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1 – 3 of 3Hang Jia, Zhiming Gao, Shixiong Wu, Jia Liang Liu and Wenbin Hu
This study aims to investigate the corrosion inhibitor effect of migrating corrosion inhibitor (MCI) on Q235 steel in high alkaline environment under cathodic polarization.
Abstract
Purpose
This study aims to investigate the corrosion inhibitor effect of migrating corrosion inhibitor (MCI) on Q235 steel in high alkaline environment under cathodic polarization.
Design/methodology/approach
This study investigated the electrochemical characteristics of Q235 steel with and without MCI by polarization curve and electrochemical impedance spectroscopy. Besides, the surface composition of Q235 steel under different environments was analyzed by X-ray photoelectron spectroscopy. In addition, the migration characteristic of MCI and the adsorption behavior of MCI under cathodic polarization were studied using Raman spectroscopy.
Findings
Diethanolamine (DEA) and N, N-dimethylethanolamine (DMEA) can inhibit the increase of Fe(II) in the oxide film of Q235 steel under cathodic polarization. The adsorption stability of DMEA film was higher under cathodic polarization potential, showing a higher corrosion inhibition ability. The corrosion inhibition mechanism of DEA and DMEA under cathodic polarization potential was proposed.
Originality/value
The MCI has a broad application prospect in the repair of damaged reinforced concrete due to its unique migratory characteristics. The interaction between MCIs, rebar and concrete with different compositions has been studied, but the passivation behavior of the steel interface in the presence of both the migrating electric field and corrosion inhibitors has been neglected. And it was investigated in this paper.
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Gang Wang, Mian Wang, ZiHan Wang, GuangTao Xu, MingHao Zhao and Lingxiao Li
The purpose of this paper is to assess the hydrogen embrittlement sensitivity of carbon gradient heterostructure materials and to verify the reliability of the scratch method.
Abstract
Purpose
The purpose of this paper is to assess the hydrogen embrittlement sensitivity of carbon gradient heterostructure materials and to verify the reliability of the scratch method.
Design/methodology/approach
The surface-modified layer of 18CrNiMo7-6 alloy steel was delaminated to study its hydrogen embrittlement characteristics via hydrogen permeation, electrochemical hydrogen charging and scratch experiments.
Findings
The results showed that the diffusion coefficients of hydrogen in the surface and matrix layers are 3.28 × 10−7 and 16.67 × 10−7 cm2/s, respectively. The diffusible-hydrogen concentration of the material increases with increasing hydrogen-charging current density. For a given hydrogen-charging current density, the diffusible-hydrogen concentration gradually decreases with increasing depth in the surface-modified layer. Fracture toughness decreases with increasing diffusible-hydrogen concentration, so the susceptibility to hydrogen embrittlement decreases with increasing depth in the surface-modified layer.
Originality/value
The reliability of the scratch method in evaluating the fracture toughness of the surface-modified layer material is verified. An empirical formula is given for fracture toughness as a function of diffused-hydrogen concentration.
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Dongyang Li, Guanghu Yao, Yuyuan Guan, Yaolei Han, Linya Zhao, Lining Xu and Lijie Qiao
In this paper, the authors aim to study the effect of hydrogen on the pitting corrosion behavior of Incoloy 825, a commonly used material for heat exchanger tubes in hydrogenated…
Abstract
Purpose
In this paper, the authors aim to study the effect of hydrogen on the pitting corrosion behavior of Incoloy 825, a commonly used material for heat exchanger tubes in hydrogenated heat exchangers.
Design/methodology/approach
The pitting initiation and propagation behaviors were investigated by electrochemical and chemical immersion experiments and observed and analyzed by scanning electron microscope and energy dispersive spectrometer methods.
Findings
The results show that hydrogen significantly affects the electrochemical behavior of Incoloy 825; the self-corrosion potential decreased from −197 mV before hydrogen charging to −263 mV, −270 mV and −657 mV after hydrogen charging, and the corrosion current density increased from 0.049 µA/cm2 before hydrogen charging to 2.490 µA/cm2, 2.560 µA/cm2 and 2.780 µA/cm2 after hydrogen charging. The pitting susceptibility of the material increases.
Originality/value
Hydrogen is enriched on the precipitate, and the pitting corrosion also initiates at that location. The synergistic effect of hydrogen and precipitate destroys the passive film on the metal surface and promotes pitting initiation.
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