Synthesis of butylated benzo-amino resin by solid formaldehyde one-step-two-stage method and its application in high solid content coatings

Abstract

Purpose

In this study, solid formaldehyde, benzoguanamine and butanol were used to synthesize butylated benzo-amino resin by one-step-two-stage method.

Design/methodology/approach

This research first examined the influence of solid formaldehyde content on the hydroxymethylation phase. Subsequently, the effects of butanol content, etherification time and hydrochloric acid content on the formation of benzo-amino resin during the etherification stage were studied in detail. In addition, the reaction process was further analyzed through interval sampling withdrawing during the hydroxymethylation and etherification stages. Finally, the synthesized benzo-amino resins were used in the production of high solid content polyester and acrylic coatings and the properties of that were also evaluated.

Findings

Based on the experimental findings, the authors have successfully determined the optimal process conditions for the one-step-two-stage method in this study. The hydroxymethylation stage demonstrated the most favorable outcomes at a reaction temperature of 60°C and a pH of 8.5. Similarly, for the etherification stage, the optimal conditions were achieved at a temperature of 45°C and a pH of 4.5. Furthermore, the investigation revealed that a ratio of benzoguanamine to solid formaldehyde to n-butanol, specifically at 1:5.2:15, produced the best results. The performance of the resulting etherified benzo-amino resin was thoroughly evaluated in high solid content coatings, and it exhibited promising characteristics. Notably, there was a significant enhancement in the water resistance, solvent resistance and glossiness of canned iron printing varnish coatings.

Originality/value

Amino resin, a versatile chemical compound widely used in various industries, presents challenges in terms of sustainability and operational efficiency when synthesized using conventional methods, primarily relying on a 37% formaldehyde solution. To address these challenges, the authors propose a novel approach in this study that combines the advantages of the solid formaldehyde with a two-stage catalytic one-step synthesis process. The primary objective of this research is to minimize the environmental impact associated with amino resin synthesis, optimize resource utilization and enhance the economic feasibility for its industrial implementation. By adopting this alternative approach, the authors aim to contribute toward a more sustainable and efficient production of amino resin.

Citation

Yang, X., Wang, X., Huang, S., Liu, X., Huang, X. and Lei, T. (2023), "Synthesis of butylated benzo-amino resin by solid formaldehyde one-step-two-stage method and its application in high solid content coatings", Pigment & Resin Technology, Vol. ahead-of-print No. ahead-of-print. https://doi.org/10.1108/PRT-05-2023-0043