Studies on synthesized nontoxic corrosion inhibitors for N80 steel in hydrochloric acid

Abstract

Purpose

The purpose of this investigation was to evaluate the protective ability of 2-amino-N-octadecylacetamide (AOA) and 2-amino-N-octadecyl-3-(4-hydroxyphenyl) propionamide (AOHP) as corrosion inhibitors for N80 steel in 15 per cent hydrochloric acid (HCl), which may find application as eco-friendly corrosion inhibitors in acidizing processes in the petroleum industry. Due to scale plugging in the well bore, there can be a decline in the crude production rate, and an acidization operation has to be carried out, normally by using 15 per cent HCl to remove the scale plugging. To reduce the aggressive attack of HCl on tubing and casing materials (N80 steel), inhibitors are added to the acid solution during the acidifying process.

Design/methodology/approach

Different concentrations of the synthesized inhibitors AOA and AOHP were added to the test solution (15 per cent HCl), and the corrosion inhibition efficiencies of these inhibitors for N80 steel were calculated from weight loss determinations, potentiodynamic polarization scans and alternating current (AC) impedance measurements. The influence of temperature (298-323 K) on the inhibition behavior was studied. Surface examinations were performed by means of Fourier transform infrared spectra and scanning electron microscope.

Findings

AOA and AOHP at 150-ppm concentration showed a maximum efficiency of 90.04 and 94.97 per cent, respectively, at 298 K in 15 per cent HCl solution. Both the inhibitors acted as mixed corrosion inhibitors. The adsorption of the corrosion inhibitors at the surface of the N80 steel was the underlying mechanism of corrosion inhibition.

Originality/value

This paper reports the preliminary laboratory results of inhibitors AOA and AOHP for the corrosion prevention of N80 steel casings and tubulars exposed to HCl and may be of practical help to petroleum engineers for carrying out acidization in oil wells after further investigation of the compound at higher temperature.

Citation

Yadav, M., Kumar, S. and Sharma, D. (2014), "Studies on synthesized nontoxic corrosion inhibitors for N80 steel in hydrochloric acid", Anti-Corrosion Methods and Materials, Vol. 61 No. 3, pp. 129-138. https://doi.org/10.1108/ACMM-12-2012-1225