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Article
Publication date: 12 March 2019

L. Sulaiman, Z.H.Z. Abidin, S.A.M. Yunus, N.A. Mazni, A.N. Hadi, A.K. Arof and K. Simarani

This paper aims to discuss about the benefits of Cu(NO3)2 applied in coating paint film that consists of plant extract from Cassia Alata. Cu(NO3)2 has been added to the coating

Abstract

Purpose

This paper aims to discuss about the benefits of Cu(NO3)2 applied in coating paint film that consists of plant extract from Cassia Alata. Cu(NO3)2 has been added to the coating paint film as a colour stabilizer and as an antifungal property by forming a zone of inhibition towards fungal growth.

Design/methodology/approach

The coating paint film resin consists of a mixture of poly (methyl methacrylate) (PMMA) and acrylic polyol. The coating paint film’s performances were observed in terms of visible optical and physical appearance.

Findings

When exposed to the fungus Trichoderma Sp., a zone of inhibition of 208 mm2 was formed around the coating paint film and therefore it gave the coating paint films an antifungal property. The commission internationale de l’éclairage (CIE) L*a*b* colour coordinate system was used to identify the colour changes in the coating paint film and it was found that the addition of Cu(NO3)2 to the coating paint film has a better colour stability, as it has a lower standard deviation (STD) value of 6.46 than the pure dye coating paint film of 8.95. The gloss of coating paint film with the addition of Cu(NO3)2 was found to be have a more stable gloss based on its smaller STD value at both angles taken at 20° and 60°.

Research limitations/implications

The Cassia Alata plant has different amount of antifungal properties based on location its growth.

Practical implications

The coating paint film developed in this study is suitable for indoor applications.

Originality/value

The plant extract from the Cassia Alata gives the coating paint film an antifungal property.

Details

Pigment & Resin Technology, vol. 50 no. 2
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 15 June 2020

L. Sulaiman, Z.H.Z. Hazrin, N.I.M. Zakir, N.A. Halim, R.A.A. Rusdi, A.S.A. Khair and H.A. Tajuddin

The effect of using microcrystalline cellulose (MCC) as an additive in coating paint films for non-stick coatings was studied in this work. This paper aims to discuss the benefits…

Abstract

Purpose

The effect of using microcrystalline cellulose (MCC) as an additive in coating paint films for non-stick coatings was studied in this work. This paper aims to discuss the benefits of MCC blended in the coating paint film that consists of poly(methyl methacrylate) (PMMA) and dammar.

Design/methodology/approach

PMMA and dammar mixed at a specific Wt.% ratio with xylene as its solvent. Two sets of mixtures were prepared, where one mixture contained MCC and another, without. The mixtures were applied to metal substrates as coating paint films. The performance of the non-stick coating paint film was observed through the adhesive test between adhesion layers on the coating paint film and also through the cross-hatch test for the adhesion of the non-stick coating paint film to the metal substrate. The results correlate with the surface roughness and glossiness tests.

Findings

The results showed that for the coating paint films, Sample B consisted of 80:20 Wt.% ratio of PMMA-dammar with an addition of 5 Wt.% MCC had an excellent performance as non-stick coating paint films. The MCC formed microparticles on the surface of the coating paint film sample and this causes the coating paint film samples with MCC to develop a rougher surface compared to the coating paint film without MCC. Sample B coating paint film had the highest average surface roughness (Ra) of 383 µm. The cross-hatch test showed the coating paint film with the addition of MCC had stronger adhesiveness on the substrate’s surface thus prevents the coating from peeling off from the surface.

Practical implications

The developed coating paint film in this study would be suitable for outdoor applications to prevent illegal advertisements and stickers.

Originality/value

MCC added to the coating paint film improves the surface performance as a non-stick coating.

Details

Pigment & Resin Technology, vol. 49 no. 5
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 30 December 2020

Amruta Joglekar-Athavale, Ganapati Shankarling, Satishchandra Dubey, Vinita Deshpande, Bikashkumar Jaiswal and Arun Nayak

The spectrally selective solar absorption paint is prepared from spinel-based mixed metal oxides with inorganic binder as a key component. Inorganic binder (furnace cement) is…

Abstract

Purpose

The spectrally selective solar absorption paint is prepared from spinel-based mixed metal oxides with inorganic binder as a key component. Inorganic binder (furnace cement) is blended with mixed metal oxide pigment during synthesis. High temperature stability upto 1,100ºC is achieved by the use of this modified coating system. The purpose of this paper is to work on solar selective coating synthesis, and application of a coating as a water-borne paint is the additive key feature that helps in reduction of solvent use.

