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The purpose of this study is to provide a highly efficient method to obtain the kinetics of the hydrogen evolution reaction (HER) on metal electrodes in an alkaline solution and to analyze the effect of thiourea addition on HER under the same cathodic overpotential.

A novel method based on hydrogen permeation tests, potentiodynamic polarization tests and electrochemical impedance spectroscopy was put forward to characterize the HER kinetics on metal electrode.

The study found that adding thiourea accelerated the Volmer, Heyrovsky and Tafel reactions associated with HER. In addition, it reduced the hydrogen surface coverage and increased the hydrogen permeation steady-state current density. As a result, thiourea facilitated HER, promoted the diffusion of hydrogen atoms into iron and reduced the number of hydrogen atoms in the adsorbed state.

This work provides novel insights into the influence of thiourea on HER kinetics, demonstrating that thiourea addition can significantly enhance HER efficiency by altering reaction dynamics and promoting hydrogen atom diffusion into iron. This has implications for hydrogen energy applications, cathodic protection and understanding hydrogen embrittlement mechanisms.

To improve the corrosion resistance of magnesium alloys, the construction of protective coatings is necessary to extend the service life of Mg-based materials.

SiO₂ nanoparticles modified by dodecyltrimethoxysilane (DTMS) were added to the PP and a superhydrophobic Mg(OH)₂/PP-60mSiO₂ composite coating was fabricated on the surface of AZ31 magnesium alloy via the hydrothermal method and subsequently the immersion treatment.

Hydrophilic SiO₂ nanoparticles become hydrophobic after modified by DTMS, showing a higher dispersibility in xylene. By incorporating modified SiO₂ nanoparticles into the composite PP coating, the hydrophobicity of the layer was enhanced, resulting in a contact angle of 166.3° and a sliding angle of 3.4°. It also improved the water repellency and durability of the coating. Furthermore, the intermediate layer of Mg(OH)₂ significantly strengthened the bond between the PP layer and the substrate. The Mg(OH)₂/PP-60mSiO₂ composite coating significantly enhances the corrosion resistance of the magnesium alloy by effectively blocking the infiltration of the corrosion anions during corrosion. The corrosion current density of the Mg(OH)₂/PP-60mSiO₂ composite coating is approximately 8.23 × 10^–9 A·cm^-2, which can achieve a magnitude three times lower than its substrate, making it a promising surface modification for the Mg alloy.

The composite coating effectively and durably enhances the corrosion resistance of magnesium alloys.

The purpose of this study is to investigate and analyse the potential of existing buildings in the UK to contribute to the net-zero emissions target. Specifically, it aims to address the significant emissions from building fabrics which pose a threat to achieving these targets if not properly addressed.

The study, based on a literature review and ten (10) case studies, explored five investigative approaches for evaluating building fabric: thermal imaging, in situ U-value testing, airtightness testing, energy assessment and condensation risk analysis. Cross-case analysis was used to evaluate both case studies using each approach. These methodologies were pivotal in assessing buildings’ existing condition and energy consumption and contributing to the UK’s net-zero ambitions.

Findings reveal that incorporating the earlier approaches into the building fabric showed great benefits. Significant temperature regulation issues were identified, energy consumption decreased by 15% after improvements, poor insulation and artistry quality affected the U-values of buildings. Implementing retrofits such as solar panels, air vents, insulation, heat recovery and air-sourced heat pumps significantly improved thermal performance while reducing energy consumption. Pulse technology proved effective in measuring airtightness, even in extremely airtight houses, and high airflow and moisture management were essential in preserving historic building fabric.

The research stresses the need to understand investigative approaches’ strengths, limitations and synergies for cost-effective energy performance strategies. It emphasizes the urgency of eliminating carbon dioxide (CO₂) and greenhouse gas emissions to combat global warming and meet the 1.5° C threshold.