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1 – 10 of 41Khishn Kumar Kandiah, Vengadaesvaran Balakrishnan, Amirul Syafiq, Nasrudin Abd Rahim, Adarsh Kumar Pandey, Yee Seng Tan, Sanjay J Dhoble, Ramesh Kasi and Ramesh Subramaniam
There is a strong inducement to develop new inorganic materials to substitute the current industrial pigments, which are known for their poor ultraviolet absorbent and low…
Abstract
Purpose
There is a strong inducement to develop new inorganic materials to substitute the current industrial pigments, which are known for their poor ultraviolet absorbent and low photoluminescence (PL) properties. The purpose of this paper is to invent a better rare-earth-based pigment material as a spectral modifier with good luminescence properties to enhance the spectral response for photovoltaic panel application.
Design/methodology/approach
Different phosphor samples made of nano-calcium carbonate (CaCO3) with varied wt.% of the dopant Dysprosium doped calcium borophosphate (CBP/Dy) as (W0 – 0%, W1 – 3,85%, W2 – 7.41%, W3 –10.71% and W4 –13.79%) were prepared via the solid-state diffusion method at 600 °C for 6 h using a muffle furnace. The structural, morphological and luminescence properties of the CaCO3:CBP/Dy powder samples were examined using scanning electron microscopy (SEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR) and PL test.
Findings
The XRD, SEM and FTIR results verified the crystalline formation, morphological behaviour and vibration bonds of synthesized CBP/Dy-doped CaCO3 powder samples. XRD pattern revealed that the synthesized powder samples exhibit crystalline structured materials, and SEM results showed irregular shape and porous-like structured morphologies. FTIR spectrum shows prominent bands at 712, 874 and 1,404 cm−1, corresponding to asymmetric stretching vibrations of CO32− groups and out-of-plane bending. PL characterization of CBP/Dy-doped CaCO3 (sample W) shows emission at 427 nm (λmax) under the excitation of 358 nm. The intensity of PL emission spectra drops due to the concentration quenching effect, while the maximum PL intensity is observed in the W3 phosphor powder system.
Research limitations/implications
This phosphor powder is expected to find out the potential application such as a spectral modifier which is applied to match the energy of photons with solar cell bandgap to improve spectral absorption and lead to better efficiency.
Originality/value
The introduction of a nano-CaCO3:CBP/Dy hybrid powder system with good luminescence properties to be used as spectral modifiers for solar cell application has been synthesized in the lab, which is a novel attempt.
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Keywords
Wojciech Chlebosz and Grzegorz Ombach
In order to reduce CO2 emissions of new cars many hydraulic and mechanical systems like e.g.: water pump, oil pump, power steering, clime compressor have been exchanged with pure…
Abstract
Purpose
In order to reduce CO2 emissions of new cars many hydraulic and mechanical systems like e.g.: water pump, oil pump, power steering, clime compressor have been exchanged with pure electromechanical systems, which are driven only on request. This helps to reduce fuel consumption. This trend requires of utilization of modern brushless electric motors, which are controlled from power electronic control unit – ECU. In today's car can be found between 30 to 150 electric motors. Many of them are still simple brush type with ferrite magnets. Also in this area, drift in the direction of brushless motors can bee seen, because of higher efficiency, longer lifetime, lower noise, better EMC and more controllable torque vs speed characteristic. There are different technological solutions, which can been used in the area of brushless motors in order to reduce size and cost of single component. One major factor of BLDC/AC motor is rear earth permanent magnet material used during production. A magnet material cost could be in the range from 30 percent (basis price 2010) up to 90 percent (basis price 2011) of total material motor cost, depends on actual rear earth material price level. In order to reduce magnet cost, the aim of this paper is to find the most robust motor design, which can be resistant against maximum temperature and phase current amplitude for the same magnet material properties, coercive force – Hcj. This behaviour is called demagnetization property.
Design/methodology/approach
Analysis was performed based on review of literature, own theoretical and practical research and experience in the area of electromechanical systems for automotive application. During motor analysis computer numerical simulation method, CAD and experiment were used.
Findings
As a result, comparison of different motors' topologies with different properties of magnet materials is presented. The worked out methodology shows very good correlation between simulations and measurements. This work can be used in order to reduce test effort and reduce cost of design.
Practical implications
The presented methodology reduces for new designs test effort and development cost and gives an implication of robust motor topology for demagnetization effects.
Originality/value
It is the first paper where demagnetization effects have been studied theoretically and in laboratory in order to find the most robust design, reduce magnet cost by reduction of dysprosium content and develop simulation procedure for analysis of demagnetizations behaviours of interior and surface permanent magnet.
Details
Keywords
The paper seeks to review the undesirable side‐effects of some measures to protect the environment, particularly the results of increased demand for certain metals used in hybrid…
Abstract
Purpose
The paper seeks to review the undesirable side‐effects of some measures to protect the environment, particularly the results of increased demand for certain metals used in hybrid cars and wind turbines, and for tantalum for mobile phones. The increased demands for indium and lithium due to technical developments are also discussed although they do not pose corresponding dilemmas.
Design/methodology/approach
The aim is to review developments on the internet, especially those of general cybernetic interest.
Findings
Undesirable side‐effects need to be considered, though means of overcoming them are not always apparent.
Practical implications
In the case of tantalum and mobile phones, attention has been given to ethical sourcing. The possibility of indium extraction in the UK is a welcome development.
Originality/value
It is hoped this is a valuable periodic review.
Details
Keywords
Emmanuel Apergis and Nicholas Apergis
The purpose of this paper is to explore, for the first time, the relationship between the prices of rare earth materials and economic growth. Renewable technologies and many…
Abstract
Purpose
The purpose of this paper is to explore, for the first time, the relationship between the prices of rare earth materials and economic growth. Renewable technologies and many high-demanded technologies need significant supplies of such materials.
Design/methodology/approach
The paper uses a panel of the six most significant rare earth producers around the globe, as well as certain panel methodologies.
Findings
The empirical analysis indicates the presence of a positive impact of such minerals prices on economic growth. Causality methodologies also indicate unidirectional causality between GDP and the prices of rare earth materials, with the causality running from these prices to economic growth. The findings survive a number of robustness checks.
Originality/value
The claim that natural resources are a curse that makes the countries worse off is not supported for the case of rare earth materials. The results are expected to be of high importance, because these particular rare earth materials are extensively used in a huge list of technological products with high demand and low costs, while they are hard to be replaced.
Details
Keywords
Rare earths mining in Australia and globally.
Details
DOI: 10.1108/OXAN-DB241260
ISSN: 2633-304X
Keywords
Geographic
Topical
Short-term factors combined to strengthen prices, including widespread flooding in China’s Sichuan province and low capacity utilisation among producers outside China. In the…
Details
DOI: 10.1108/OXAN-DB261080
ISSN: 2633-304X
Keywords
Geographic
Topical
The rare earth ores China imports from the United States will face a 25% rate, however, reducing the attractiveness of processing the material in China. The rare earth…
Details
DOI: 10.1108/OXAN-DB243711
ISSN: 2633-304X
Keywords
Geographic
Topical
Ten years after first imposing export restrictions on these metals, China's dominance has shifted but not waned. President Xi Jinping's visit to a rare earth magnet factory at the…
Details
DOI: 10.1108/OXAN-DB254237
ISSN: 2633-304X
Keywords
Geographic
Topical
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