Design/methodology/approach

The paint was formulated using water-based system, and the main component of colorant was made by mixed metal oxide–based spinel pigment and highly temperature stable inorganic binder.

Findings

The paint formed shows excellent absorptive power with low emittance even at high temperature. Optical and thermal properties were determined along with adhesion, abrasion and other properties. The solar absorptance for these samples were as = 0.93–0.95 with corresponding thermal emittance of eT = 0.096 (at room temperature) and 0.2–0.22 (at elevated temperature 100°C).

Originality/value

The paint formed shows excellent absorptive power with low emittance even at high temperature. The paint can be applied in solar absorptive tower system. The obtained results indicated excellent thermal stability of prepared paint coatings. As inorganic binder was used, the paint has reduction in solvent use, and being water as a base, it is environment friendly, easy to apply and durable at high temperatures, as the binder itself is stable up to 1,500ºC.

Details

Pigment & Resin Technology, vol. 50 no. 4
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 1 April 1995

Powder coating in the car industry. “The future for powder coatings in the car industry is bright”, Chrysler Corporation's Ernie McLaughlin said in the keynote address at the…

Abstract

Powder coating in the car industry. “The future for powder coatings in the car industry is bright”, Chrysler Corporation's Ernie McLaughlin said in the keynote address at the recent Powder Coating '94 in Cincinnati.

Details

Pigment & Resin Technology, vol. 24 no. 4
Type: Research Article
ISSN: 0369-9420

Article
Publication date: 29 May 2007

A. Kalendová, D. Veselý and P. Kalenda

To synthesise calcium titanate with a perovskite structure as an anticorrosion pigment for metal protecting paints.

Abstract

Purpose

To synthesise calcium titanate with a perovskite structure as an anticorrosion pigment for metal protecting paints.

Design/methodology/approach

Calcium titanate was synthesised from titanium dioxide and calcium carbonate at high temperature. The pigment obtained was characterised by means of X‐ray diffraction, particle size distribution measurement and scanning electron microscopy. The pigment obtained was further characterised with regard to the parameters required for paint formulation; its specific mass was determined by oil consumption and critical pigment volume concentration. The synthesised calcium titanate was used to prepare epoxy coatings with varying contents of the anticorrosion pigment. The coating was tested for physical‐mechanical properties and in corrosive atmospheres. The results were compared with titanium dioxide that served as a starting material for calcium titanate preparation.

Findings

Calcium titanate was prepared from materials that do not add any impurities to the anticorrosion properties of the pigment. It was identified that calcium titanate of perovskite structure is a highly efficient anticorrosion pigment for paints.

Practical implications

Calcium titanate can be utilised for the preparation of anticorrosion paints to protect metal bases from corrosion.

Originality/value

The method of synthesising calcium titanate as an anticorrosion pigment is new. The literature has not yet described the use of calcium titanate as a pigment with inhibitive properties in paints. From an ecologic standpoint, the application of a new anticorrosion pigment for paints presents a highly positive trend.

Details

Pigment & Resin Technology, vol. 36 no. 3
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 15 March 2013

Z.H.Z. Abidin, K.M. Nasir, S.K.M. Jamari, N. Saidon, S.V. Lee, N.A. Halim and R. Yahya

The purpose of this work is to investigate the correlation characteristics in mechanical, thermal and optical properties of PMMA‐acrylic polyol polymer blends mixed with lawsone…

Abstract

Purpose

The purpose of this work is to investigate the correlation characteristics in mechanical, thermal and optical properties of PMMA‐acrylic polyol polymer blends mixed with lawsone natural dye for coating paint application.

Design/methodology/approach

Natural brownish dye colorant was extracted from Lawsonia Inermis leaves used as a dye colorant in this paint coating system by using ethanol as the solvent. Poly(methyl methacrylate) (PMMA), blended with acrylic polyol was used as the binder system. The ratio of PMMA to acrylic polyol was varied with PMMA dominance. The dye colorant was fixed at 10 wt percent.

Findings

The potential time measurement tests showed that the dye colorant paint system with 10 wt percent of acrylic polyol has the highest coating resistance against electrolyte penetration. The dye colorant paint system with 30 wt percent acrylic polyol performed better in mechanical tests such as cross‐hatch and impact resistance. The dye colorant paint system molecular crosslinks were analysed by using the fourier transform infrared spectroscopy (FTIR) and X‐ray diffraction spectroscopy.

Research limitations/implications

The ratio of lawsone dye colorant in the polymer blends is found limited to 10 percent. Increasing in the percentage of lawsone dye colorant will cause inhomogeneity in coating paint sample.

