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Corrosion resistance of MWCNTs-nanoZnO composite reinforced chromium-free Zn-Al coating

Yu Fu (Key Lab of Advanced Technologies of Materials, Ministry of Education, School of Materials Science and Engineering, Southwest Jiaotong University, Chengdu, China)
Junwen Zhao (Key Lab of Advanced Technologies of Materials, Ministry of Education, School of Materials Science and Engineering, Southwest Jiaotong University, Chengdu, China)
Xujia Li (Key Lab of Advanced Technologies of Materials, Ministry of Education, School of Materials Science and Engineering, Southwest Jiaotong University, Chengdu, China)
Yiwen Peng (Key Lab of Advanced Technologies of Materials, Ministry of Education, School of Materials Science and Engineering, Southwest Jiaotong University, Chengdu, China)

Anti-Corrosion Methods and Materials

ISSN: 0003-5599

Article publication date: 26 September 2024

Issue publication date: 30 October 2024

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Abstract

Purpose

This paper aims to prepare high corrosion-resistant chromium-free zinc-aluminum (Zn–Al) coatings reinforced with multi-walled carbon nanotubes (MWCNTs) and nano-ZnO particle composites.

Design/methodology/approach

The morphology, composition and corrosion resistance of the coatings were analyzed by electrochemical tests, water contact angle tests, immersion tests, scanning electron microscopy/energy dispersive spectrometer and X-ray diffraction.

Findings

The composite coating with 0.3% MWCNTs and 0.5% nano-ZnO particles demonstrated both high shielding performance and cathodic protection performance, which was attributed to the porosity filling of MWCNTs and nano-ZnO particles together with the electrical connection of MWCNTs between the zinc and aluminum powders.

Originality/value

This work laid an experimental foundation for the preparation and corrosion mechanism of high corrosion-resistant chromium-free Zn–Al coating reinforced with MWCNTs and nano-ZnO particles.

Keywords

Acknowledgements

This work was supported by the Sichuan Science and Technology Program (No. 2023YFG0195 and 2023YFG0234).

Declaration of competing interest: The authors declare that they have no known competing financial interests or personal relationships that could have influenced the work reported in this study.

Ethical compliance: The study was approved by the Ethics Committee of Southwest Jiaotong University. All procedures performed in studies involving human participants were in accordance with the ethical standards of the institutional and/or national research committee and with the 1964 Helsinki Declaration and its later amendments or comparable ethical standards.

Citation

Fu, Y., Zhao, J., Li, X. and Peng, Y. (2024), "Corrosion resistance of MWCNTs-nanoZnO composite reinforced chromium-free Zn-Al coating", Anti-Corrosion Methods and Materials, Vol. 71 No. 6, pp. 640-649. https://doi.org/10.1108/ACMM-01-2024-2948

Publisher

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Emerald Publishing Limited

Copyright © 2024, Emerald Publishing Limited

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