow strain rate tests. Meanwhile, the effect of hydrogen on the structures and the mechanical properties of the simplified models of the steel was also investigated by first-principle calculations.

Findings

Experimental results showed that after hydrogen pre-charging in this work, hydrogen had little effect on the microstructure of the steel. The elongations and reduction of cross-sectional area of the samples reduced a lot, by contrast, the yield and tensile strengths changed slightly. The 12Cr2Mo1R(H) steel was not very susceptible to HE with a maximum embrittlement index of about 20.00%. First principles calculation results showed that after H dissolution, lattice distortion occurred and interstitial H atoms would preferentially occupy the tetrahedral interstitial site in bcc-Fe crystal and increase the stability of the supercells. With the increase of H atoms added into the simplified model, the steel still possessed a good ductility and toughness at a low hydrogen concentration, while the material would become brittle as the concentration of hydrogen continued to increase.

Originality/value

These finds can provide valuable information for subsequent HE studies on this steel.

Details

Anti-Corrosion Methods and Materials, vol. 67 no. 6
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 9 August 2019

Kun Zhang, Yicheng Fan, Xiaowei Luo, Xiaolang Chen, Chaolei Ban, Heming Zhao and Yiqing Chen

12Cr2Mo1R(H) steel is commonly used to make hot-wall hydrogenation reactors given its excellent mechanical properties and hydrogen embrittlement (HE) resistance. Longtime exposure…

225

Abstract

Purpose

12Cr2Mo1R(H) steel is commonly used to make hot-wall hydrogenation reactors given its excellent mechanical properties and hydrogen embrittlement (HE) resistance. Longtime exposure to high-pressure hydrogen at medium temperature would still severely damage the mechanical properties of the Cr-Mo steel with surface HICs caused by hydrogen adsorption and hydrogen uptake. The mechanisms of HE remain controversial and have not been fully understood so far.

Design/methodology/approach

The HE of the steel was investigated by slow strain rate test at different strain rates with in situ hydrogen charging. The diffusion coefficient of hydrogen in the steel is measured by electrochemical technology of hydrogen permeation. HIC cracks of the fractured specimens were captured with field emission SEM equipped with an electron backscatter diffraction system.

Findings

Results showed that the hydrogen led to the plasticity of the samples reduced significantly, together with the distinct work hardening behavior induced by hydrogen charging during plastic flow stage. The fracture of in situ charged sample changes from quasi-cleavage to intergranular fracture with the decreasing of strain rates, which indicates that the steel become more susceptible to hydrogen. High densities of dislocations and deformation are found around the crack, where grains are highly sensitive to HIC. Grains with different Taylor factor are more susceptible to intergranular crack.

Originality/value

The results of the study would be helpful to a safer application of the steel.

Details

Anti-Corrosion Methods and Materials, vol. 66 no. 5
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 5 May 2015

Zhiling Peng and Heming Zhao

– An engine component made from 1Cr18Ni9Ti alloy to be used underwater was the subject of the present research investigation.

Abstract

Purpose

An engine component made from 1Cr18Ni9Ti alloy to be used underwater was the subject of the present research investigation.

Design/methodology/approach

A stereomicroscope, a metallurgical microscope, a microhardness tester and an electron energy dispersion spectroscope were used to observe cross-sections of the alloy’s microstructure at different locations, as well as its overall corrosion behavior.

Findings

The corrosion of the 1Cr18Ni9Ti alloy, attributed to welding, cold processing and plastic deformation processes, was investigated together with an analysis of the chemical composition of the corrosion products and microsclerometry of the cross-sections. It was revealed that defects such as shrinkage cavities and porosity, often were observed to occur in the welding fusion zone. During cold processing treatments, work hardening was induced in the surface layer. Corrosion products consisted of oxides, chlorides and sulfides, with oxides as the dominant component. The high chromium content of d-ferrite had resulted in chromium depletion in nearby phase boundaries, which had led to oxidation and corrosion at these boundaries. As the electrode potential of d-ferrite is different to that of austenite, it is possible for a galvanic couple to develop between the two phases, leading to differential rates of corrosion attack.

Originality/value

Methods are proposed to improve corrosion resistance by improving the quality of the surface overlaying processes and by adopting special surface treatment techniques.