Originality/value

A new formulation of natural dye colorant paint system with 10 percent wt dye volume concentration of lawsone as pigment was obtained.

Details

Pigment & Resin Technology, vol. 42 no. 2
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 1 February 1994

Making Fine Powders ‐ Extremely fine and uniform particles, of 5–50 nanometers, have been produced by a process being developed at Battelle Pacific Northwest Laboratories…

Abstract

Making Fine Powders ‐ Extremely fine and uniform particles, of 5–50 nanometers, have been produced by a process being developed at Battelle Pacific Northwest Laboratories. Researchers have used the technique to synthesize new, highly dispersed catalysts with a high surface area. It offers a way to make other products which have improved properties: ceramic ball bearings and gears which are stronger and more durable than those available today, and pigments for paints and inks.

Details

Pigment & Resin Technology, vol. 23 no. 2
Type: Research Article
ISSN: 0369-9420

Article
Publication date: 1 September 1974

Americus

The paint industry is always intrigued by speciality coatings. Literally thousands of paint formulations have been devised over the years with highly specialized and very…

Abstract

The paint industry is always intrigued by speciality coatings. Literally thousands of paint formulations have been devised over the years with highly specialized and very frequently intriguing functions. In this latter category is a process described in Japanese patent 19,790 (1971) for painting polka dots upon sheet metal. How often the need for such technology might arise in the life of the average paint chemist is, of course, a moot question. But some comfort can no doubt be drawn from the fact that this unique methodology exists!

Details

Pigment & Resin Technology, vol. 3 no. 9
Type: Research Article
ISSN: 0369-9420

Article
Publication date: 15 March 2013

Z.H.Z. Abidin, N.N. Naziron, K.M. Nasir, M.S. Rusli, S.V. Lee, M.Z. Kufian, S.R. Majid, B. Vengadaesvaran, A.K. Arof, R.M. Taha and R. Yahya

The purpose of this work is to investigate the influence of curcumin dye natural colorant on adhesion, mechanical, thermal and electrochemical properties of blend poly (methyl…

Abstract

Purpose

The purpose of this work is to investigate the influence of curcumin dye natural colorant on adhesion, mechanical, thermal and electrochemical properties of blend poly (methyl methacrylate) (PMMA) – acrylic polyol.

Design/methodology/approach

Extracted curcumin yellow dye colorant from Curcuma Demostica was mixed with PMMA‐acrylic polyol blended polymer in the volume ratios of 9:1, 8:2 and 7:3. The mixtures were applied on pre‐treated cold‐roll mild steel panels. All of the paint coating samples were subjected to potential time measurement (PTM), rapid impact deformation, differential scanning calorimetry (DSC), cross hatch and Fourier transform infrared spectroscopy (FTIR) tests.

Findings

The addition of curcumin dye colorant was able to improve the adhesion, flexibilities and resistance against electrolytes penetration of the blended poly (methyl methacrylate) (PMMA) – acrylic polyol polymer paint system. Cross hatch test studies showed that high amount of curcumin dye colorant (AP30 paint system) had the lowest peel‐off coating area from the substrate. The FTIR test had confirmed the high concentration of hydroxyl group in the AP30 sample. The hydroxyl group was able to promote hydrogen bonding between coating substrate interface. The AP30 sample had the highest coating flexibilities when tested with rapid impact test. This was due to the lowest glass transition value Tg which indicated lowest cross linking density in the coating molecules structure. In the PTM test, AP30 paint system had shown the highest rate electrolytes penetration within the AP sample.

Research limitations/implications

The composition of curcumin dye colorant in the polymer blend is limited from 10 percent to 30 percent pigment volume concentration. Increasing the amount of lawsone pigment will result inhomogeneous mixtures.

Originality/value

The AP paint system is suitable for interior applications. This paint system has to be mixed with suitable additive materials to improve its performance for exterior purpose.

Details

Pigment & Resin Technology, vol. 42 no. 2
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 1 March 1975

Americus

The coatings industry is in large measure a function of the world around it. Advances in related disciplines are scrutinised carefully by coatings chemists because of the…

Abstract

The coatings industry is in large measure a function of the world around it. Advances in related disciplines are scrutinised carefully by coatings chemists because of the ramifications that these new discoveries and inventions may have if applied directly to the coatings area. This is certainly true relative to new resins and other raw materials. It applies also to the development of new energy forms which reflect themselves in new ways to cure coatings. Accordingly, some of these newer advances which could eventually have important ramifications in the coatings industry will be reviewed here.

Details

Pigment & Resin Technology, vol. 4 no. 3
Type: Research Article
ISSN: 0369-9420

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