Comparative analysis of stearates as grease lubricant thickeners
Industrial Lubrication and Tribology
ISSN: 0036-8792
Article publication date: 6 August 2019
Issue publication date: 22 October 2019
Abstract
Purpose
This paper aims to investigate the influence of stearate types on the thickening ability, dropping point and fiber structure of greases.
Design/methodology/approach
Several greases were prepared from polyolefins and various stearates. The melting point of the stearates and the dropping point of the resultant greases were measured, and the intermolecular binding energies of the thickener and the radial distribution function of the metal–oxygen in the thickener were determined with the aid of molecular simulation. The microstructures of the greases were also analyzed via scanning electron microscopy.
Findings
A higher stearate binding energy was found to correlate to a higher dropping point of the resultant greases. The thickening ability of the stearate is related to the group and period of the constituent metal ion. Within a group, greater atomic numbers of the metal were correlated to lower thickening ability. In a period, as the atomic number of the metal increased, the thickening ability was enhanced. The radial distribution functions of metal and oxygen can explain the aggregation of the stearate thickeners in the grease.
Originality/value
This work compared the thickening capacity of several stearates. Guidelines for preparing stearates to tailor the resultant grease are presented.
Keywords
Acknowledgements
This research was supported by the National Natural Science Foundation of China (Grant No. 51675153) and Major Science and Technology Special Project in Anhui (Grant No. 17030901084), which are gratefully acknowledged.
Citation
Yao, L., Wang, L., Yang, H., Li, C., Song, H. and Hu, X. (2019), "Comparative analysis of stearates as grease lubricant thickeners", Industrial Lubrication and Tribology, Vol. 71 No. 9, pp. 1093-1098. https://doi.org/10.1108/ILT-01-2019-0008
Publisher
:Emerald Publishing Limited
Copyright © 2019, Emerald Publishing Limited