Search results

This study aims to prepare an imprinted composite membrane with grafted temperature-sensitive blocks for the efficient adsorption and separation of rhenium(Re) from aqueous solutions.

PVDF resin membrane was used as the substrate, dopamine and chitosan (CS) were used to modify the membrane surface and temperature-sensitive block PDEA was grafted on the membrane surface. Then acrylic acid (AA) and N-methylol acrylamide (N-MAM) were used as the functional monomers, ethyleneglycol dimethacrylate (EGDMA) as the cross-linker and ascorbic acid-hydrogen peroxide (Vc-H₂O₂) as the initiator to obtain the temperature-sensitive ReO4⁻ imprinted composite membranes.

The effect of the preparation process on the performance of CS–Re–TIICM was investigated in detail, and the optimal preparation conditions were as follows: the molar ratios of AA–NH₄ReO₄, N-MAM and EGDMA were 0.13, 0.60 and 1.00, respectively. The optimal temperature and time of the reaction were 40 °C and 24 h. The maximum adsorption capacity of CS–Re–TIICM prepared under optimal conditions was 0.1071 mmol/g, and the separation was 3.90 when MnO4⁻ was used as the interfering ion. The quasi first-order kinetics model and Langmuir model were more suitable to describe the adsorption process.

With the increasing demand for Re, the recovery of Re from Re-containing secondary resources becomes important. This study demonstrated a new material that could be separated and recovered Re in a complex environment, which could effectively alleviate the conflict between the supply and demand of Re.

This contribution provided a new material for the selective separation and purification of ReO4⁻, and the adsorption capacity and separation of CS–Re–TIICM were increased with 1.673 times and 1.219 time compared with other Re adsorbents, respectively. In addition, when it was used for the purification of NH₄ReO₄ crude, the purity was increased from 91.950% to 99.999%.

This study aims to present a sustainable approach in the natural dyeing of cellulose fabric followed by nanosilver finishing through a green crosslinker of citric acid for potential antibacterial surgical gown fabrication.

The nanosilver finish was reproduced using the chemical reduction method. The fabric dyeing was performed on a lab-scale dyeing machine, whereas silver nano-finishing through a pad-dry-cure approach. Citric acid was used as an eco-friendly crosslinker. The specimens were characterized for antibacterial activity, surface chemical, textile, color properties and finish release trend.

The results demonstrated the successful application of curcumin dye followed by silver nano-finishing. The resultant fabric exhibited appropriate textile, dyeing performance indicators, hydrophobic behavior and sustainable broad-spectrum antibacterial activity.

The prepared nanosilver-finished/curcumin-treated fabric expressed desirable properties for potential applications in the fabrication of surgical gowns.

The authors found no reports on an extensive examination of nanosilver finishing on the color parameters of curcumin-dyed cellulose fabric while retaining its textile and comfort properties for possible surgical gown fabrication.

The purpose of this paper is to study and analyze the effects of fly ash (FA) as a mineral admixture on compressive strength (CS), carbonation resistance and corrosion resistance of reinforced concrete (RC). In addition, the utilization of inexpensive and abundantly available FA as a cement replacement in concrete has several benefits including reduced OPC usage and elimination of the FA disposal problem.

Reinforcement corrosion and carbonation significantly affect the strength and durability of the RC structures. Also, the utilization of FA as green corrosion inhibitors, which are nontoxic and environmentally friendly alternatives. This review discusses the effects of FA on the mechanical characteristics of concrete. Also, this review analyzes the impact of FA as a partial replacement of cement in concrete and its effect on the depth of carbonation in concrete elements and the corrosion rate of embedded steel as well as the chemical composition and microstructure (X-ray diffraction analysis and scanning electron microscopy) of FA concrete were also reviewed.

