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The purpose of this paper is to improve the properties of shellac by blending with epoxidised novolac resin for its use as coating material for metal surfaces.

Epoxidised-novolac resin was synthesised by epoxidation of novolac resin, which in turn was synthesised by reaction of phenol with formaldehyde. The epoxidised-novolac resin was blended with different weight ratios of shellac ranging 10-50 weight per cent with an interval of 10 weight per cent. Films of the blends were studied for different coating properties using standard procedure.

Significant improvement in coating properties of shellac such as gloss, scratch hardness and impact resistance was observed on blending with epoxidised novolac resin. Resistance towards water and alkali increased, while acid resistance decreased, with the increase in concentration of epoxidised novolac resin in the blends. Contact angle measurement revealed that blends showed more resistance towards polar solvent than non-polar ones.

Epoxidised-novolac resin used in the study was synthesised of epoxy equivalent of 187. Epoxidised-novolac resin of different epoxy equivalent can also be synthesised and used for blending and studying the properties.

Blending of shellac with epoxidised-novolac resin improved the coating properties of shellac, which was further enhanced with the treatment of butylated melamine formaldehyde resin. The formulation can be used as coating material for metal surfaces.

Blending of shellac with epoxidised-novolac resin was done for the first time. The formulation can be utilised for developing coating material for metal surfaces.

The purpose of this study is to improve the coating properties of shellac–epoxidised novolac blends by treatment with melamine formaldehyde resin (MF) at ambient temperature for its use as a coating material.

Epoxidised-novolac resin was synthesised by epoxidation of novolac resin with epichlorohydrin. Novolac resin was synthesised by reaction of phenol with formaldehyde in acidic medium. Shellac was blended with the epoxidised-novolac resin in solution in varying ratios and treated the blends with MF resin in fixed ratio. Coating properties of the treated compositions were studied using a standard procedure. The compositions were characterised with Fourier transform infrared spectroscopy (FT-IR), thermogravimetric analysis (TGA) and scanning electron microscopic (SEM) spectroscopy.

Treatment of shellac–epoxidised-novolac blends with MF resin improved water and alkali resistance of the blends, besides enhancing gloss. Gloss in all the blends was uniformly increased on treatment with MF resin. Water resistance of the blends tremendously improved after treatment with MF resin. Contact angle of the blends against water increased while decreased against ethylene glycol and dioxane. The compositions were more resistant to polar solvent than non-polar ones, suggesting that the compositions shifted to hydrophobic (lipophilic) nature on treatment with the MF resin.

A specified concentration of MF resin was used in the study. Different concentrations of the MF resin can also be tried for treatment of shellac–epoxidised-novolac blends to see the effect of the resin on the blends.

Treatment of shellac–epoxidised-novolac blend with MF resin improved the coating properties of the blends. The formulation SeNB-64 is the best with high gloss, good impact, scratch hardness and water resistance, and hence can be used as coating material for metal surfaces.

Blending of shellac with epoxidised-novolac resin and treatment of the blends with the MF resin was done for the first time. The formulation SeNB-64 can be used as coating material for metal surfaces.

The purpose of this paper is to develop eco‐friendly coatings based on low‐cost epoxide resins prepared by using a natural phenolic material such as cardanol (non‐toxic), in place of ordinary phenol (toxic), which can be self‐curable at an optimum temperature.

Cardanol‐formaldehyde novolac resins (CNs) were prepared by reacting cardanol with formaldehyde in different molar ratios varying from 1:0.6 to 1:0.9. Prepared CNs were epoxidised by reacting with epichlorohydrin to produce epoxide resins, which would be called as epoxidised CNs (ECNs). Further, ECNs were modified by reacting with diethanolamine (DEtOA), a secondary amine to introduce tertiary amino group(s) into the molecules, required for self‐curability of ECNs. These modified ECNs are referred to as MECNs. The molar ratio of ECNs to DEtOA was taken in accordance with epoxy functionality of epoxide resins (ECNs) which ranged from 0.5 to 2.9. Nine numbers of MECNs (MECN₁ to MECN₉) were prepared by using four epoxide resins. These resins viz. CNs, ECNs and MECNs were characterized by ¹H NMR and FTIR spectroscopic methods for their structure elucidatation, and by gel permeation chromatography for determining their molecular weights.