Details

Anti-Corrosion Methods and Materials, vol. 62 no. 3
Type: Research Article
ISSN: 0003-5599

Keywords

Article
Publication date: 17 September 2024

Wanfeng Zhu, Petia Venkova Sice, Wenchun Zhang, Krystyna Krajewska and Zhangyang Zhao

The purpose of this paper is to bring into the public domain converging ways of thinking about reality and human systems, exploring parallels between the theory of Physical Vacuum…

Abstract

Purpose

The purpose of this paper is to bring into the public domain converging ways of thinking about reality and human systems, exploring parallels between the theory of Physical Vacuum and the concept of Qi in Medical Qigong science.

Design/methodology/approach

The approach adopted in this paper includes: review of the relevant literature; dialogues between the first two authors over an eight-month period; review of the findings and discussion of interpretations by all.

Findings

There is evidence for the existence of an ideal information field. This field is a real space-time torsion structure. Qi is a torsion field. It spreads with superluminal velocity and connects the whole Universe. Any entity is in a constant dynamic connection with everything else in the Universe.

Research limitations/implications

This paper offers limited discussion of the wider area of scientific discoveries.

Social implications

The findings may impact future interdisciplinary research, health/well-being practices and public policy.

Originality/value

There is no known to us publication interpreting the parallels between the theory of the Physical Vacuum and the concept of Qi.

Details

Kybernetes, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0368-492X

Keywords

Article
Publication date: 5 July 2023

Yanmei Xu, Yanan Zhang, Ziqiang Wang, Xia Song, Zhenli Bai and Xiang Li

Unlike traditional industries, the e-cigarette is an epoch-making innovative product originating in China and occupying an absolute competitive advantage in the international…

Abstract

Purpose

Unlike traditional industries, the e-cigarette is an epoch-making innovative product originating in China and occupying an absolute competitive advantage in the international market. The traditional A-U model describes the laws and characteristics of technological innovation in developed countries. In contrast, the inverse A-U model depicts the process of “secondary innovation” in late-developing countries through digestion and absorption. This paper aims to find out that if the e-cigarette, as a “first innovation” industry in a late-developing country, conform to the A-U model or conform to the “inverse A-U model”.

Design/methodology/approach

This paper takes the patent data of e-cigarettes from 2004 to 2021 as the research object, and uses Python’s Jieba segment words to divide product innovation and process innovation, and then uses statistical analysis methods to conduct empirical analyses on these data.

Findings

Thus, an improved A-U model suitable for the e-cigarette industry is proposed. In this model, product innovation in the e-cigarette industry appeared earlier than process innovation, but the synchronous development of product and process innovation is not lagging. The improved A-U model in the e-cigarette industry is not only different from the traditional A-U model but also does not conform to the inverse A-U model.

Research limitations/implications

It is conducive to expanding and clarifying the theoretical contribution and applicable boundaries of the A-U model and has sparked thinking and exploration of the A-U model in e-cigarettes and emerging industries.

Practical implications

On this basis, suggestions on the development path and countermeasures of the e-cigarette industry are put forward.

Originality/value

Based on the e-cigarette industry, this paper takes patents as the research object and provides the method of dividing product innovation and process innovation, and proposes an A-U model suitable for the e-cigarette industry on this basis. By comparing the traditional A-U model with the inverse A-U model in latecomer countries, the background and causes of e-cigarette A-U model heterogeneity are analyzed from different stages and overall morphology. Based on this, the heterogeneity characteristics of e-cigarette innovation are summarized and sorted out.

Details

Nankai Business Review International, vol. 15 no. 2
Type: Research Article
ISSN: 2040-8749

Keywords

Article
Publication date: 16 July 2024

Keng-Chieh Yang

This study uses big data analysis aimed at discovering city bus passenger ridership patterns. Hence, marketing managers can get sufficient insights to formulate effective business…

Abstract

Purpose

This study uses big data analysis aimed at discovering city bus passenger ridership patterns. Hence, marketing managers can get sufficient insights to formulate effective business plans and make timely decisions about company operations.

Design/methodology/approach

This study uses a mixed-method analysis to analyze the results. First uses the RFM (recency, frequency, and monetary) model combined with a big data technique (K-means) to analyze bus passenger boarding behavior. In order to improve the validity and quality of the research, this study also conducted interviews with senior managers of the bus company from which the data was obtained.

