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Article
Publication date: 17 April 2023

Laiming Yu, Yaqin Fu and Yubing Dong

The purpose of this study is to improve the mechanical property and processing performance and reduce the cost of the polylacticacid/polybutyleneadipate-co-terephthalate(PLA/PBAT…

Abstract

Purpose

The purpose of this study is to improve the mechanical property and processing performance and reduce the cost of the polylacticacid/polybutyleneadipate-co-terephthalate(PLA/PBAT) composites, the calcium carbonate (CaCO3) and compatibilizer styrene-maleicanhydride copolymer (SMA-2025) were added to the PLA/PBAT system, and the effect of CaCO3 and SMA-2025 on the morphology, structure, mechanical property, thermal property, thermalstability and shape memory property of the CaCO3/PLA/PBAT composites were studied and discussed.

Design/methodology/approach

The CaCO3/PLA/PBAT shape memory composites were prepared via melt-blending and hot-pressing methods, and the effect of CaCO3 and SMA-2025 on the property of the composites was investigated via scanning electron microscope, universal testing instrument, Fourier transform infrared spectroscopy, differential scanning calorimetry, thermogravimetric analysis and DMA, respectively.

Findings

The interface property, mechanical property, thermal stability, shape memory recovery ratios and recovery stresses, and processing performance of the CaCO3/PLA/PBAT shape memory composites were significantly improved by adding of CaCO3 and SMA-2025. Moreover, the CaCO3/PLA/PBAT composites have good blowing film processing performance.

Originality/value

This study will provide a reference for the research, processing and application of the high-performance CaCO3/PLA/PBAT shape memory composites.

Details

Pigment & Resin Technology, vol. 53 no. 5
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 27 January 2023

Yangdong Liu, Siyuan Lu, Hongyi Tu, Boyuan Zhang, Yaqin Zhao, Jiasheng He, Liangliang He and Zhenbin Chen

To save the economic cost and improve the performance of enterprises, this study aims to synthesize high performance immobilized penicillin G acylase (PGA) carriers with fast…

Abstract

Purpose

To save the economic cost and improve the performance of enterprises, this study aims to synthesize high performance immobilized penicillin G acylase (PGA) carriers with fast reaction speed, high recovery rate of enzyme activity and good reusability through corresponding theoretical guidance and experimental exploration.

Design methodology approach

A diblock resin was synthesized by reversible addition-fragmentation chain transfer polymerization method using N, N-diethylacrylamide (DEA) and β-hydroxyethyl methacrylate (HEMA) as functional monomers poly(N, N-diethylacrylamide)-b-poly(β-hydroxyethyl methacrylate) (PDEA-b-PHEMA) was obtained, and the effect of the ratio of DEA and HEMA on the activity of PGA was investigated, and the appropriate block ratio of DEA and HEMA was obtained. After that, the competitive rate of HEMA and glycidyl methacrylate (GMA) under the carrier preparation conditions was investigated. Based on the above work, a thermosensitive resin carrier PDEA-b-PHEMA-b-P(HEMA-co-GMA) with different target distances was synthesized, and the chemical structures and molecular weight of copolymers were investigated by hydrogen NMR (1H NMR).

Findings

The lower critical solution temperature of the resin support decreases with the increase of the monomer HEMA in the random copolymerization; the catalytic performance study indicated that the response rate of the immobilized PGA is fast, and the recovery rate of the enzyme activity of the immobilized PGA varies with the distance between the targets. When the molar ratio of HEMA to GMA in the resin block is 8.15:1 [i.e. resin PDEA100-b-PHEMA10-b-P(HEMA65-co-GMA8)], the activity recovery rate of immobilized PGA can reach 50.51%, which was 15.49% higher than that of pure GMA immobilized PGA.

Originality value

This contribution provides a novel carrier for immobilizing PGA. Under the optimal molar ratio, the enzyme activity recovery could be up to 50.51%, which was 15.49% higher than that of PGA immobilized on the carrier with nonregulated distance between two immobilization sites.

Details

Pigment & Resin Technology, vol. 53 no. 5
Type: Research Article
ISSN: 0369-9420

Keywords

Article
Publication date: 11 September 2024

Swarup Mukherjee, Anupam De and Supriyo Roy

Traditional risk prioritization methods in Enterprise Risk Management (ERM) rely on precise data, which is often not available in real-world contexts. This study addresses the…

Abstract

Purpose

Traditional risk prioritization methods in Enterprise Risk Management (ERM) rely on precise data, which is often not available in real-world contexts. This study addresses the need for a robust model that can handle uncertain and imprecise information for more accurate risk assessment.

Design/methodology/approach

We propose a group decision-making approach using fuzzy numbers to represent risk attributes and preferences. These are converted into fuzzy risk scores through defuzzification, providing a reliable method for risk ranking.

Findings

The proposed fuzzy risk prioritization framework improves decision-making and risk awareness in businesses. It offers a more accurate and robust ranking of enterprise risks, enhancing control and performance in supply chain operations by effectively representing uncertainty and accommodating multiple decision-makers.

Practical implications

The adoption of this fuzzy risk prioritization framework can lead to significant improvements in enterprise risk management across various industries. By accommodating uncertainty and multiple decision-makers, organizations can achieve more reliable risk assessments, ultimately enhancing operational efficiency and strategic decision-making. This model serves as a guide for firms seeking to refine their risk management processes under conditions of imprecise information.

Originality/value

This study introduces a novel weighted fuzzy Risk Priority Number method validated in the risk management process of an integrated steel plant. It is the first to apply this fuzzy approach in the steel industry, demonstrating its practical effectiveness under imprecise information. The results contribute significantly to risk assessment literature and provide a benchmarking tool for improving ERM practices.

Details

Benchmarking: An International Journal, vol. ahead-of-print no. ahead-of-print
Type: Research Article
ISSN: 1463-5771

Keywords

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