This review provides a clear analysis of the available study, providing a thorough overview of the current state of knowledge on this topic. Regarding concrete CS, the findings indicate that the incorporation of FA often leads to a loss in early-age strength. However, as the curing period increased, the strength of fly ash concrete (FAC) increased with or even surpassed that of conventional concrete. Analysis of the accelerated carbonation test revealed that incorporating FA into the concrete mix led to a shallower carbonation depth and slower diffusion of carbon dioxide (CO₂) into the concrete. Furthermore, the half-cell potential test shows that the inclusion of FA increases the durability of RC by slowing the rate of steel-reinforcement corrosion.

This systematic review analyzes a wide range of existing studies on the topic, providing a comprehensive overview of the research conducted so far. This review intends to critically assess the enhancements in mechanical and durability attributes (such as CS, carbonation and corrosion resistance) of FAC and FA-RC. This systematic review has practical implications for the construction and engineering industries. This can support engineers and designers in making informed decisions regarding the use of FA in concrete mixtures, considering both its benefits and potential drawbacks.

The objective of the research is to evaluate the carbon footprint of the green asparagus (Asparagus officinalis L.) supply chain, encompassing the agricultural production to the packaging stage in Italy, as it is the sixth largest producer and the second largest in Europe. It provides an assessment in the province of Foggia and highlights the global perspective of the carbon footprint application in agro-food systems.

The carbon footprint (ISO 14067:2018) considers 1 t of packaged fresh asparagus as a functional unit in the agricultural production and packaging stage and is based on primary data collected in one of the leading companies of asparagus production in the province of Foggia, which markets about 0.21 kt of asparagus per year produced in about 31 ha. Data were integrated with face-to-face in-depth interviews and pre-filled checklists.

Findings show that the carbon footprint of 1 t of packaged fresh asparagus is equivalent to 335.31 kgCO2eq, of which 61% in the agricultural stage and 39% in the packaging one. The majority of the emissions are associated with the fertigation and the diesel consumption for the transportation of workers. Farmers should adopt green electricity so as to reduce the emissions associated with the electric pump for the extraction of water from artesian wells. Moreover, it would be desirable to replace mineral urea phosphate with organic fertilizers.

To the best of the authors’ knowledge, scholars have not yet investigated the environmental impacts of the green asparagus supply chain, even if it represents one of the most cultivated vegetables worldwide, with a global production that amounts to 8.5 Mt per year.

The purpose of this paper is to examine the use of phragmites australis ash (PAA) in cementitious systems to achieve sustainable construction.

In this paper, the properties of mortar containing PAA as partial cement replacement are determined. The PAA is produced through slow burning in a closed system to minimize the CO₂ emission. A total of four mortar mixes are prepared with PAA replacement levels ranging from 0% to 30% by weight. The water to binder and the proportions of binder to sand are 0.55 and 1:3 by weight, respectively. The properties tested are density, compressive strength, flexural strength, ultrasonic pulse velocity, water absorption by total immersion and capillary rise. Testing is conducted at 1, 7, 28 and 90 days.

While there is a decrease in strength as the amount of PAA increases, there is strong indication of pozzolanic reaction in the presence of PAA. This is in agreement with the results reported by Salvo et al. (2015), where they found noticeable pozzolanic activities in the presence of straw ash, which is rich in SiO₂ and relatively high K₂O content. At 90 days of curing, there is a decrease of 5% in compressive strength at 10% PAA replacement. However, at 20% and 30% replacement, the reduction in compressive strength is 23% and 32%, respectively. The trend in flexural strength and ultrasonic pulse velocity is similar to that in compressive strength. The water absorption by total immersion and capillary rise tends to increase with increasing amounts of PAA in the mix. There seems to be a linear relationship between water absorption and compressive strength at each curing age.

The Phragmites australis plant used in this investigation is obtained from one location and this present a limitation as the type of soil may change the properties. Also one method of slow burning is used. Different burning methods may alter the composition of the PAA.

This outcome of this research will contribute towards sustainable development as it will make use of the waste generated, reduce the amount of energy-intensive cement used in construction and help generate local employment in the area where the Phragmites australis plant grows.

