The influence of the solubility of zinc phosphate pigments on their anticorrosive behaviour

Abstract

The objective of this work was to study the anticorrosive behaviour of three commercial pigments containing micronized zinc phosphate. The chemical analyses of the pigments were carried out in the laboratory to characterise them with respect to their composition and soluble matter. It was proposed to check pigments’ efficiency in solvent‐borne paints with 30 per cent v/v of the pigment by volume and a pigment volume concentration/critical pigment volume concentration ratio (PVC/CPVC) equal to 0.8. The behaviour of paints formulated with two binders (alkyd and epoxy) was assessed by accelerated (salt spray cabinet, humidity chamber and accelerated weathering) and electrochemical (corrosion potential, ionic resistance and polarisation resistance) tests. It was demonstrated that pigment performance is highly influenced by their solubility which, in turn, could influence the formation of the protective layer on the metal substrate. Good correlation was obtained between salt spray and electrochemical tests.

Citation

Blustein, G., del Amo, B. and Romagnoli, R. (2000), "The influence of the solubility of zinc phosphate pigments on their anticorrosive behaviour", Pigment & Resin Technology, Vol. 29 No. 2, pp. 100-107. https://doi.org/10.1108/03699420010319148