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Article
Publication date: 22 September 2023

Aying Zhang, Ziyu Xing and Haibao Lu

The purpose of this paper is to study the mechanochemical effect and self-growth mechanism of double-network (DN) gel and to provide a quasiperiodic model for rubber elasticity.

Abstract

Purpose

The purpose of this paper is to study the mechanochemical effect and self-growth mechanism of double-network (DN) gel and to provide a quasiperiodic model for rubber elasticity.

Design/methodology/approach

The chemical reaction kinetics is used to identify the mechanochemical transition probability of host brittle network and to explore the mechanical behavior of endosymbiont ductile network. A quasiperiodic model is proposed to characterize the cooperative coupling of host–endosymbiont networks using the Penrose tiling of a 2 × 2 matrix. Moreover, a free-energy model is formulated to explore the constitutive stress–strain relationship for the DN gel based on the rubber elasticity theory and Gent model.

Findings

In this study, a quasiperiodic graph model has been developed to describe the cooperative interaction between brittle and ductile networks, which undergo the mechanochemical coupling and mechanical stretching behaviors, respectively. The quasiperiodic Penrose tiling determines the mechanochemistry and self-growth effect of DNs.

Originality/value

It is expected to formulate a quasiperiodic graph model of host–guest interaction between two networks to explore the working principle of mechanical and self-growing behavior in DN hydrogels, undergoing complex mechanochemical effect. The effectiveness of the proposed model is verified using both finite element analysis and experimental results of DN gels reported in literature.

Details

Pigment & Resin Technology, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 20 February 2024

Abdolrahim Gheyassi and Amir Alambeigi

This study’s main objective is to determine the extent to which social capital and psychological capital can explain differences in career adaptability among higher education…

Abstract

Purpose

This study’s main objective is to determine the extent to which social capital and psychological capital can explain differences in career adaptability among higher education students.

Design/methodology/approach

The study employed a quantitative approach, utilizing a survey research design. Data were gathered using an online questionnaire completed by 384 fourth-year undergraduate agricultural students in Iran. The inverse square root and multistage sampling methods were used to determine the sample size. The partial least squares-structural equation modelling (PLS-SEM) method examined the associations between latent variables.

Findings

The results suggest that social and psychological capital significantly influence the career adaptability of agricultural students, highlighting their significance in enhancing career adaptability. Moreover, psychological capital positively mediates the relationship between social capital and career adaptability.

Practical implications

Agricultural higher education institutions must focus on developing students' social and psychological capital to cultivate career adaptability in agricultural students. Agricultural higher education institutions, for example, should help students develop soft skills.

Originality/value

This study offers novel insights into the significance of individual resources, such as social and psychological capital, in enhancing the career adaptability of students. In addition, the key contribution of this study is the researchers' empirical evidence that multiple career resources are interconnected (social capital, career adaptability, and psychological capital).

Details

Higher Education, Skills and Work-Based Learning, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 2042-3896

Keywords

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