To the best knowledge of the authors, the ash from the Phragmites australis plant has not been used in cementitious system and this research can be considered original as it examines the properties of mortar containing PAA. Also, the process of burning in a closed system using this material.

This study aims to design and validate a decision support system (DSS), named preliminary risk assessment of brownfield sites (PRABS). It is intended that the proposed DSS will aid the identification of potential hazards and, in doing so, highlight challenges facing those stakeholders dealing with the decision-making on brownfield site redevelopments, where the examples of diverse stakeholders would include, for instance, risk assessors, local planning authorities, regulator, developers, civil engineers, architectures, landowners, investors and alike. Moreover, the DSS will enable them to promote safer redevelopment and minimise the risks to future occupants of brownfield sites and neighbouring lands, on the top of the tool being communal platform of an effective communication between them as it is for both experts and non-experts.

This research employs a comprehensive five-stage process, integrating both quantitative and qualitative methods and utilizing mixed methods for a nuanced exploration of data. The initial stage involves an in-depth examination of contemporary risk assessment tools for contaminated sites, setting the foundation and benchmarks for subsequent stages. Stage two focuses on creating a conceptual framework using insights from existing literature to guide the development of the DSS tool. Stage three introduces a validation mechanism through a questionnaire administered to experts. Stage four involves the active development of the DSS tool, transforming theoretical constructs into a practical application. The final stage, stage five, employs quantitative data analysis and case studies to validate, refine and enhance the DSS tool’s applicability in real-world scenarios, ensuring its approval.

This study presents PRABS, a user-friendly DSS for the PRABS. Validation through a quantitative online survey indicates strong support for PRABS, with around 80% of participants willing to recommend it due to its ease of use and information quality. Qualitative data analysis using real-life case studies further demonstrates the tool’s effectiveness. PRABS proves valuable in identifying hazards during the preliminary stage, accurately predicting potential contaminants despite limited input data in the case studies. The tool’s hazard identification aligns well with expert judgments and case study reports, confirming its practical utility.

This study has several limitations. First, the DSS identifies only hazards associated with one layer of site geology, even though sites may include multiple layers, which limits the comprehensiveness of the hazard identification process. Second, adopting an online survey approach posed challenges in achieving a high response rate and gathering a representative sample, making it uncertain how the results might vary with a higher number of professional participants. This limitation affects the generalisability of the findings. Finally, while this study identified 65 potential hazards associated with brownfield sites, this number could be expanded to include hazards related to plants, animals and air, indicating the need for a more inclusive approach to hazard identification. Given these limitations, future research should focus on addressing these gaps.

The contributions of this study offer practical benefits. Firstly, it enables the initial risk assessment process to be more comprehensive and integrated and reduces complexity in the risk assessment process by ensuring that all probabilities, along with their significance, are identified at the initial stage of the risk assessment. This could be a strong starting point for successfully conducting a more detailed risk assessment and remediation. Secondly, the developed PRABS can promote effective environmental communication among stakeholders, which should speed up the planning process and help develop brownfield sites more efficiently and effectively, while preserving the natural environment.

Designing an efficient routing protocol that opportunistically forwards data to the destination node through nearby sensor nodes or devices is significantly important for an effective incidence response and disaster recovery framework. Existing sensor routing protocols are mostly not effective in such disaster recovery applications as the networks are affected (destroyed or overused) in disasters such as earthquake, flood, Tsunami and wildfire. These protocols require a large number of message transmissions to reestablish the clusters and communications that is not energy efficient and result in packet loss. This paper introduces ODCR - an energy efficient and reliable opportunistic density clustered-based routing protocol for such emergency sensor applications. We perform simulation to measure the performance of ODCR protocol in terms of network energy consumptions, throughput and packet loss ratio. Simulation results demonstrate that the ODCR protocol is much better than the existing TEEN, LEACH and LORA protocols in term of these performance metrics.