The most suitable molar ratio of ECN:DEtOA for the preparation of MECNs was found to be 1:1. The CN prepared by using cardanol and formaldehyde in the molar ratio of 1:0.7 was used for the preparation of ECN₂ and MECN₂. Applied films of epoxide resins, designated as MECN₂, had reasonably good physical and chemical resistance properties. With a wide cure window, the films of MECN₂ were found to be self‐curable at an optimum cure schedule of 160°C/30 min. Owing to self‐curability of the developed epoxide resins, the coatings based on them did not require any additional/external crosslinker to be incorporated in the coating composition.

The prepared epoxide resins (MECNs) had good physical and chemical resistance properties, but demonstrated low stability and low resistance to xylene, in particular.

The paper shows how the epoxide resins were prepared by using a low‐cost phenolic material (cardanol) which is obtained from natural renewable resources, instead of petroleum, and is non‐toxic. These developed coatings can be applied as primer coat and top coat on metallic substrates. True self‐curability of the coating films has been achieved via anionic polymerization.

The purpose of this paper is to study the effect of various stoichiometric ratios for synthesised epoxy phenolic novolac (EPN) resins on their physicochemical, thermomechanical and morphological properties.

In the present study, EPN (EPN-1, EPN-2, EPN-3, EPN-4 and EPN-5) resins were synthesised by varying five types of different stoichiometric ratios for phenol/formaldehyde along with the corresponding molar ratios for novolac/epichlorohydrin. Their different physicochemical properties of interest, thermomechanical properties as well as morphological properties were studied by means of cured samples with the variation of its stoichiometric ratios.

The average functionality and reactivity of EPN resin can be controlled by controlling epoxy equivalence as well as cross-linking density upon its curing as all of these factors are internally correlated with each other.

Epoxy resins are characterised by a three-membered ring known as the epoxy or oxirane group. The capability of the epoxy ring to react with a variety of substrates imparts versatility to the resin. However, these resins have a major drawback of low toughness, and they are also very brittle, which limits their application in products that require high impact and fracture strength.

Epoxy resins have been widely used as high-performance adhesives and matrix resins for composites because of their outstanding mechanical and thermal properties. Because of their highly cross-linked structure, the epoxy resin disables segmental movement, making them hard, and it is also notch sensitive, having very low fracture energy.

Epoxy resin is widely used in industry as protective coatings and for structural applications, such as laminates and composites, tooling, moulding, casting, bonding and adhesives.

Systematic study has been done for the first time, as no exact quantitative stoichiometric data for the synthesis of EPN resin were available on the changes of its different properties. Thus, an optimised stoichiometric composition for the synthesis of the EPN resin was found.

This paper aims to obtain high mechanical and good tribological properties of epoxy resin-based coatings under dry friction conditions.

Bonded solid lubricant coatings containing Kevlar fibres were prepared by a spraying method. The friction and wear properties of the coatings were experimentally investigated with a face-to-face tribometre under dry friction conditions. Scanning electron microscopy, energy dispersive X-ray spectroscopy and 3D laser scanning technologies were used to characterise the tribological properties. The action mechanism of the Kevlar fibres on a solid lubricant transfer film was also analysed.

Adding Kevlar fibres can significantly improve the wear resistance of the coatings. When the Kevlar fibre content increases, the tribological properties of the coatings improve and then worsen. Superior properties are obtained with 0.03 g of Kevlar fibres. Appropriately increasing the load or speed is beneficial to the removal of the outer epoxy resin and the formation of a lubricant film. During friction, the solid lubricants wrapped in the epoxy resin accumulate on the surface to form a transfer film that shows a good self-lubricating performance. In the later friction stage, fatigue cracks occur on the solid lubricant film but cannot connect to one another because of the high wear resistance and the entanglement of the rod-like Kevlar fibres. Thus, no large-area film falls from the matrix, thereby ensuring the long-term functioning of solid lubricant coatings.

Epoxy resin-based solid lubricant coatings modified by Kevlar fibres were prepared, and their friction and wear properties were investigated. Their tribological mechanisms were also proposed. This work provided a basis for the analysis of the tribological properties and design of bonded solid lubricant coatings containing Kevlar fibres.