Findings

The study identifies six distinct groups of passengers with different boarding behaviors, ranging from “general passengers” to “most valuable passengers”. General passengers constituted the largest group. As such, they should be the main target for municipal governments when promoting bus ridership as part of energy conservation and carbon-reduction activities. This group of passengers should be encouraged to take public transport vehicles more, instead of relying on personal vehicles. The fourth group identified included elderly passengers with hospitals as their destinations. Bus companies can cooperate with municipal government to provide morning “medical bus” services for the elderly. Interviews with bus company managers confirmed that the analytical results of this study correspond with the observations, experiences, and actual business operating plans of bus companies.

Originality/value

Only few studies have analyzed passengers' boarding behavior applying a mixed-method analysis.

Details

Kybernetes, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0368-492X

Keywords

Article
Publication date: 6 September 2024

Esmat Taghipour Anari, Seyed Hessameddin Zegordi and Amir Albadvi

This paper aims to determine the type of supplier involvement in terms of time and extent of supplier involvement in automobile product development based on the characteristics of…

Abstract

Purpose

This paper aims to determine the type of supplier involvement in terms of time and extent of supplier involvement in automobile product development based on the characteristics of parts in the Iranian automotive industry.

Design/methodology/approach

The paper proposes the clustering and analytic hierarchy process (AHP) methods. Combining the K-means clustering method and metaheuristic algorithms, the genetic algorithm (GA) and particle swarm optimization (PSO) algorithm are applied to achieve better clustering results.

Findings

The results show that lack of internal knowledge, high technology change and complexity of parts increase the need to outsource the design process. In addition to these reasons, high development costs and high interface complexity justify suppliers’ early involvement.

Originality/value

Most research only presents a conceptual framework for understanding the various levels of supplier involvement in new product development (NPD). However, in the automotive industry, numerous parts have differing degrees of importance and priority, and experts may have varying opinions based on different criteria. Therefore, the existing conceptual model for analyzing the types of involvement of each supplier is not practical. We have formulated a problem-solving approach that utilizes the clustering and AHP methods to analyze data obtained from qualitative research and determine the type of supplier involvement.

Details

Journal of Advances in Management Research, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0972-7981

Keywords

Article
Publication date: 10 November 2020

Azmat Ullah, Muhammad Ayat, Hakeem Ur Rehman and Lochan Kumar Batala

The purpose of this paper is to develop a model that determines whether how much effort of preventive maintenance action is worthwhile for the consumer over the post-sale product…

Abstract

Purpose

The purpose of this paper is to develop a model that determines whether how much effort of preventive maintenance action is worthwhile for the consumer over the post-sale product life cycle of a repairable complex product where the product is under warranty and subject to stochastic multimode failure process, that is, damaging failure and light failure with different probabilities.

Design/methodology/approach

The expected life cycle cost is designed for a warranted product from the consumer perspective. The product failure is quantified with failure rate function, which is the number of failures incurred over the product life cycle. The authors consider the failure rate function reduction method in their model where the scale parameter of a failure rate function is maximized by applying the optimal preventive maintenance level. The scale parameter of any failure distribution refers to the meantime to failure (MTTF). The first-order condition is applied with respect to the maintenance level in order to achieve the convexity of the nonlinear function of the expected life cycle cost function.

Findings

The authors have found analytically the close form of the preventive maintenance level, which can be used to find the optimal reduced form of the failure rate function of the product and the minimum product expected life cycle cost under the given condition of multimode stochastic failure process. The authors have suggested different maintenance policies to consumers in order to implement the proposed preventive maintenance model under different conditions. A numerical example further illustrated the analytical model by considering the Weibull distribution.

Practical implications

The consumer may use this study in the accurate modeling of the life cycle cost of a product that is under warranty and fails with a multimode failure process. Also, the suggested preventive maintenance approach of this study helps the consumer in making appropriate maintenance decisions such as to minimize the expected life cycle cost of a product.

Originality/value

This study proposes an accurate estimation of a life cycle cost for a product that is under the support of warranty and fails with multimode. Furthermore, for such a kind of product, which is under warranty and fails with multimode, this study suggests a new preventive maintenance approach that assures the minimum expected life cycle cost.

Details

International Journal of Quality & Reliability Management, vol. 38 no. 5
Type: Research Article
ISSN: 0265-671X

Keywords

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