Consumers often prefer sustainable goods and services but fail to follow through with purchases that reflect these espoused values. The green intention–outcome gap is studied in many contexts but has yet to inform deathcare decisions. Industry reports suggest that most Americans prefer sustainable deathcare options, yet unsustainable corpse dispositions dominate the market. The purpose of this paper is to understand how history informs this phenonea.

This study looks to the past – using historical narrative analysis of deathcare trends and influential intermediaries – to understand the future of sustainable deathcare and the prospective role that marketers can play in bridging the gap between decedents’ preferences and survivors’ purchase outcomes.

Historical ritualization, medicalization and commercialization have resulted in the monopolization of traditional deathcare services. Mortuary professionals remain unresponsive to consumer preferences for sustainable alternatives.

Socioeconomic shocks can allow humanity to reflect and transition from consumerism to sustainability. COVID-19 has led to greater awareness of self-mortality, and death has become less taboo. The slow market penetration of sustainable deathcare services suggests a lack of communication between a decedent and their survivors. Marketing scholars need to help marketing practitioners bridge the preference-outcome gap.

To the best of the authors’ knowledge, this study is amongst the first to examine how history informs the sustainable action–outcome gap for deathcare preferences in a post-COVID environment and the role that marketers can play in perpetuating change.

The purpose of this study is to create sustainable additives for future vehicles, characterized by low levels of sulfated ash, sulfur and phosphorus (SAPS) or even SAPS-free alternatives. These newly developed additives must not only match or outperform the current commercial benchmarks in terms of tribological performance, but also align with the emerging sustainability trends. It is anticipated that this innovative technology will yield promising outcomes in the realm of hybrid and electric vehicles.

This research primarily focused on chemical synthesis, performance evaluation and characterizations. These aspects were studied through collaboration between Syensqo, Southwest Research Institute (the USA) and the Lab of the Future in France. The data was generated and analyzed by a team of research scientists, internship students and technical specialists.

Two types of additives have been specifically designed and synthesized in accordance with sustainable requirements. Both technologies have exhibited exceptional frictional and wear-resistant properties. Moreover, the leading candidates exhibit a lower rate of copper corrosion, stable electric conductivity and outstanding thermal stability when compared to commercial benchmarks. This study is expected to open a new research avenue for developing next-generation additives for lubricants, with wide potential applications including hybrid electric vehicle and electric vehicle markets.

In the current lubricant market, there is a lack of effective low-SAPS or SAPS-free additives. This research aims to address this gap by designing sustainable additives for next-generation vehicles that not only meet specific requirements but also maintain optimal lubrication performance.

The peer review history for this article is available at: https://publons.com/publon/10.1108/ILT-01-2024-0033/

Bridge deterioration is a critical risk to public safety, which mandates regular inspection and maintenance to ensure sustainable transport services. Many models have been developed to aid in understanding deterioration patterns and in planning maintenance actions and fund allocation. This study aims at developing a deep-learning model to predict the deterioration of concrete bridge decks.

Three long short-term memory (LSTM) models are formulated to predict the condition rating of bridge decks, namely vanilla LSTM (vLSTM), stacked LSTM (sLSTM), and convolutional neural networks combined with LSTM (CNN-LSTM). The models are developed by utilising the National Bridge Inventory (NBI) datasets spanning from 2001 to 2019 to predict the deck condition ratings in 2021.

Results reveal that all three models have accuracies of 90% and above, with mean squared errors (MSE) between 0.81 and 0.103. Moreover, CNN-LSTM has the best performance, achieving an accuracy of 93%, coefficient of correlation of 0.91, R2 value of 0.83, and MSE of 0.081.

The study used the NBI bridge inventory databases to develop the bridge deterioration models. Future studies can extend the model to other bridge databases and other applications in the construction industry.

This study provides a detailed and extensive data cleansing process to address the shortcomings in the NBI database. This research presents a framework for implementing artificial intelligence-based models to enhance maintenance planning and a guideline for utilising the NBI or other bridge inventory databases to develop accurate bridge deterioration models. Future studies can extend the model to other bridge databases and other applications in the construction industry.